Aqueous electrochemical intercalation of bromine into graphite fibers

For the first time, graphite fibers have been electrochemically intercalated with Br⁻ that have the same structure and properties as those intercalated from vapor phase Br₂. This was accomplished by intercalating pitch-based Thornel^® K-1100 graphite fibers at low temperature (near 0 °C) and high currents (2 A) for long times (6 h). The mechanism appears to be that Br⁻ is oxidized to aqueous Br₂ which, when sufficient local concentration builds up, intercalates the fiber. This was confirmed by intercalating K-1100 fiber in a saturated aqueous Br₂ solution without passing an electrical current. The applied voltage does apparently lower the activation energy of the reaction as evidenced by the observation that P-120 and P-100 fibers will not intercalate in aqueous Br₂ unless a voltage is applied.     

中国传统家具造型的传承与创新

中国传统家具源远流长,经过千年历炼在明清时期达到历史颠蜂,然而随着国门的被迫打开。中国家具经历了动荡起伏的局面。笔者深入解读中国传统家具发展现状,探讨萁造型的演变以及近现代尝试与不足,最后对中国传统家具的传承和创新提出自己观点。     

“A+一+X,B+一+Y”构式的分类及释义模板

该文以现代汉语中的“A+一+X,B+一+Y”格式为例,介绍了构建《现代汉语构式知识库》的初步工作。“A+一+X,B+一+Y”格式可根据其表义功能不同分为三个大类,十个小类。该文重点阐释了该构式表达“因果倚变义、事物交错义、状态交替义、动作行为交替义、周遍大量义、让步小量义”等6种意义的判定条件及相应的释义模板。     

改性5A分子筛对水中As(Ⅴ)的吸附作用研究

改性5A分子筛是一种高效吸附材料。实验用5A分子筛作为载体,制备了该吸附剂,并表征了其基本性质。结果表明,改性5A分子筛对As(Ⅴ)具有很高的吸附率和选择性;室温下,pH=7时,改性5A分子筛吸附As(Ⅴ)的吸附等温线符合Langmuir型和Freundlich型。     

基于SVM模型的妫水河叶绿素a浓度的遥感反演

以北京市妫水河为研究区,基于2011年9月25日和2012年9月30日的两期叶绿素a浓度实测数据和准同步的环境一号卫星(HJ-1A)多光谱数据,分别构建一元线性和多元支持向量机模型(SVMM),通过决定系数R²和平均相对误差对模型的精度进行检验,用模型进行水体叶绿素a浓度的反演,并分析其时空分布特征。研究表明:在样本数较少的情况下,SVM具有很强的非线性映射能力,能够取得较好的预测结果,更适用于反演叶绿素a浓度。时间分布上,研究区叶绿素a浓度呈增加趋势,均值上升了6.86 μg/L;空间分布上,深水区叶绿素a浓度值低于浅水区,上游高于下游。国产HJ-1A CCD2多光谱数据以其4 d的时间分辨率,在水质动态变化监测方面具有优势。     

Evolution of chemistry and morphology during the carbonization and combustion of rice husk

Both fine carbon/silica and pure silica powders can be obtained by carbonization and combustion of rice husk under non-isothermal conditions, and the products can be used for preparation of high-quality ceramic materials. Studies on the morphology, chemical and physical characteristics of products were carried out by N₂-adsorptionmeter, SEM, XRD, FTIR, ICP-MS and EA. Results indicate that decreasing the heating rate increased the specific surface area, pore volume and pore diameter. At a heating rate of 5 °C/min, the specific surface areas of both the carbon/silica and pure silica powders were 261 and 235 m²/g, and the average pore diameters were 2.2 and 5.4 nm, respectively. The products obtained from various heating rates were all amorphous. Thermogravimetric analysis was employed to study the reaction characteristics during carbonization or combustion, indicating that decomposition process of rice husk could be divided into three temperature zones. This results of the study can also provide the important information on the recovery of biomass material from rice husk.     

基于蜜罐技术的主动防护网络入侵探究

随着信息技术的快速发展,网络安全问题日益突出,如何保护网络安全成为人们研究的重点.在实际工作过程中应用蜜罐技术来进行主动防护网络入侵是一种新方式.由蜜罐技术和分布式代理构成的防护体系,能够有效降低攻击检测误报率.网络安全形势日益复杂的背景下加强对蜜罐技术的研究具有重要意义.本文将重点探讨如何利用蜜罐技术来实现对网络入侵的主动防护.     

Important issues in a molecular dynamics simulation for characterising the mechanical properties of carbon nanotubes

This paper discusses several important issues in a molecular dynamics simulation for analysing carbon nanotubes and their mechanical properties. In particular, the paper addresses the problems in selecting appropriate inter-atomic potentials, number of thermostat atoms, thermostat techniques, time and displacement steps and number of relaxation steps to reach the dynamic equilibrium. Based on these, the structural changes of armchair and zigzag nanotubes and their mechanical properties are investigated. The Young's modulus and Poisson's ratio of the armchair tube are 3.96 and 0.15 TPa, respectively, and those of the zigzag tube are 4.88 and 0.19 TPa, respectively. The best simulation technique identified in this study predicts that the ultimate tensile strain of a carbon nanotube is around 40% before atomic bond breakage.     

SPCE061A与AD9851的低频可控信号发生器

基于DDS直接数字频率合成技术原理,采用凌阳SPCE061A单片机作为人机界面控制单元和参数形成处理单元,首先以一片AD9851芯片为核心产生频率在10Hz~30 MHz可调、幅度稳定的正弦波、方波和三角波信号,然后通过一路可控模拟开关(使用AD7502芯片)选择波形输出。再通过外接键盘按键控制输出频率及频率步进,并通过LCD显示输出波类型、频率及电压幅度。该系统除具有基本函数信号发生器的主要功能外,还可控制输出频率在10Hz~1MHz之间变化的波型信号,同时还能够保障输出电平满足Vpp=(0~5V)±0.1V。在输出为50Ω负载的条件下,可实现频率在10Hz~1kHz范围内步进10Hz,在10kHz~1MHz范围内步进1kHz。在实验教学、生产等应用中,有一定的使用和推广价值。