氧化热处理对VO2薄膜红外光学相变特性的影响

采用直流磁控溅射法在硅基底上制备VO2薄膜,并对薄膜氧化热处理。分别对热处理前后薄膜进行X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)透射率测试,分析了热处理对VO2薄膜晶相成分与红外透射率相变特性的影响。实验分析表明,经热处理的VO2发生非晶态向晶态转变,单斜金红石结构VO2(011)晶体具有明显择优取向,晶粒尺寸均匀度提高,且薄膜的红外透射率具有明显相变特性,相变温度为60.5℃,3~5μm、8~12μm波段的红外透射率对比值达到99%,适合应用于红外探测器的激光防护研究。     

高稳定大量程复合光纤干涉位移测量系统研究

为了使位移测量系统达到大量程、高分辨率,采用复合光纤干涉的方法,进行了理论分析和实验验证。利用光纤光栅作为反射镜,构成两个干涉光路几乎共路的光纤迈克尔逊干涉仪。其中一个光纤迈克尔逊干涉仪通过反馈控制补偿环境干扰对测量系统的影响,使测量系统适合在线测量;另一个干涉仪用于完成测量工作。两个不同波长的光同时作用于完成测量的干涉仪中,测量量程由两个波长的合成波干涉信号确定,使测量量程大于1mm;测量分辨率由其中一个单波长干涉信号确定,测量分辨率小于1nm。结果表明,这种基于复合光纤干涉仪的位移测量系统可以实现大量程、高稳定的位移在线测量。     

氟金云母衬底上C_(60)薄膜的光学性质

用热壁外延法在氟金云母衬底上生长出了高质量 C6 0 薄膜 ,用原子力显微镜观察了样品的表面形貌 .测量并分析了不同厚度 C6 0 薄膜的紫外 -可见吸收光谱 .由测量的透射及反射光谱 ,经计算得到了吸收系数与入射光子能量的关系 .利用结晶半导体的带间跃迁理论 ,对禁戒的带间直接跃迁 hu→ t1 u和电偶极允许的带间直接跃迁 hu→ t1 g的带隙分别进行了计算     

石英玻璃中杂质对光纤损耗影响的研究

石英玻璃根据生产加工的工艺可以分为四类,不同工艺生产的石英玻璃其杂质含量也不相同.石英玻璃作为光纤预制棒生产过程中必不可少的辅助材料[1],其中的杂质含量会对生产的预制棒最终的拉丝光纤衰减产生影响.为避免因杂质吸收产生的衰减,需要根据使用的工况要求选择合适的石英玻璃.     

Development of Nd (III)-Based Terahertz Absorbers Revealing Temperature Dependent Near-Infrared Luminescence

Molecular vibrations in the solid-state, detectable in the terahertz (THz) region, are the subject of research to further develop THz technologies. To observe such vibrations in terahertz time-domain spectroscopy (THz-TDS) and low-frequency (LF) Raman spectroscopy, two supramolecular assemblies with the formula [Nd^III (phen)₃ (NCX)₃] 0.3EtOH (X = S, 1-S; Se, 1-Se) were designed and prepared. Both compounds show several THz-TDS and LF-Raman peaks in the sub-THz range, with the lowest frequencies of 0.65 and 0.59 THz for 1-S and 1-Se, and 0.75 and 0.61 THz for 1-S and 1-Se, respectively. The peak redshift was observed due to the substitution of SCN⁻ by SeCN⁻. Additionally, temperature-dependent TDS-THz studies showed a thermal blueshift phenomenon, as the peak position shifted to 0.68 THz for 1-S and 0.62 THz for 1-Se at 10 K. Based on ab initio calculations, sub-THz vibrations were ascribed to the swaying of the three thiocyanate/selenocyanate. Moreover, both samples exhibited near-infrared (NIR) emission from Nd (III), and very good thermometric properties in the 300–150 K range, comparable to neodymium (III) oxide-based thermometers and higher than previously reported complexes. Moreover, the temperature dependence of fluorescence and THz spectroscopy analysis showed that the reduction in anharmonic thermal vibrations leads to a significant increase in the intensity and a reduction in the width of the emission and LF absorption peaks. These studies provide the basis for developing new routes to adjust the LF vibrational absorption.     

发光波长可调的聚吡咯甲烷的制备及光学特性

聚合物发光材料因其拥有诸多优点,在有机发光二极管器件方面的应用前景广阔.然而,对于蓝光聚合物发光材料,由于其发光性能、使用寿命等方面仍然存在不足,难以满足全色显示的需要.以吡咯类单体和4-乙基苯甲醛单体为原料,采用溶液缩聚法制备了3种聚吡咯甲烷(聚{吡咯-[2,5-二(4-乙基苯甲烷)]}(PPE)、聚{N-甲基吡咯-...     

一种适用于DCO-OFDM系统的DFT信道估计算法

针对直流偏置光正交频分复用系统中传统离散傅里叶变换(DFT)信道估计算法运算复杂度高和循环前缀(CP)内存在非有效信道系数的问题,提出厄米特对称的DFT(H-DFT)阈值改进信道估计算法.首先,根据信道时域响应变换到频域满足厄米特对称的性质,只需对有效子载波的信道频域响应做厄米特对称即可获得全部子载波的信道频域响应;其...     

基于垂直扭转梳齿驱动结构的硅微机械扭转微镜的设计加工与表征

为了改善扭转微镜的机电耦合特性和光学特性,提出了一种新的基于SOI硅片的垂直扭转梳齿静电驱动结构．通过有限元与边界元方法,对不同厚度扭转梁的机电耦合特性进行了数值模拟,得到了相应的阈值电压和吸合电压,并提出了几种新的折叠梁结构,以进一步改善器件的机电耦合特性;通过力学分析,从理论上推导了垂直扭转梳齿静电驱动方式微镜的最大扭转角度、阈值电压、扭转刚度以及固有频率,获得了结构参数对器件机电耦合特性的影响机制;最后,利用比例散射理论讨论了表面粗糙度、入射光束波长和入射角度等参数对微镜表面光学反射性能的影响,并利用原子力显微镜测量了微镜的表面粗糙度,理论模拟与实验研究表明,基于SOI硅片和垂直扭转梳齿结构的硅微机械扭转微镜可显著降低器件的驱动电压,提高器件的机电耦合特性和微镜表面的光学反射特性．     

Design and Development of a Bimodal Optical Instrument for Simultaneous Vibrational Spectroscopy Measurements

Vibrational spectroscopy techniques are widely used in analytical chemistry, physics and biology. The most prominent techniques are Raman and Fourier-transform infrared spectroscopy (FTIR). Combining both techniques delivers complementary information of the test sample. We present the design, construction, and calibration of a novel bimodal spectroscopy system featuring both Raman and infrared measurements simultaneously on the same sample without mutual interference. The optomechanical design provides a modular flexible system for solid and liquid samples and different configurations for Raman. As a novel feature, the Raman module can be operated off-axis for optical sectioning. The calibrated system demonstrates high sensitivity, precision, and resolution for simultaneous operation of both techniques and shows excellent calibration curves with coefficients of determination greater than 0.96. We demonstrate the ability to simultaneously measure Raman and infrared spectra of complex biological material using bovine serum albumin. The performance competes with commercial systems; moreover, it presents the additional advantage of simultaneously operating Raman and infrared techniques. To the best of our knowledge, it is the first demonstration of a combined Raman-infrared system that can analyze the same sample volume and obtain optically sectioned Raman signals. Additionally, quantitative comparison of confocality of backscattering micro-Raman and off-axis Raman was performed for the first time.     

黄麻纤维性能及其服用产品开发

随着生态与环保意识的加强,黄麻纤维优良的抗茵舒适性能也引起了人们的关注,为此,对尚未充分开发的黄麻纤维作产品的设计,已经成为一个重要的研究方向。介绍了黄麻纤维的主要性能,展望了黄麻纤维与其他纤维混纺产品的发展前景。