Pervaporation study of water and tert‐butanol mixtures

The permeation behavior of water/tert‐butanol mixture through Sulzer Pervap2510 hydrophilic poly(vinyl alcohol) membranes was investigated and the effects of feed composition and temperature on separation efficiency of the membranes were studied. The pervaporation experiments were carried out with feed water content varying from 0 to 20 wt % according to the existing industrial needs and with the feed temperature from 60 to 100°C. Over this range, both water flux and separation factor increased with increasing water content and feed temperature. These phenomena may be attributed to (1) the strong interaction between water and the membrane, (2) the decoupling effect of the permeants and the membrane at elevated temperatures, and (3) the steric hindrance effect of branch chain alcohol. The permeability ratio (the ideal separation factor) of water to tert‐butanol across the membrane was calculated and found to follow the same relationship with increasing temperature and water content. Both flux and separation factor obtained from the Pervap2510 membrane in this study were much higher than previous reported values, possible causes for which were analyzed. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 4082–4090, 2004     

PROBING HIDDEN POLYMERIC INTERFACES USINGIR-VISIBLE SUM-FREQUENCY GENERATION SPECTROSCOPY

Understanding the molecular-level processes underlying interfacial phenomena is important in the area of adhesion. We briefly introduce IR-visible sum-frequency generation spectroscopy (SFG) using a total-internal-reflection geometry for the study of polymer-air, polymer-solid, and polymer-polymer interfaces. The following examples, predominantly of work done in our lab, illustrating differences in molecular structure and dynamic properties at interfaces are presented: the air- and solid-interface structure of an amorphous polystyrene (PS) and a semicrystalline polymer with side-chain crystallinity, poly(octadecyl acrylate) (PA-18); structure of a polymer-polymer interface between thin films of a semicrystalline polymer with side-chain crystallinity, poly(vinyl-N-octadecylcarbamate- co-vinyl acetate), and an amorphous PS; thermal order-to-disorder transitions of the air and solid interface of PA-18, and the interface of this polymer with PS; and dynamic surface-relaxation studies of a rubbed PS film.     

聚丙烯酸叔丁酯的可控合成

以偶氮二异丁腈(AIBN)为引发剂,1-苯乙基二硫代苯乙酸酯(PEPDTA)为RAFT试剂,在乙酸乙酯中实施了丙烯酸叔丁酯(tBA)的RAFT自由基聚合。分子量测试表明,在高转化率(93%)下P(tBA)的分子量分布指数(Mw/Mn)小于1.1,且数均分子量与转化率成良好的线性关系,体现了可控/"活性"聚合的特征。     

基于多保留策略的复合型遗传算法及其收敛性分析

遗传算法(GA)作为一种新型的智能优化方法,以其结构简单、适应性强等特点在众多实际领域取得了成功的应用,但存在计算复杂度大、易于局部收敛等方面的不足。本文在分析现有遗传操作的不足和生物进化的基本特征基础上,从提高进化效率的角度出发,提出基于多保留策略的复合型遗传算法(简称MRS-CGA);进而利用Markov链理论和仿真技术,从不同的层面分析了算法的性能。讨论结果表明,算法从本质上推广了常规的GA,在计算效率和收敛性能上均明显地优于常规的GA。     

Conditional probability Markov chain simulation based reliability analysis method for nonnormal variables

Based on fast Markov chain simulation for generating the samples distributed in failure region and saddlepoint approximation(SA) technique,an efficient reliability analysis method is presented to evaluate the small failure probability of non-linear limit state function(LSF) with non-normal variables.In the presented method,the failure probability of the non-linear LSF is transformed into a product of the failure probability of the introduced linear LSF and a feature ratio factor.The introduced linear LSF wh...     

供应链失效风险识别与评估*

供应链风险是影响供应链实践应用的关键因素之一,供应链风险管理是供应链管理的重要内容。采用故障树理论和模糊理论对供应链风险进行了分析,构造了供应链失效风险故障树,该故障树由供应商、制造商、分销商三部分组成;分析了各个部分的失效原因,设计了正态模糊算子,阐述了供应链风险概率计算方法。针对一个供应链实例,采用上述方法对各个要素失效风险进行了定量计算,确定了供应链失效风险等级。     

基于组织变革的企业供应链管理策略

分析了三类供应链危机的征兆,提出企业供应链管理组织变革原则,并通过利丰、富士康、沃尔玛等企业的案例,提出了不同类别供应链管理的组织变革策略.     

构树纤维产业链初探

经过调查研究,围绕构树纤维产业的现状,分析构树纤维产业链的背景,构建构树纤维产业链,并初步提出促进产业链发展的几点建议。     

Comparing the bullwhip effect under different inventory policies in engineering project supply chains

Measuring bullwhip effect is useful for making better controls on production planning and enhancing the supply chain operating efficiency.First,this article establishes the comparative analysis model of bullwhip effect between(s,S)and Periodic Review(PR)inventory policy based on the quantitative bullwhip effect model under different inventories.Then,the impacts of lead time,inventory review time,autocorrelation coefficient,and the number of samples on the gap of bullwhip effect under(s,S)and PR IP are analyzed.The results show that bullwhip effect in PR is more intense than(s,S)inventory policy.Contractors should pay more attention to control bullwhip effect when adopting PR inventory policy to enhance the total operating efficiency of the engineering project supply chains.     

汽车发动机正时链系统设计方法

为深入研究发动机正时链系统,分析了汽车链的服役条件及其主要失效形式,阐述汽车链的选择与计算方法,导出了汽车链垂度和链长的解析表达式,研究了张紧器工作行程以及张紧板、导向板曲率半径和长度的设计准则,提出了汽车发动机正时链系统的设计方法.试验研究表明,该设计计算方法对于自主研发汽车发动机正时链系统具有重要意义.