一种自适应入位固持装置及试验研究

为解决飞机数字化装配中难以对机身大部件增加辅助固持并保持大部件位姿不变的技术难题,提出一种基于气浮和万向球座的大部件位姿跟随固持方法,并设计制造称之为随动定位器的专用柔性工装.结合某工程,进行定位器关键参数的分析计算和相关工艺试验研究,并对油压波动、相关零件磨损对锁紧力的影响以及芯轴自由端关键参数选择与入位可靠性问题进行了研究.结果表明,在芯轴角度偏差较小时,随动定位器可以在确保大部件位姿不被破坏的情况下,实现芯轴的小阻力自适应入位,并可以根据选定的工作油压和配合间隙可靠固持大部件,其性能可以满足工程要求.     

大港歧北斜坡三维地震深层目标精细处理及地质效果分析

歧北斜坡深层沙二、沙三段发育沿岸滩坝、辫状河水道及斜坡扇沉积体系。储层总体比较发育,但是横向变化大,单层厚度薄。现有地震资料横、纵向上地震分辨率低,无法满足砂体追踪和精细储层预测的要求。通过运用叠前反褶积、静校正、能量调整、叠后提高分辨率等技术,并实施处理解释一体化工作模式,处理质量过程控制等方法,使处理成果地震资料在保持地层波组特征不变的情况下,纵横向分辨率有了较大程度的提高,成像特征有了较大幅度的改善,基本上满足了地质需求。利用新处理的资料,通过井震结合,储层地球物理特征分析,在常规波阻抗反演的基础上,利用拟波阻抗反演的方法预测了沙二、三段各油组砂体的空间展布规律。取得了较好的地质效果。     

基于定向扩散的无线传感器网络拥塞控制方法

为了缓解无线传感器网络中多对一通信方式出现的拥塞问题,提出了一种基于定向扩散路由协议的拥塞控制方法.在该方法中,转发节点根据本地的拥塞信息调整速率;sink节点周期地检测网络中的拥塞状态并将拥塞信息通过逐跳的方式反馈到源节点,而源节点根据接收到的反馈信息调节速率.仿真实验表明,该算法能有效地缓解网络中出现的拥塞,保证数...     

水泥工业结构调整的特点及对人才的需求

我国是世界上最大的水泥生产国和消费国.目前水泥工业进入了结构调整阶段.随着我国经济和社会发展水平的提高,人们对资源和环境问题的重视,水泥工业的结构调整出现了新的特点,对人才的需求也出现了新的变化.     

Cure kinetics and mechanical properties of the blend system of epoxy/diaminodiphenyl sulfone and amine terminated polyetherimide-carboxyl terminated poly(butadiene-co-acrylonitrile) block copolymer

The cure kinetics of blends of epoxy resin (4,4’-tetraglycidyl diaminodiphenyl methane; TGDDM)/curing agent (diaminodiphenyl sulfone; DDS) with ATPEI (amine terminated poly-etherimide) -CTBN (carboxyl terminated poly (butadiene-co-acrylonitrile)) block copolymer (AB type) were studied using differential scanning calorimetry under isothermal conditions to determine the reaction kinetic parameters such as activation energy and reaction constants. Final cure conversion decreased with increasing amount of AB in the blends. A diffusion controlled reaction was observed as the cure conversion increased, and the curing reaction was successfully analyzed by incorporating the diffusion control term in the rate equation for the epoxy/DDS/AB blends. The fracture toughness was improved to about 350% compared to that of the unmodified resin at 30% of AB block copolymer. This is attributed to the formation of co-continuous morphology between the epoxy phase and AB block copolymer phase. By increasing the amount of AB, the modulus of the cured blends decreased, which was due to the presence of CTBN rubbery phases.     

Morphology and micromechanical behavior of binary blends comprising block copolymers having different architectures

Morphology and deformation behavior of binary blends comprising styrene/butadiene block copolymers (polystyrene content, Φ_PS∼0.70) having different molecular architectures were studied by means of transmission electron microscopy and tensile testing. In contrast to the binary diblock copolymer blends discussed in literature, the phase separation behavior of the blends investigated was found to be strongly affected by asymmetric molecular architecture. The blends showed macrophase separated grains, in which the structures resembled the microphase morphology of none of the blend components. Unlike the classical rubber-modified or particle-filled thermoplastics, neither debonding at the particle/matrix interface nor the particle cavitation was observed in these nanostructured blends. The microdeformation of the blends revealed plastic drawing of polystyrene lamellae or PS struts dispersed in rubbery matrix and orientation of the whole deformation structures along the strain direction.     

基于高炉TRT系统控制技术的研究与改进

介绍高炉TRT控制系统的改进,以达到节能、降噪、环保的目的.     

Poly(styrene-b-isobutylene-b-styrene) block copolymer ionomers (BCPI) and BCPI/silicate nanocomposites. 2. NaBCPI sol-gel polymerization templates

Polystyrene (PS) blocks in poly(styrene-b-isobutylene-b-styrene) (PS-PIB-PS) block copolymers were partially sulfonated and the acid groups converted to Na⁺SO₃⁻ groups to create ionomers. Then, dimethylacetamide was used to selectively swell the ionic PS domains and the swollen films were exposed to sol-gel reactive tetraethylorthosilicate solutions. (EtO)_4−xSi(OH)_x monomers then permeated films so that sol-gel reactions occurred within/around the ionic PS domains. Environmental scanning electron microscopy/energy dispersive X-ray spectroscopy investigations showed that silicate structures can be incorporated within the interior of the ionomer films. Differential scanning calorimetry studies indicated that there is no variance in the PIB block T_g with respect to ionomer formation, or with respect to silicate loading of the ionomer at low levels, which suggests that the silicate component does not reside in the PIB phase. ²³Na solid state NMR spectroscopy detected isolated Na⁺SO₃⁻ groups as well as aggregated SO₃⁻Na⁺ ion pairs for ‘as cast’ and ‘dry’ non-silicate containing ionomer samples. In a hydrated sample, almost all Na⁺ ions were solvent-separated. AFM analysis showed that phase separation exists, but that the degree of order is significantly less than that for hybrids based on the corresponding benzyltrimethylammonium ionomer. This frustrated morphology was also seen in the results of small angle X-ray scattering experiments. Given the scale of organic/inorganic heterogeneity, these hybrids are properly classified as nanocomposites.     

Influence of block lengths and symmetries of block copolymers on phase behavior of polymer A/polymer B/block copolymer ternary blends

Monte Carlo simulations were used to investigate the compatibilizing effects of diblock copolymers in A/B/A-B diblock copolymer ternary blends and triblock copolymers in A/B/triblock copolymer ternary blends, respectively. The volume fraction of homopolymer A was 19% and was the dispersed phase. The simulation results show that diblock copolymers with longer A-blocks are more efficient as compatibilizers, and symmetric triblock copolymers with a shorter middle block length are easily able to bridge each other through the association of the end blocks. This kind of triblock copolymers have relatively high ability to retard phase separation as compatibilizers.     

Temperature-composition phase diagrams of binary blends of block copolymer and homopolymer

The temperature-composition phase diagrams for six pairs of diblock copolymer and homopolymer are presented, putting emphasis on the effects of block copolymer composition and the molecular weight of added homopolymers. For the study, two polystyrene-block-polyisoprene (SI diblock) copolymers having lamellar or spherical microdomains, a polystyrene-block-polybutadiene (SB diblock) copolymer having lamellar microdomains, and a series of polystyrene (PS), polyisoprene (PI), and polybutadiene (PB) were used to prepare SI/PS, SI/PI, SB/PS, and SB/PB binary blends, via solvent casting, over a wide range of compositions. The shape of temperature-composition phase diagram of block copolymer/homopolymer blend is greatly affected by a small change in the ratio of the molecular weight of added homopolymer to the molecular weight of corresponding block (M_H,A/M_C,A or M_H,B/M_C,B) when the block copolymer is highly asymmetric in composition but only moderately even for a large change in M_H,A/M_C,A ratio when the block copolymer is symmetric or nearly symmetric in composition. The boundary between the mesophase (M₁) of block copolymer and the homogeneous phase (H) of block copolymer/homopolymer blend was determined using oscillatory shear rheometry, and the boundary between the homogeneous phase (H) and two-phase liquid mixture (L₁+L₂) with L₁ being disordered block copolymer and L₂ being macrophase-separated homopolymer was determined using cloud point measurement. It is found that the addition of PI to a lamella-forming SI diblock copolymer or the addition of PB to a lamella-forming SB diblock copolymer gives rise to disordered micelles (DM) having no long-range order, while the addition of PS to a lamella-forming SB diblock copolymer retains lamellar microdomain structure until microdomains disappear completely. Thus, the phase diagram of SI/PI or SB/PB blends looks more complicated than that of SI/PS or SB/PS blends.