一氧化碳对聚丙烯收率、结构的影响

分析研究了Montell(Himont)聚丙烯工艺中CO对聚丙烯收率、产品结构的影响。     

长庆上古生界气层CO2增能压裂工艺

长庆上古气藏物性差,压力系数低,水锁伤害大,采用常规水力压裂,入井液返排困难,气井产量低。在储层改造地质研究的基础上,通过对CO2泡沫压裂技术进行室内攻关,引进开发了CO2泡沫压裂酸性交联技术,优化了CO2泡沫方案设计及现场施工工艺,配套了CO2增能压裂工艺技术。经过现场应用,充分说明了CO2增能压裂是一项行之有效的工艺技术,对于提高单井产量和长庆气田整体开发水平都是有益的。     

轴快流CO2激光器气体压力控制

激光切割对激光功率模式、功率密度和功率稳定性要求很高,采用轴快流CO2激光器时,控制工作气体压力工作在最佳状态并保持其恒定是激光器输出连续、稳定功率的必要条件和关键技术之一。在深入研究激光器工作原理和影响激光输出功率因素的基础上,采用带积分分离的智能PID控制算法对工作气体压力进行调节。该过程控制算法简单实用,可以有效地提高气体压力控制精度,改善功率控制精度和稳定性,并用实验加以验证。     

Design and characterisation of a close-concentric annular reactor for kinetic studies at high temperatures

A novel annular reactor for kinetic studies at high temperature and flow conditions has been designed to keep eccentricity tolerances below 10%. In a previous work, we have shown that it is very important to keep such low eccentricity values in order to collect reliable kinetic data from this type of reactors. As proposed in this study, a modified reactor with the use of a spacer could guarantee an annular duct with low levels of eccentricity. Manufacturing tolerances or deformation effects giving rise to eccentricity can be significantly minimised when using this apparatus. The reactor has been both experimentally and theoretically characterised. Carbon monoxide oxidation was used as a model reaction under mass-transfer limited conditions revealing an eccentricity of ∼5%. With such small eccentricity levels, a concentric annular form can be assumed in the reactor analysis. Simple 1D or 2D models can therefore be inexpensively used in the evaluation of the kinetic data. Also, prior to the design of the annular reactor, a numerical investigation was carried out to clarify the effects of eccentricity, physical properties of the carrier gas and the annular aspect ratio on mass-transfer limitations. Contrary to expectations, a considerable increase in the fuel mass-diffusivity by carrier gas substitution did not change the mass-transfer rates for cases when eccentricity and aspect ratios were high.     

超临界CO2萃取技术及成套装备

介绍了超临界CO2 萃取这一新兴分离技术在工业化装置的工艺流程、化工过程、设备及过程控制系统等方面的内容     

Energy System Consequences When Installing an Advanced Delignification Process

In the pulp and paper industry, during major modernization projects the overall energy system consequences are often not estimated in detail, usually only local energy consequences are taken into account when evaluating possible projects. In this paper, the effects on the overall energy system when installing an advanced delignification process (i.e., a “state‐of‐the‐art” pulp digester and oxygen delignification process) will be presented. Also, the effect such an installation has on the potential for further energy integration is discussed. Furthermore, the CO₂ consequences for both installing such a system and integrating the mill further energy‐wise are presented.     

Spatially resolved infrared spectroscopy: a novel technique for in situ study of spatial surface coverage during CO oxidation on supported catalysts

A spatially resolved infrared (IR) imaging technique to monitor the linear adsorbed CO coverage on supported catalyst surface combining an IR bandpass filter and an IR thermography camera has been developed. Images acquired during the CO adsorption/desorption and ignition indicate that the technique provides an excellent method to image the change of surface coverage with a spatial resolution. It is expected that the combination of infrared thermography with spatially resolved imaging of surface coverage will provide a deeper insight in the dynamics of spatio-temporal patterns on heterogeneous catalysts.     

In situ FTIR spectroscopy on rhodium-exchanged NaX zeolite with different metal dispersion during syngas reaction

In situ FTIR spectroscopy has been applied to study the reason of the different selectivity behaviour of rhodium in the CO hydrogenation reaction in dependence on the different particle size. Several forms of molecularly adsorbed CO are observed, such as linearly- and bridgedbonded CO on metallic rhodium as well as dicarbonyl species with Rh(I) centres formed by oxidation of Rh(0) with protons in presence of CO. Furthermore, non-reactive formate, acetate, and carbonate species are produced as side products of the reaction. The higher selectivity to oxygenates, particularly to methanol, is explained by the existence of multiple-bonded CO present only on small rhodium crystallites. The multiple-bonded CO formed at low temperatures is converted at higher temperatures to the highly reactive formyl species, which is hydrogenated to methanol.     

Application of Acoustic Wave Propagation Analysis Methods for Monitoring a Miscible Mixing Zone in Porous Media

The Biot's acoustics theory, which describes acoustic wave propagation in a porous medium, and computer simulation techniques were utilized to model the behavior of acoustic waves entering and leaving a mixing zone in a miscible displacement in porous media. The results indicate that the angles of waves produced by a mixing zone are equal to angles of waves produced by an abrupt fluid-fluid interface. Therefore, acoustic methods and a relationship between the incident, reflection, and transmission angles can be used to determine the location and thickness of the mixing zone during a miscible displacement process in porous media.