Enzymatic esterification of glycerol II. Lipase-catalyzed synthesis of regioisomerically pure 1(3)-rac-monoacylglycerols

Regioisomerically pure 1(3)-rac-monoacylglycerols are conveniently prepared in high yields (>75%) and in multigram quantities by enzymatic esterification of glycerol in the presence of various lipases(Chromobacterium viscosum, Rhizopus delemar, Rhizomucor miehei) with a variety of different acyl donors, such as free fatty acids, fatty acid alkyl esters, vinyl esters and triacylglycerols, as well as natural fats and oils. All reactions are carried out in aprotic organic solvents with low water content, namelyn-hexane, diethyl ether, tBuOMe or mixtures of these solvents. Essential for the success of these transformations were the following two factors. First, the creation of an artificial interphase between the solvent-immiscible hydrophilic glycerol and the hydrophobic reaction medium by its adsorption onto a solid support. Second, a facile system for the separation of the desired monoacylglycerol from the reaction mixture, coupled with the continuous recycling of acyl donor and undesirable by-products.     

基于KPCA和SVM的火箭发动机试验台故障诊断方法

为了解决液体火箭发动机试验台的故障诊断问题,提出了一种基于核主元分析(KPCA)特征提取和支持向量多分类机(SVM)的故障诊断方法,该方法首先利用核主元分析对试验台标准故障样本进行特征提取,通过特征分析,建立适合于试验台故障状态识别的层次多分类支持向量机,并对其进行训练,然后将试验数据在主元上投影,输入到训练好的支持向量多分类器,对试验台故障状态进行识别.该方法充分利用了核主元分析强大的非线性特征提取能力和支持向量分类机良好的小样本泛化特性,解决了试验台故障诊断中的小样本、非线性模式识别问题.对试验台的试验结果表明,该方法是有效的、可行的.     

锡崖沟瀑布景观工程水力模型试验研究

根据锡崖沟景区规划设计,沿锡崖沟水库溢洪道下部开凿底洞引水,在水库下游红岩大峡谷常年形成20 m宽大瀑布.以满足瀑布流的重力和紊动阻力相似的原则进行了其正态模型设计.通过模型放水试验表明：流量变化对瀑布水流流态影响很大,溢流槽空间狭小,加之上游进口扇形扩散段扩散角偏大,水流扩散不充分,堰顶溢流不均匀,瀑布景观效果差.将模型的溢流堰顶修改为T型复式断面后,顺应了水流的流动特性,在各级流量下均能获得比较好的瀑布景观效果.     

提升检测机构水平、保持体系有效的运行

探讨了检测机构提高管理水平和技术能力的途径,提出了保持管理体系的持续有效运行方法。     

电子剪切散斑技术在木材无损检测中的应用

复合板材及木制品等表面或内部的缺陷对材料性能有很大影响,如何快速准确地对其进行无损检测,并判断缺陷的位置大小是很有意义的.针对松木板试件,通过预置表面和内部隐藏缺陷来近似模拟实际缺陷情况,提出一种基于剪切散斑干涉技术的木材无损检测技术新方法,实现了对松木试件的无损检测.在表面缺陷的检测中讨论了剪切量对结果的影响,利用像素标定的方法,得到直径为6、5、3mm的缺陷信息;在内部隐藏缺陷检测中,借助热加载技术同时引入相移技术使剪切散斑检测技术不仅具有非接触、全场实时检测等特点,而且完成对内部隐藏近表面缺陷的定量无损检测.整个检测过程光路简单,实时快速,实验结果与实际情况符合较好.     

三氯异氰尿酸生产技术研究

对三氯异氰尿酸合成反应过程中的主要工艺参数进行分析和实验研究,并成功地开发出了连续法生产三氯异氰尿酸的新工艺,该工艺和传统工艺相比,具有生产安全、高效、节能的特点。     

Experimental study on temperature stress calculation and temperature control optimization of concrete based on early age parameters

Temperature control curve is the key to achieving temperature control and crack prevention of high concrete dam during construction,and its rationality depends on the accurate measurement of temperature stress.With the simulation testing machine for the temperature stress,in the present study,we carried out the deformation process tests of concrete under three temperature curves：convex,straight and concave.Besides,we not only measured the early-age elastic modulus,creep parameters and stress process,but also proposed the preferred type.The results show that at early age,higher temperature always leads to greater elastic modulus and smaller creep.However,the traditional indoor experiments have underestimated the elastic modulus and creep development at early age,which makes the calculated value of temperature stress too small,thus increasing the cracking risk.In this study,the stress values of the three curves calculated based on the strain and early-age parameters are in good agreement with the temperature stress measured by the temperature stress testing machine,which verifies the method accuracy.When the temperature changes along the concave curve,the law of stress development is in consistent with that of strength.Under this condition,the stress fluctuation is small and the crack prevention safety of the concave type is higher,so the concave type is better.The test results provide a reliable basis and support for temperature control curve design and optimization of concrete dams.     

液态铝合金表面张力快速检测新方法与装置

表面张力是液态合金的重要物性参数之一,铝合金表面张力与其变质处理效果及充型能力等质量参数密切相关,研究铸造铝合金表面张力快速检测方法及装置,对于开发铝合金熔炼质量炉前实时评价系统具有非常重要的实际意义.介绍了一种液态铝合金表面张力快速测试的新方法和新装置,新方法以固定时间内吹入被测液体的气泡个数以及气泡在生长过程中内部压差变化为信息参数,通过回归公式求解表面张力.基于该方法研制的表面张力新型测试装置由单片机测控单元、探头及其锁紧和升降机构、供气单元等部分构成.采用新装置可在5 s内测得铝合金表面张力,且具有较高的测试精度.     

基于漏磁原理的钢丝绳探伤仪影响因素研究

介绍了钢丝绳探伤仪漏磁检测原理,并使用有限元分析方法分析了传感器零件的材料、钢丝绳的提离距离及断丝根数等对基于漏磁原理的钢丝绳探伤仪检测结果的影响。分析结果表明,提离距离、断丝根数等因素对探伤仪检测结果影响较大,断丝角度、深度等因素影响较小。     

Test frame updating in CPM testing of Prolog programs

Category Partition Method (CPM) is a general approach to specification-based program testing, where test frame reduction and refinement are two important issues. Test frame reduction is necessary since too many test frames may be produced, and test frame refinement is important since during CPM testing new information about test frame generation may be achieved and considered incrementally. Besides the information provided by testers or users, implementation related knowledge offers alternative information for reducing and refining CPM test frames. This paper explores the idea by proposing a call patterns semantics based test frame updating method for Prolog programs, in which a call patterns analysis is used to collect information about the way in which procedures are used in a program. The updated test frames will be represented as constraints. The effect of our test frame updating is two-fold. On one hand, it removes “uncared” data from the original set of test frames; on the other hand, it refines the test frames to which we should pay more attention. The first effect makes the input domain on which a procedure must be tested a subset of the procedure’s input domain, and the latter makes testers stand more chance to find out the faults that are more likely to show their presence in the use of the program under consideration. Our test frame updating method preserves the effectiveness of CPM testing with respect to the detection of faults we care. The test case generation from the updated set of test frames is also discussed. In order to show the applicability of our method an approximation call patterns semantics is proposed, and the test frame updating on the semantics is illustrated by an example.