拟稳态法测定气相扩散系数

根据拟稳态一维扩散原理,建立了气相扩散系数的测定装置。在该装置上,测定了8个体系的气相扩散系数,其中CH_2Cl_2-空气,CH_2Cl_2-H_2,CH_3CH_2Br-空气,CH_3Cl_2Br-H_2,CHCl_3-H_2等5个体系的气相扩散系数实验值,迄今尚未见文献报道。实验结果表明,本测试装置稳定性好,实验误差小,实验装置体积小,测试过程较为简便。     

GENERALIZED DERIVATIONS FOR MIXTURES USING THE VIRIAL EQUATION: APPLICATION TO FUGACITY

Calculation of mixture properties using the virial equation of state (VEOS) becomes tedious when the expression contains more than the second virial term. This paper describes a derivation procedure which permits relatively simple extension to any number of virial terms. We have used the fugacity derivation as an example of using the new technique and provide an equation for the fugacity coefficient using any number of terms and any number of components.     

阻燃剂四溴苯酐的热分解动力学研究

用热重-差热分析法对阻燃剂四溴苯酐的热分解过程进行了动力学研究.结果表明四溴苯酐的热分解过程分两步进行.采用Dbyle-Ozawa积分法和Achar-Brindley-Sharp-Wendworth微分法对两步热分解过程分别进行分析,在30种机理函数中进行筛选,得到了四溴苯酐的两步热分解的最概然机理及动力学特性参数.     

Formation of Nanocrystalline Calcia by the Decomposition of Calcite

Formation of nanocrystalline calcia from calcite has been studied in situ via transmission electron microscopy. The crystallographic transformation occurred via two mechanisms: the first is by distortion of the cleaved rhombohedron of calcite, formed by {104} planes in hexagonal coordinates, into a cube. This produced a microstructure of oriented, elongated nanocrystals of calcia with planar boundaries. In the second mechanism, the micrometer-sized parent calcite particles broke up into nano-sized grains as the decomposition began, leading to irregularly shaped, randomly oriented nanocrystals of calcia.     

The Chemistry of Water Treatment Processes Involving Ozone,Hydrogen Peroxide and Ultraviolet Radiation

Advanced oxidation processes are defined as those which involve the generation of hydroxyl radicals in sufficient quantity to affect water purification. The theoretical and (practical yield of OH from O₃ at high pH, 0₃/H₂0₂, O₃/UV and H₂O₂/UV systems is reviewed. New data is presented which illustrates the importance of direct photolysis in the O₃/UV process, the effect of the H₂0₂:0₃ ratio in the O₃/H₂O₂ process, and the impact of the low extinction coefficient of H₂O₂ in the H₂0₂/UV process.     

基于满意度和GA的区间系数多目标规划求解*

在缺乏先验知识的前提下,提出了约束条件的一种满意度,按照遗传算法求解多目标问题的步骤,求出非劣解集;然后根据适应度大小选出最优解;最后算例证明了该算法的有效性和可行性。     

Extending Dynamic Range of Phase Diversity

A method for extending dynamic range of phase diversity (PD) is proposed. The estimating of pupil phase is divided into two steps. Low-order Zernike coefficients of the phase are estimated firstly before all of the Zernike coefficients estimated. The method is based on the assumption that the aberrations of the system are dominated by low order Zernike modes, which is true to most practical situations. The algorithm of Broyden-Fletcher-Goldfarb-Shanno(BFGS) is used in the two steps for optimizing process. Computer simulations are conducted after the theoretical analysis. The result shows that this method can effectively avoid the trap in local minimum during iteration process, and the dynamic range that PD can detect extends from about 2λ to about 4λ.     

摩擦滑移水平隔震支座的性能试验

对一种新型的聚四氟乙烯板摩擦滑移水平隔震支座进行了性能试验,支座由聚四氟乙烯摩擦滑移装置隔震,而并联的水平弹簧使其在震后具有复位能力.试验测定了不锈钢板与聚四氟乙烯摩擦片间的摩擦系数及支座在简谐激励与地震激励下的滞回性能,并对竖向输入动压力时支座的滞回特征进行了测试.结果表明,滑移速度、竖向压力及地震激励的类别是影响摩擦系数与滞回性能的主要因素,为支座理论模型的建立提供了基础.     

Speech-stream detection in short-wave channel based on empirical mode decomposition and higher-order statistics

To capture the presence of speech embedded in nonspeech events and background noise in short-wave non-cooperative communication,an algorithm for speech-stream detection in noisy environments is presented based on Empirical Mode Decomposition (EMD) and statistical properties of higher-order cumulants of speech signals.With the EMD,the noise signals can be decomposed into different numbers of IMFs.Then,the fourth-order cumulant (FOC) can be used to extract the desired feature of statistical properties for IMF components.Since the higher-order cumulants are blind for Gaussian signals,the proposed method is especially effective regarding the problem of speech-stream detection,where the speech signal is distorted by Gaussian noise.With the self-adaptive decomposition by EMD,the proposed method can also work well for non-Gaussian noise.The experiments show that the proposed algorithm can suppress different noise types with different SNRs,and the algorithm is robust in real signal tests.     

氯化钠从水到乙二醇水混合中的迁移性质

在乙二醇和水为混合溶剂中加入NaCl组成三元系,在20~40℃时,改变混合溶剂中乙二醇的质量分数,在w=0%,10%,20%和30%的条件下,测定下列电池电动势AgCl-Ag|NaCl(mA),C2H6O2(w),H2O(1-w)|Na-ISE,(A)确定混合溶剂中AgCl-Ag和Na-ISE电极对在不同温度时的标准电动势,计算了NaCl的迁移性质。结果表明,低温时NaCl在纯水中有较高的吉布斯自由能状态,而在高温时,NaCl在乙二醇和水的混合溶液中处于较高的吉布斯自由能状态。