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991.
Ying Chen Shuichi Iwata Tetsuo Mohri 《稀有金属(英文版)》2006,25(5):437-440
Theoretical investigation of the phase equilibria of the Fe-Ni alloy has been performed by combining the FLAPW total energy calculations and the Cluster Variation Method through the Cluster Expansion Method. The calculations have proved the stabilization of the LIE phase at 1:3 stoichiometry, which is in agreement with the experimental result, and predicted the existence of L1 0 as a stable phase below 550 K; this L1 0 phase has been missing in the conventional phase diagram. The calculations are extended to the Fe-rich region that is characterized by a wide range phase separation and has drawn considerable attention because of the intriguing Invar property associated with a Fe concentration of 65%. To reveal the origin of the phase separation, a P-V curve in an entire concentration range is derived by the second derivative of free energy functional of the disordered phase with respect to the volume. The calculation confirmed that the phase separation is caused by the breakdown of the mechanical-stability criterion. The newly calculated phase separation line combined with the L1 0 and L12Eorder-disordered phase boundaries provides phase equilibria in the wider concentration range of the system. Furthermore, a coefficient of thermal expansion (CTE) is attempted by incorporating the thermal vibration effect through harmonic approximation of the Debye-Gruneisen model. The Invar behavior has been reproduced, and the origin of this anomalous volume change has been discussed. 相似文献
992.
LIU Xingjun WANG Cuiping WEN Mingzhong CHEN Xing PAN Fusheng 《稀有金属(英文版)》2006,25(5):441-447
The Mg-Al-Zn-Y-Ce system is one of the key systems for designing high-strength Mg alloys. The purpose of the present article is to develop a thermodynamic database for the Mg-Al-Zn-Y-Ce multicomponent system to design Mg alloys using the calculation of phase diagrams (CALPHAD) method, where the Gibbs energies of solution phases such as liquid, fcc, bcc, and hcp phases were described by the subregular solution model, whereas those of all the compounds were described by the sublattice model. The thermodynamic parameters describing Gibbs energies of the different phases in this database were evaluated by fitting the experimental data for phase equilibria and thermodynamic properties. On the basis of this database, a lot of information concerning stable and metastable phase equilibria of isothermal and vertical sections, molar fractions of constituent phases, the liquidus projection, etc., can be predicted. This database is expected to play an important role in the design of Mg alloys. 相似文献
993.
萃取预分离法分离富铕中钇矿新工艺 总被引:2,自引:0,他引:2
采用一种新的串级萃取方式--萃取预分离法分离富铕中钇矿的新工艺.原料首先流入十几的三出口预先粗分离工艺,其萃余液La~Gd(TbDy)直接流入Nd/Sm工艺;中间出口流入(Gd)Tb~HoY(Er)Gd~Dy/Ho~LuY细分离工艺;出口负载有机相(Ho)Er~LuY流入Gd~Dy/Ho~LuY的洗涤段.结果表明,新工艺的粗分离工艺将占原料约70%的La~Gd(TbDy)预分离掉,使流入Gd~Dy/Ho~LuY工艺的稀土量减少约70%;由于Gd~Dy/Ho~LuY分组的萃余液GdTbDy含Ho2O3小于0.03%,省去原工艺的GdTbDy/HoY分离;新工艺的处理能力提高30%,酸碱消耗减少20%以上,贵重稀土元素Eu和Tb的存槽量大大减少. 相似文献
994.
995.
996.
对低速走丝电火花线切割机加工某一类工件的4种编程方法作了详尽的分析、比较,总结出一种最优化的方法,可达到减少差错,降低成本,避免重复劳动,提高生产效率的目的。 相似文献
997.
采用简单的溶液还原方法,以聚乙烯吡咯烷酮(PVP,MW=58,000)作为高分子表面修饰剂,用水合肼(50%)作为还原剂,经回流处理,成功地制备出了分散性较好的钻纳米颗粒。利用XRD、TEM、SQUID等实验方法对产物的形貌、物相及磁性进行了表征。结果表明,产物为六方结构。其饱和磁化强度为153emu/g-1.62μB/Co,是体相材料的饱和磁矩的95%,其矫顽力为5174A·m^-1。此方法的优点在于反应条件温和、成本较低,重复性强、产率高且宜于控制。 相似文献
998.
The rigid–plastic integralless–meshless method is applied to the analysis of plane strain backward extrusion. The rigid–plastic integralless–meshless method, based on the moving least squares approximation and the partial differential equations of mechanical equilibrium, is a truly meshless method. In addition, since there is no any integration in the formulation of the rigid–plastic integralless–meshless method, this method is also an integralless method. Compared with the conventional rigid–plastic FEMs, the rigid–plastic integralless–meshless method has some advantages that are briefly no mesh generation, no remeshing and no integration. Compared with BEMs and FBEMs, the rigid–plastic integralless–meshless method is found to have some merits such as sparse matrix, no singularity, no integration and no fundamental solution. Contours of the equivalent strain rate, the equivalent strain, the equivalent stress and the shear stress, etc. of the backward extrusion analysis using the rigid–plastic integralless–meshless method are obtained successfully. 相似文献
999.
利用铸造CAE技术优化铸造工艺 总被引:5,自引:0,他引:5
介绍了铸造商品化软件华铸CAE在优化球铁件铸造工艺中的应用。结果表明,利用铸造CAE技术,可以对不同的工艺方案进行分析、比较及优化,有助于缩短产品试制周期,减少试制损耗,提高企业经济效益和竞争能力。 相似文献
1000.
Pil-Ryung Cha Ho-Seok Nam Dae-Yeong Jeon Jong-Kyu Yoon 《Metals and Materials International》2002,8(1):119-127
This study presents a simple and robust algorithm for the optimal design of the system with coupled complex transport phenomena:
the transport phenomena comprise fluid flow, heat and mass transfer. The (1+1)-Evolution Strategy method is adopted as the optimization method. In order to analyze the transport phenomena in the complex geometry generated
during the optimization procedure, thefinite volume method with a boundary fitted curvilinear coordinate system is used. To confirm the validity of the present method, the optimal
design for the inner shape of the simplified two-dimensionalSubmerged Entry Nozzle in the continuous slab caster is conducted. It is shown that the resulting design of the nozzle is consistent with the purpose
and constraints of the design. 相似文献