Stretchable Gold Tracks on Flat Polydimethylsiloxane (PDMS) Rubber Substrate

A process to fabricate stretchable gold tracks on silicone rubber substrates is studied by XPS, static water contact angle measurement, AFM, and SEM. The process involves several steps: removing uncured oligomers by hexane Soxhlet extraction; pre-stretching the substrate; activating the strained silicone surface by an oxygen plasma treatment; coating the strained substrate with 5 nm titanium and 80 nm gold layers; and finally releasing the sample. The plasma treatment creates a thin brittle silica-like layer that temporarily increases the substrate's surface energy. Indeed, the plasma treatment is followed by a hydrophobic recovery. As a consequence, the delay between plasma treatment and metal deposition has to be reduced as much as possible. The silica-like layer can be nicely observed after release. The entire process allows us to obtain stretchable metallized samples that remain conductive even after an excessive deformation leading to electrical failure.     

Effect of carbon surface oxidation on platinum supported carbon particles on the performance of gas diffusion electrodes for the oxygen reduction reaction

The effect of carbon surface oxidation on platinum supported carbon particles (Pt/C) with nitric acid was investigated by cyclic voltammetry, electrochemical impedance spectroscopy, polarization experiments and chronoamperometry. Cyclic voltammograms, polarization curves and electrochemical impedance spectra showed that the treated catalyst had much larger active surface area and higher ionic conductivity than the untreated catalyst, and provided enhanced performance for oxygen reduction. The formation of acidic groups was examined by IR spectra. The Pt/C surface oxidation had a large effect on the performance of a gas diffusion electrode for oxygen reduction reaction.     

Water and salt permeability of reinforcement polymer‐gel composite membrane

The charged mosaic polymer membrane (CMM) without reinforcement and the composite charged mosaic polymer membrane (CCMM) with reinforcement were investigated in terms of salt and water transport (permeability). The composite charged mosaic polymer membrane (CCMM) with reinforcement showed a unique transport behavior such as preferential material transport L_p and ω. Water permeability coefficient, L_p and salt permeability coefficient, ω were estimated by taking account of active layer thickness of composite polymer gel. The L_p and ω values of CCMM with reinforcement were larger than those of CMM without reinforcement. On the other hand, the reflection coefficient of CCMM, σ, showed negative value, which suggested preferential material transport to solvent transport. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

薄层隔热保温涂料的研制及应用

常规保温材料的研究以提高孔隙率、提高热阻、降低传导传热性能为主,但其对流传热及辐射传热较难降低。当今以传热机理改进保温材料及保温结构是重要发展方向。文章介绍了一种借鉴国外航天工业用高科技绝热涂层的技术思路,并结合国情研制成功的具有高辐射率的薄层隔热保温涂料,它可弥补常规保温材料的不足。该保温涂料以液态涂料方式存在,干燥后的涂层热阻较大,特别是热反射率高,可有效地降低辐射传热,施工方便,涂层薄,无接缝,附着力好,集防水隔热外护于一体。绝热等级为R21.1,热反射度0.79,热辐射率0.83,固含量54％,性能接近国外同类产品水平,成本仅为国外产品的1/4左右。可直接以涂层方式使用,也可与其他多孔保温材料复合构成低辐射传热结构,作为石油石化行业成品油罐及储罐的隔热保温、管道及设备的保冷及屋面隔热保温涂层使用,综合节能效益高。     

郑411块超稠油试油试采工艺技术应用

郑411块沙三段地层疏松出砂、原油粘度高，属中深层超稠油，常规试油试采方法难以突破出油关，采用APR全通径氮气垫测试、地层与井筒复合防砂、水平井配合直井蒸汽吞吐、氮气泡沫封堵调剖和井筒加热举升稠油等配套工艺技术，取得了较好的效果，为中深层超稠油油藏的开发提供了技术思路。     

LB技术制备大面积超薄PMMA抗蚀层的研究

采用自行研制的ＬＢ自动提膜装置，制备出大面积（１０×８ｃｍ２）、高质量的ＰＭＭＡ超薄抗蚀剂膜，并将其用于高分辨率铬掩模版的研制。通过电子束曝光，湿法蚀刻，制作了分辨率优于０．５μｍ，特征线宽０．３８μｍ的４（１００ｍｍ）铬掩模版。     

冷库地坪防冻臌机械通风的传热计算

设计手册中关于使用机械通风防止冷库地坪冻臌的参数（风道直径、间距及长度）仅是推荐值，它忽略了地坪结构、土壤温度和外界空气温度对通风系统节能的影响，因而造成地基土壤的热损失和冷库负荷的增大。从冷库节能和冷库建筑安全使用出发，对采用机械通风防止地坪冻臌进行了传热分析，提出了在传热计算中参数的合理选择和通风系统的设计方法。     

Monitoring of CdTe atomic layer epitaxy using in-situ spectroscopic ellipsometry

Atomic layer epitaxy or ALE has proven to be useful for the growth of epitaxial layers of high uniformity, good quality, and well-controlled thickness. In this study, we have carried out in-situ monitoring during the atmospheric pressure ALE of CdTe on GaAs (100) substrates using spectroscopic ellipsometry (SE). The susceptor temperature, reactant partial pressures, as well as the flow and flush duration for each precursor are crucial process variables for ALE growth. Growth was carried out for 20–25 cycles under different sets of these process conditions during the experiment and in-situ SE was used to verify the presence of layer-by-layer growth, which enabled the quick determination of the process window. We observed ALE growth of CdTe at 300°C, supporting the explanation that the growth of CdTe occurs via a surface catalyzed decomposition of the Te precursor di-isopropyltelluride (DIPTe). Investigation of ALE mode growth behavior for different susceptor temperatures and DIPTe flush times indicated that the growth was limited by competition between desorption and reaction of the adsorbed DIPTe species on the Cd terminated surface.     

格栅式水泥搅拌桩支护在西涌泵站的应用

简介水泥搅拌桩的支护机理,以西涌泵站为例介绍采用格栅式水泥搅拌桩作支护结构的设计及计算方法,指出该技术能较好地解决软湿粘性土地区枢纽深基础开挖问题.     

Kinetics of TSCD zinc oxide nano-layer growth by modified diffuse-interface model

Deposition of zinc oxide films from aqueous solutions containing complex Zn²⁺ ions on soda-lime substrates were studied by two-stage chemical deposition (TSCD) process. It was shown that the film thickness can be controlled by the number of dipping stages. Nano-layers were produced with less than nine times dipping stages. Greater dipping numbers resulted in film thickness exceeding 100 nm. The growth rate obeyed double-stage zeroth order with respect to the concentration and first order with respect to the temperature. This rate was proportional to the difference between the temperature of the hot water and the substrate. Overall activation energy of 17.20 ± 0.42 kJ mol⁻¹ and frequency factor of 2.81 ± 0.07 μm s⁻¹ was determined for ZnO deposition. These values were attributed to two resistances. One resistance corresponded with film heat transfer mechanism. The other was attributed to species attachment to the solid substrate. A modification to the diffuse-interface kinetic model was devised for explanation of the latter. EDAX (electron dispersive elemental analysis), XRD (X-ray diffraction) and SEM (scanning electron microscopy) were used to characterize the layer formed. These methods showed that the product consisted solely of pure elliptical ZnO grains.