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71.
Makikazu Takehana Tomomichi Nishino Katsuyasu Sugawara Takuo Sugawara 《Korean Journal of Chemical Engineering》1996,13(5):538-543
Cobalt-, praseodymium-added zinc oxide varistor was prepared through a wet chemical method followed by sintering with or without
calcination. Changes in grain size, compact density, additives distribution, and voltagecurrent/ capacitance-voltage relations
were investigated for the characterization of the samples sintered at temperatures from 1473 to 1573 K without calcination
or with calcination at 773 K for 2 h. The electrical properties were compared with nhose of samples prepared by two types
of ball mill methods. The wet chemical method provided almost the same additives-distribution profile and less impurities
in comparison with the ball grinding method carried out for 10–100 h. The donor concentration and the potential-barrier height
for the samples were evaluated by Double Schottky Barrier Model. Addition of small amount of both cobalt and praseodymium
in preparation by the wet chemical method was effective for a better nonlinearity relation between voltage and current, which
has potential for a smaller sized varistor. 相似文献
72.
73.
Steady-state and three-dimensional simulations were carried out to study the influences of geometrical parameters on the performance of PEMFC under different hydrating conditions. Flow fields, species transport, transport of water in polymer membrane and movement of liquid water in cathode and anode porous layers were determined, in order to accomplish a complete estimation of ohmic and concentration losses of PEMFC power. The geometrical parameters were thickness of the polymer membrane, cathode catalyst layer as well as gas channel to rib width ratio. Every simulation was made under different relative humidities of inlet flows (50 and 100%) for every change of characteristic length. Results show that the influence of the geometrical parameters on ohmic and concentration losses is of considerable importance. The performance of PEMFC is seriously affected under dehydrating conditions. However, such performance may be considerably improved by using suitable geometrical parameters. Cathode and anode liquid saturation may not only affect the transport of species, but also the polymer electrolyte water content. These results show the importance of simultaneously calculating both the water absorption and desorption through the polymer electrolyte and the liquid saturation in the cathode and anode porous mediums to obtain an actual view of ohmic and concentration losses of the PEMFC performance. 相似文献
74.
75.
Bai-Huan Xu Dong-Ya Sun Cong Ding Xue-Zhong Liu Zi-Jing Xiao 《Materials Research Bulletin》2007,42(9):1633-1639
Layered nanocomposite PEG/WS2, intercalating oligomeric poly(ethylene glycol) (PEG6000) into the tungsten disulfide host galleries, was synthesized using the exfoliation-adsorption technique. X-ray diffraction revealed that the intercalated oligomer within the host galleries is in a double-layer arrangement with an interlayer expansion of about 8.8 Å. The optimum conditions were explored to prepare the single-phase product with a composition of Li0.12(PEG)1.51WS2. Thermal analyses suggested that the resulting material shows good thermal stability, with the decomposition of the interacted oligomeric chains within the disulfide galleries occurring at around 258 °C. Despite high conductivity of the host material, those of the PEG/WS2 nanocomposite were found to be high in the order of 1 × 10−2 S cm−1 at ambient temperature, resulted from the host guest-host charge transfers. 相似文献
76.
Advanced high-energy plasma systems are being used to achieve the benefits of the high-velocity oxy-fuel (HVOF) system without
losing the inherent advantages of plasma for coating of gas turbine parts. MCrAlY coatings play a very important role in the
performance and reliability of gas turbine components. One of the important considerations for next generation of gas turbines,
which have more demanding conditions and need to withstand ever increasing operating temperatures, is that they should possess
very low oxygen content levels in the coating. Low oxygen content coatings are applied by the expensive low-pressure plasma
spray (LPPS)/vacuum plasma spray (VPS) technique for critical components in aero- and land-based gas turbines. This work deals
with the development of low-cost LPPS equivalent coatings (having low oxygen content) using the high-energy high-velocity
plasma spray (HEHVPS) gun and inert gas shroud. A comparison has also been made with CoNiCrAlY coatings by HVOF. 相似文献
77.
Z. Gruba? 《Materials Letters》2007,61(3):794-798
The initial stage of copper electrodeposition on the electrochemically activated assembly of carbon microelectrodes from an acid solution of copper sulfate was investigated using cyclic voltammetry, potentiostatic pulse technique and electrochemical impedance spectroscopy. Analysis of the experimental current transients has been carried out using a non-linear fitting procedure according to the model that takes into account spherical diffusion towards a disc-shaped microelectrode. The higher values of diffusion coefficient in comparison with those observed on planar electrodes were explained with an increased diffusion caused by the electrode geometry. Impedance spectra showed two time constants, the high-frequency related to the charge transfer process and the low-frequency corresponded to the deposit morphology. 相似文献
78.
R. P. Okatov F. K. Nizametdinov B. N. Tsai T. T. Bondarenko 《Journal of Mining Science》2003,39(2):139-142
Using the synthesis of the kinetic concept on solid strength and the Coulomb - Mohr strength theory as the base, the failure conditions taking into account the time and temperature factors are obtained. 相似文献
79.
本文介绍了南钢中板厂将系统工程最优化技术中的随机服务系统理论和可靠性设计方法引入到电气设备的维护和管理工作中,并结合现场实际情况摸索出一套电气设备可靠性保障方法。 相似文献
80.
Higher order elastic constants have been calculated in ZnS at 300 K and 500 K following the interaction potential model. Ultrasonic attenuation, velocity and other related parameters have been calculated using the higher order elastic constants for the different size of the material at 500 K. The size dependency of the ultrasonic properties is discussed in correlation with elastic, thermal and electrical properties. It has been found that the thermal conductivity is the main contributor to the behaviour of the ultrasonic attenuation as a function of the size and the responsible cause of attenuation is phonon-phonon interaction. The semiconducting nature of ZnS film has been achieved with the study of size variation of thermal relaxation time and ultrasonic attenuation. 相似文献