Acidity and basicity of hydrotalcite derived mixed Mg-Al oxides studied by test reaction of MBOH conversion and temperature programmed desorption of NH3 and CO2

Mg-Al hydrotalcites intercalated with five different interlayer anions—CO₃²⁻, SO₄²⁻, Cl⁻, HPO₄²⁻ or terephthalate—were synthesized by either the coprecipitation or ion-exchange method. The structure of the as-synthesized samples and the presence of intended anions in the interlayer gallery of hydrotalcites were determined by X-ray diffraction and FTIR spectroscopy. On calcination at 600 °C the materials were transformed into mixed metal oxides. The kind of the counterbalancing anions present in the parent hydrotalcite influences strongly textural parameters of the obtained Mg-Al oxides. Both temperature-programmed desorption of NH₃ and CO₂, and test reaction of 2-methyl-3-butyn-2-ol (MBOH) conversion were used to determine the acidity and basicity of the samples. The hydrotalcite derived mixed Mg-Al oxides showed the presence of Brønsted and Lewis acid and base sites. However, the strong basic character of the solids caused that acetone and acetylene were observed as the major products of MBOH conversion.     

Fluorescence and IR characterization of epoxy cured with aliphatic amines

Cure reactions of the stoichiometric mixtures of diglycidyl ether of bisphenol A (DGEBA) and two very low molecular weight aliphatic polyether diamines (PED) were studied by using fluorescence and mid- and near-IR spectroscopic techniques. As the cure proceeded, the primary amine groups in PED are converted to the secondary and the tertiary amines. Near-IR spectral analysis was used to calculate the concentration of the three amine groups as a function of cure time. The decrease in the fluorescence intensity of DGEBA at about 307 nm was observed due to more effective quenching of the tertiary amine groups in PED, in comparison to the primary and the secondary amine groups. A large decrease in fluorescence intensity at 75 and 95 °C cure was observed. The amount of all the amine species was estimated from NIR spectra to shed light on the cure kinetics of PPO (polypropylene oxide) in comparison with PEO (polyethylene oxide) epoxy, as well as to explain their fluorescence behavior.The fluorescence intensity changes were correlated to the extent of epoxy reaction obtained by mid- and near-IR spectroscopy.     

An investigation into physicochemical characteristics of ash produced from combustion of oil palm biomass wastein a boiler

Ash derived from combustion of Malaysian oil palm biomass (empty fruit bunches consisting of fibers) was physically and chemically characterized in order to provide a comprehensive understanding of its specific properties in terms of toxicity, compositions and reusability. Principal analyses conducted include particle size distribution, scanning electron microscopy, elemental dispersive X-ray, elemental analysis, toxicity characteristic leaching procedure (TCLP) as well as thermogravimetric, X-ray diffractometry and Fourier-transform infrared analyses. TCLP result indicated that the oil palm ash (OPA) should not be classified as toxic wastes in terms of heavy metal leachability since leachable copper, cadmium, lead and nickel concentrations were detected below the stipulated leachability limits. It was determined that the OPA contained high amount of potassium as well as presence of silica which implied its suitability to be reused as crude fertilizer or cement replacement material.     

From Long Infrared to Very Long Infrared Wavelength Focal Plane Arrays Made with HgCdTe n + n ?/ p Ion Implantation Technology

This paper aims at studying the feasibility of very long infrared wavelength (VLWIR) (12–18 μm) focal plane arrays using n-on-p planar ion-implanted technology. To explore and analyze the feasibility of such VLWIR detectors, a set of four Cd _x Hg_1−x Te LPE layers with an 18 μ cutoff at 50 K has been processed at Defir (LETI/LIR–Sofradir joint laboratory), using both our “standard” n-on-p process and our improved low dark current process. Several 320 × 256 arrays, 30-μm pitch, have been hybridized on standard Sofradir readout circuits and tested. Small dimension test arrays characterization is also presented. Measured photonic currents with a 20°C black body suggest an internal quantum efficiency above 50%. Typical I(V) curves and thermal evolution of the saturation current are discussed, showing that standard photodiodes remain diffusion limited at low biases for temperatures down to 30 K. Moreover, the dark current gain brought by the improved process is clearly visible for temperatures higher than 40 K. Noise measurements are also discussed showing that a very large majority of detectors appeared background limited under usual illumination and biases. In our opinion, such results demonstrate the feasibility of high-performance complex focal plane arrays in the VLWIR range at medium term.     

小波包变换压缩与地震数据处理

探讨了地震数据经小波包变换压缩后对后续处理过程的影响,以及经过某些处理后的数据会对小波包变换压缩产生什么影响等问题。将小波包变换压缩地震数据的结果与快速傅里叶变换压缩地震数据的结果进行了对比,其结果表明:应用小波包变换压缩地震数据,有效信号的损失非常小,压缩比大于快速傅里叶变换的压缩比。在大批量地震数据处理中可以使用小波包变换压缩地震数据。     

Structural properties of phosphorous-doped polycrystalline silicon

The structural properties and hydrogen bonding of undoped and phosphorous doped polycrystalline silicon produced by step-by-step laser dehydrogenation and crystallization technique were investigated using Raman spectroscopy and hydrogen effusion measurements. At low laser fluences, E_L, a two-layer system is created. This is accompanied by the change in hydrogen bonding. The intensity of the Si–H vibration mode at 2000 decreases faster than the one at 2100 cm⁻¹. This is even more pronounced in phosphorous-doped specimens. The laser crystallization results in an increase of the hydrogen binding energy by approximately 0.2–0.3 eV compared to the amorphous starting materials.     

Formation and electronic structure of interface

In the present work the formation of the interface between polycrystalline silver and thin films of titanium oxide was studied with photoelectron spectroscopy (XPS, UPS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS). Titanium oxide was deposited stepwise on 100 nm thick silver films by reactive magnetron sputtering allowing to study the evolution of the interface formation process. The process involves two steps: formation of thin layer of silver oxide and subsequent growth of the TiO₂ film. For better understanding of the silver oxidation process, pure silver films were exposed to a low temperature Ar/O plasma for different time intervals providing a possibility to investigate early stages of the oxide film growth.     

单层开采的圆形定压边界两层油藏压力动态分析

为更好地分析具有越流的多层油藏的压力动态，采用有效井径的概念，在半透壁模型的基础上建立了圆形定压边界、两层越流油藏单层开采时的渗流数学模型。通过拉氏变换得到了拉氏空间中以Bessel函数表示的精确解。数值反演计算结果表明，单层开采的两层油藏与全部打开的两层油藏的压力动态基本相同，都表现为3个阶段：早期是介于两个渗透层之间的均质流动；中间为过渡段，导数曲线出现下凹特征；晚期表现为整个油藏的均质特征。随着边界距离的增加，压力导数值趋近于0．5。半透率越大过渡段出现得越早。导数曲线下凹程度越小；储容比越大导数曲线峰值越小，导数曲线下凹程度越小；随着两层渗透率比值变小。过渡段变短，导数曲线下凹程度变小。图1参9     

小波提升算法及其在图像处理中的应用

小波提升算法是一种新的双正交小波构造方法，通过预测算子，确定高频信息，并初步确定低频信息，然后通过更新算子，对初步确定的低频信息进行修正，从而确定低频信息。它在空域对信号进行变换，完成了对信号频域的分析。在图像处理中，基于离散小波变换的提升算法比传统的卷积算法运算简单，实时性好，易于实现，因而被新一代图像压缩标准JPEG2000所采用。文中简要介绍了小波提升算法的原理，分析了其特点，并介绍了JPEG2000标准中采用的W5／3、D9／7两种小波的提升格式和实现算法。     

Quasi-Chun-Ching Shih''''s Fractional Fourier Transform with Periodicity of 2,3 and M

Based on Chun-Ching Shih's idea, the basic transform was substituted and the quasi-ChunChing Shih's fractional Fourier transform with periodicity of 2, 3 and M was deduced. The two former transforms and the Chun-Ching Shih's fractional Fourier transform were only the particular cases of quasiChun-Ching Shih's fractional Fourier transform with periodicity of M.