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61.
62.
The use of activated carbon beds for the removal of natural humic and fulvic substances found in water supplies, has recently received considerable attention in water treatment operation (Lee et al., 1980; Le Cloirec et al., 1983). Moreover, the use of carbon adsorption for the reduction of haloform precursors (Anderson et al., 1981) and trihalomethanes produced by chlorination process, has contributed to a comprehensive investigation of adsorption characteristics of natural organic compounds (McCreary and Snoeyink, 1981). Many recent works showed the influence of adsorption system characteristics, such as pH, salt type, salt concentration and ionic heterogeneity in multicomponent adsorption systems, on the removal efficiency of humic and fulvic substances by activated carbon (McCreary and Snoeyink, 1980; Randtke and Jepsen, 1982; Weber et al., 1983). The purpose of this study is to examine the effect of a main component of domestic detergents, sodium triphosphate (STP), on the adsorptive capacities of powdered activated carbon (PAC) for commercially supplied humic acids, at different pH values in distilled water. Also, the effect of STP concentration and pH on the adsorption affinity of the PAC for humic acids, is discussed in relation with electrokinetic properties of carbon particles (zeta potential measurements).A first batch equilibrium study (Figs 1 and 2), showed an effective enhancement of adsorption capacity for humic acids as a function of STP concentration, in a non buffered media (pH of distilled water, close to 5.0). For example, visible absorption analysis of humic acids indicates an increase of 93% (500 mg l?1 PAC) and 133% (1000 mg l?1 PAC) in the carbon adsorption efficiency for a STP concentration from 0.2 to 1.0mM. A second batch equilibrium study (Figs 3 and 4) led to adsorption isotherms for humic acids in distilled water, as a function of STP concentration and initial pH value of the non buffered multicomponent system. Freundlich isotherms showed an increase in the adsorption capacity of the PAC for humic acids, with a decrease in pH and an increase in STP concentration. However, the adsorption capacity for humic acids is quite reduced at high pH values in presence of STP, in comparison with results obtained with distilled water.Electrokinetic measurements on PAC suspensions (Fig. 5) indicates that both humic acids and STP induce a negative variation of the zeta potential of carbon particles. In such a binary system, the zeta potential is a linear function of the pH; the negative surface charge of the carbon increasing with an elevation of pH (Fig. 6). Therefore, it appears that some adsorption of triphosphate polyanion from solution could occur, contributing then to the apparent negative surface charge of PAC particles.It has been previously showed that the type of anion in sodium salts, had little effect on the enhancement of adsorptive capacities of activated carbon for humic substances (Lafrance and Mazet, 1985), due to Na+ ions. However, adsorption of TP anions on the carbon surface may produce a source of repulsive charges, unfavourable to the co-adsorption of humic acids as the pH of the binary system reach more basic conditions. The influence of possible electrostatic interactions between adsorbates at the carbon surface, on the adsorption efficiency for humic acids, could then be studied by zeta potential measurements of PAC particles during the adsorption process. 相似文献
63.
A direct measurement of the dynamics of electrons in the X6 valley for a GaAs crystal by time-resolved absorption spectroscopy is reported for the first time. IR picosecond probe pulses were used to monitor the growth and decay of the population in the X6 valley subsequent to excitation by a 527 nm pump pulse. The intervalley X6→Γ6, L6 scattering time tx of 0.70 ± 0.50 ps is determined and the crossection for the X6→X7 transition is estimated to be 1.8 × 10−16 cm2. 相似文献
64.
W. Fischer 《Progress in Organic Coatings》1993,22(1-4):181-193
Corrosion protection of organic coated steel is determined by free corrosion potential measurements and impedance spectroscopy. The results are classified by means of very basic considerations and evaluation figures are developed. These electrochemical data are correlated with the extent of the corrosion for each coating system. The evaluation figures are used for ranking coating systems and this ranking is correlated with the ranking with reference to the results of standardized and exposure tests. 相似文献
65.
感覆盖率是WSN系统中重要的性能指标之一。Sink节点的移动性能提高系统的传感覆盖率,人工势场能描述普通节点与Sink节点之间的关系。提出了一种利用人工势场方法有效的Sink节点移动控制策略,通过Sink节点的移动能够提高系统的传感覆盖率。普通节点搜集的数据能通过多跳的方式传送给Sink节点。在最初的随机部署之后,由人工势场产生的力迫使移动Sink节点移动到整个环境中的平衡点以获得更高的传感覆盖率。在整个算法执行过程中无需事先了解环境的情况,此方法能在实时的环境中采用。给出了具体的算法步骤,最后利用一个仿真实例对控制效果进行了说明。 相似文献
66.
67.
制备了基于一种简单的金属铜配合物2,4-二羟基苯甲酸铜(Ⅱ)(Cu(Ⅱ)DHBA)为载体的PVC膜硫氰酸根离子(SCN-)选择性电极。该电极在1.0×10-1~1.0×10-6mol/LSCN-浓度范围内呈现斜率为-59.5mV/dec的近Nernst电位响应,检测下限为9.1×10-7mol/L。利用紫外可见光谱及交流阻抗技术初步探讨了电极对SCN-呈现的选择性电位响应机理。该电极作为直接电位分析法的指示电极,成功运用于实验室废水中硫氰酸盐含量的测定。 相似文献
68.
Operational optimization of a building-level
integrated energy system considering
additional potential benefits of energy
storage 下载免费PDF全文
Sai Liu Cheng Zhou Haomin Guo Qingxin Shi Tiancheng E. Song Ian Schomer Yu Liu 《电力系统保护与控制》2021,6(1):55-64
As a key component of an integrated energy system (IES), energy storage can effectively alleviate the problem of
the times between energy production and consumption. Exploiting the benefits of energy storage can improve the
competitiveness of multi-energy systems. This paper proposes a method for day-ahead operation optimization of a
building-level integrated energy system (BIES) considering additional potential benefits of energy storage. Based on
the characteristics of peak-shaving and valley-filling of energy storage, and further consideration of the changes in
the system’s load and real-time electricity price, a model of additional potential benefits of energy storage is
developed. Aiming at the lowest total operating cost, a bi-level optimal operational model for day-ahead operation
of BIES is developed. A case analysis of different dispatch strategies verifies that the addition of the proposed
battery scheduling strategy improves economic operation. The results demonstrate that the model can exploit
energy storage’s potential, further optimize the power output of BIES and reduce the economic cost. 相似文献
69.
The voltage-gated proton channel, Hv1, also termed VSOP, was discovered in 2006. It has long been suggested that proton transport through voltage-gated proton channels regulate reactive oxygen species (ROS) production in phagocytes by counteracting the charge imbalance caused by the activation of NADPH oxidase. Discovery of Hv1/VSOP not only confirmed this process in phagocytes, but also led to the elucidation of novel functions in phagocytes. The compensation of charge by Hv1/VSOP sustains ROS production and is also crucial for promoting Ca2+ influx at the plasma membrane. In addition, proton extrusion into neutrophil phagosomes by Hv1/VSOP is necessary to maintain neutral phagosomal pH for the effective killing of bacteria. Contrary to the function of Hv1/VSOP as a positive regulator for ROS generation, it has been revealed that Hv1/VSOP also acts to inhibit ROS production in neutrophils. Hv1/VSOP inhibits hypochlorous acid production by regulating degranulation, leading to reduced inflammation upon fungal infection, and suppresses the activation of extracellular signal-regulated kinase (ERK) signaling by inhibiting ROS production. Thus, Hv1/VSOP is a two-way player regulating ROS production. Here, we review the functions of Hv1/VSOP in neutrophils and discuss future perspectives. 相似文献
70.
针对上肢外骨骼控制信号产生与外部设备响应存在时间滞后导致脑机接口(BCI)系统实时性差的问题,采集被试手部自主抓握前运动相关皮质电位(MRCP) ,提出基于非线性复杂度特征样本熵 (SampEn)与线性幅值特征融合算法的手部运动意图预测方法. 从时频、神经复杂度分析不同大脑状态之间存在的差异,通过特征融合实现对手部抓握运动意图的预测. 基于特征融合意图离线预测准确率最高可达88.46%,可以在人体手部自主运动发生时刻?1 400 ms实现对手部运动预测. 与平静时期手部静止状态相比,被试产生手部抓握运动意图时脑电信号的功率谱与复杂度均产生明显变化,为基于手部运动意图预测提前驱动机器人实现人机协同提供控制策略. 相似文献