Thermodynamic assessment of MCl–YCl3 (M=Na,K, Rb,Cs) systems

Thermodynamic properties and phase diagrams of the MCl–YCl₃ (M=Na, K, Rb, Cs) systems were reassessed by using the CALPHAD method with the latest phase diagram data. A two-sublattice ionic solution model (M⁺)_P(Cl⁻, ${\mathrm{YCL}}_6^{3-}$, YCl₃)_Q reflecting the ionic behavior of the components was adopted to describe the liquid phase in the systems. A new set of optimized model parameters was found, and the calculated phase diagrams and enthalpies of mixing have good agreement with experimental data. The calculated liquidus near to YCl₃ side agrees much better with experimental data compared with previous work. In consideration of high and low temperature modifications as well as stability of intermediate compounds, Gibbs energies of formation of these compounds evaluated in the present work are more reasonable.     

An understanding of high entropy alloys from phase diagram calculations

The concept of High Entropy Alloy (HEA) is understood from the point of view of phase diagram calculation. The role of entropy of mixing on the phase stability is discussed for both ideal and non-ideal solid solution phases. The relative stability of a solid solution phase and line compounds is illustrated using hypothetical systems. Calculated binary and multicomponent phase diagrams are used to explain the phenomena observed experimentally for HEAs. The potential of using the CALPHAD (CALculation of PHAse Diagrams) approach in aiding the design of alloys with multiple key components is also discussed.     

Experimental investigations and thermodynamic modelling of KCl–LiCl–UCl3 system

Experimental investigations and Gibbs energy modelling of KCl–LiCl–UCl₃ system employing CALPHAD method are reported. Gibbs energy modelling of the subsystems KCl–UCl₃ and LiCl–UCl₃ was carried out primarily using phase diagram data from the literature. For the Gibbs energy modelling of the KCl–LiCl subsystem, new phase boundary data corresponding to four terminal compositions $(x_{\mathrm{LiCl}}=0.03$, 0.05, 0.95 and 0.97) obtained through differential thermal analysis data along with thermochemical and phase diagram data from the literature were used. Thermal analysis was also carried out for KCl–LiCl eutectic mixture containing small amounts of UCl₃ $(x_{{\mathrm{UCl}}_3}=9.03\times {10}^{-3}$ and $1.79\times {10}^{-2}$). The liquidus temperatures for these compositions were found to be 637 K and 674 K. Electromotive force data for dilute solutions of UCl₃ in the KCl–LiCl eutectic melt, measured in the temperature range 708–833 K in the present work, were found to be in good agreement with the literature data. These data were also used as input for the Gibbs energy modelling of the KCl–LiCl–UCl₃ system. In order to improve the quality of the resulting Gibbs energy functions of the quasibinaries and the quasiternary, enthalpies of mixing of the corresponding melts estimated using an empirical correlation based on surrounded-ion model were also used as input. Finally, the generated Gibbs energy functions were used to compute phase equilibria.     

控制图在复极电解槽控制中的应用

根据离子膜制碱工艺的特点，与控制图的应用理论相结合，寻找控制对象并选择控制图的类型。通过选择合适的工艺参数，使用控制图的数据处理技术对实际数据进行处理，绘制出控制图，利用参数波动符合正态分布的特点对控制图的波动情况进行分析，用来诊断电解槽运行的受控情况。     

Tabu-based GIS for solving the vehicle routing problem

Besides being a hard combinatorial problem, the VRP is also a spatial problem. Hence, effective decision making in this field strongly requires the integration of GIS and optimization systems (GIS-O). This article integrates GIS and optimization tools for solving the vehicle routing problem with loading and distance requirements (DCVRP). A general outline of the multi-step integration is pointed out showing the interaction of the GIS and the spatial optimization according to the loose coupling strategy. The computational performance of the TS-VRP algorithm for the DCVRP turned out to be quite efficient on both computation time and solution quality. The Tunisian case study well illustrates the incentive behind using such a spatial decision support system that allows the management of the problem from the data acquisition to the visualization of possible simulation scenarios in a more realistic way.     

基于面向服务的泥石流数值模拟通用平台

对当前泥石流模拟系统的单一性缺点进行了研究,提出了面向服务的泥石流数值模拟的通用平台思想。以有限差分模型为基础,采用面向服务的思想,设计了系统 C/S模式的技术方案并完成了整个系统的设计和实现。经过香港滑坡地形图的验证,证明了本通用平台的可行性和有效性。     

粉体高浓度输送相图

根据以固体质量流速和固体装入量为参数的Zenz相图（即压降与表观气速的关系图）和洪江等人的模型[6]，对粗聚氯乙烯和细PVC颗粒的水平气力输送进行了合理的预测     

基于工作流和智能手机的城市综合管理平台

为适应现代城市综合管理的需要,提高城市管理水平,提出利用GIS技术的二三维一体化联动提高管理平台可视化;基于工作流的管理使事件处理更加自动化;利用智能手机的方便使管理人员与系统进行动态交互;利用模糊数学提高任务完成质量评价的科学性。整个平台在Windows7下进行开发,基于B/S(浏览器/服务器)和C/S(客户端/服务器)结合的架构,运用JavaEE、工作流、模糊数学、无线通信、视频融合等技术,实现平台对交通灯、人员、车辆、消防、事件和任务的管理。     

Cr^3＋=Al2（WO4）3晶体生长助熔剂体系的研究

本文用DTA和XRD法研究了Na_2O-Al_2O_3-WO_3三元系中的Al_2(WO_4)_3-Na_2WO_4截面的相平衡关系。在这截面中发现一新化合物AlNa_3(WO_4)_2。以45mol％Na_2WO_4为助熔剂生长了Cr~(3+):Al_2(WO_4)_3晶体。