R407系列产品专利研究

介绍了杜邦公司R407系列产品专利申请、授权和专利权有效期情况。     

超磁致伸缩作动器的率相关Hammerstein模型与H∞鲁棒跟踪控制

利用Hammerstein模型对超磁致伸缩作动器（Giant magnetostrictive actuators,GMA）的率相关迟滞非线性进行建模,分别以改进的 Prandtl-Ishlinskii（Modified Prandtl-Ishlinskii）模型和外因输入自回归模型（Autoregressive model with exogenous input,ARX）代表Hammerstein模型中的静态非线性部分和线性动态部分,并给出了模型的辨识方法. 此模型能在1～100Hz频率范围内较好地描述GMA的率相关迟滞非线性. 提出了带有逆补偿器和H∞鲁棒控制器的二自由度跟踪控制策略,实时跟踪控制实验结果证明了所提策略的有效性.     

微波辐射下一步合成2-甲氧基-3-氰基-4-芳基吡啶和2-氨基-3-氰基-4-芳基吡喃衍生物

2，5－双亚苄基环戊酮与丙二腈在氢氧化钠－甲醇或哌啶－乙醇中，经微波辐射一步合成了2－甲氧基－3－氰基－4－芳基吡啶和2－氨基－3－氰基－4－芳基吡喃衍生物，反应在3－9mi内完成，产率56％－78％。     

2,2′-oxo-1,1′-azobenzene: microbial transformation of rye (Secale cereale L.) allelochemical in field soils byAcinetobacter calcoaceticus: III

Acinetobacter calcoaceticus, a gram-negative bacterium isolated from field soil, was found to be responsible for the biotransformation of 2(3H)-benzoxazolinone (BOA) to 2,2-oxo-1,1-azobenzene (AZOB). Experiments were conducted to evaluate the transformation of BOA to AZOB by this microbe in sterile and nonsterile soil. Transformation studies with soils inoculated withA. calcoaceticus indicated that the production of AZOB increased linearly with the concentration of BOA in sterile soil and showed a quadratic trend in nonsterile soils. This also indicated that all soil types studied for the transformation experiments might containA. calcoaceticus capable of the conversion of benzoxazolinones.     

H4SiW12O40-PAn催化剂催化合成苯甲醛乙二醇缩醛

报道了以自制的H4SiW12 O40 (硅钨酸 ) -PAn (聚苯胺 )为催化剂 ,通过苯甲醛和乙二醇为原料合成了苯甲醛乙二醇缩醛。实验表明 :合成苯甲醛乙二醇缩醛适宜反应条件为 :n(苯甲醛 ) /n(乙二醇 ) =1 /2 .0 ,催化剂用量为反应物料总质量的 1 .0 % ,环己烷为带水剂 ,反应时间 1 .0h。上述条件下 ,苯甲醛乙二醇缩醛的收率可达 86.7% .     

气固相氢氟化催化剂的研究

对于气固相氢氟化反应制备七氟丙烷的催化剂,进行了系统的研究。采用浸渍法制备催化剂,当催化活性组分Ａ为载体的８．５％～１０％,组分Ｃ２为１．０％～２．５％、二者之和为１１％时,达到了较佳的催化性能,将其应用于由六氟丙烯制备七氟丙烷时,在反应温度≥２１０℃时,粗品气中的Ｆ－２２７含量≥９８．５％。     

基于IP网络的河北质监三级视频会议系统建设研究

随着Internet飞速发展,网络带宽的提升,特别是H.323协议的推出,使视频会议系统得到了空前发展。为了加快信息化建设,提高各单位的工作效率,河北省质监局在原有的省市两级视频会议基础上,扩展到全省184个县区局单位,建设了省市县三级视频会议系统。     

A vibrational study of the activation sequence of C–H and C–C bonds of isobutene and 1-butene on Mo(110) and (4 × 4)-C/Mo(110) surfaces

The thermal decomposition pathways of isobutene and 1-butene on both Mo(110) and 4 × 4-C/Mo(110) surfaces have been studied using high-resolution electron energy loss spectroscopy (HREELS) in order to highlight the substantially different activities of these two surfaces towards the cleavage of C–H and C–C bonds. On clean Mo(110), the CH₂ group of isobutene decomposes upon heating to 150 K, producing either a /-bonded isobutenylidene [(CH₃)₂CCH] species or a 1,1-di-/-bonded isobutenyl [(CH₃)₂CC] species. Upon further heating, extensive C–H bond scission occurs to form hydrocarbon fragments which do not contain CH₃ or CH₂ groups, but appear to have largely intact carbon skeletons. By contrast, isobutene is molecularly adsorbed on the carbide-modified surface at 150 K. Further heating produces isobutylidyne [(CH₃)₂HCC] by 300 K, which subsequently decomposes via C–C bond scission to generate surface methyl groups. The different activation sequence of the C–H and C–C bonds of isobutene on clean and carbide-modified Mo(110) surfaces is also qualitatively confirmed by comparative studies of 1-butene on the two surfaces.     

On the catalytic C-H activation of some silicon dioxide overlayers on thin metal film systems — An observation on the isokinetic effect

Kinetic data on the exchange reaction betwee hexane and deuterium have recently been reported by Maier and coworkers [1]. The reaction was catalysed by a series of platinum or rhodium systems, some of which had the property that the upper surface was shielded by a silica overlayer. The data are reinterpreted to indicate an isokinetic temperature of 580 K. This observation indicates that all the catalysts behave in a similar manner, which means that the exchange reaction does not require a free metal surface.     

Noble-free potassium-bimetallic catalysts supported on beta-zeolite for the simultaneous removal of NOx and soot from simulated diesel exhaust

This paper deals with the activity of the KCu and KCo catalysts supported on beta-zeolite for the simultaneous NO_x/soot removal from a simulated diesel exhaust, containing C₃H₆ as model hydrocarbon. In order to reveal the effect of potassium, the corresponding monometallic catalysts (Co/beta and Cu/beta) were analyzed and different potassium loadings were used. In addition, for comparative purpose, the performance of a platinum based catalyst (Pt/beta) was studied. All noble-free catalysts show, at 450 °C, a high activity for the simultaneous NO_x/soot removal. Among them, K1Cu/beta presents the best global performance at 350 and 450 °C achieving a high soot consumption rate (comparable to platinum catalysts) and the highest NO_x reduction. In contrast to platinum catalysts, K1Cu/beta has the advantage that the main reaction products are N₂ and CO_2.