Effect of powder characteristics on Cr internal oxidation for preparation of Cr2O3/Cu composite

Abstract

Cr O₃/Cu composite was prepared by the internal oxidation of Cu–Cr pre-alloyed powders formed by high energy milling. Effects of milling time on the internal oxidation characteristics of Cu–Cr pre-alloyed powders were also discussed in this paper. The results indicate that the degree of the internal oxidation continually increases with prolonged milling time. At the initial stage, external oxidation rather than internal oxidation occurs, resulting in coarse Cr₂O₃ particles. With further milling, the internal oxidation becomes more complete and the sizes of Cr₂O₃ particles also become finer and well distributed. The properties of the composite are therefore improved. A high quality composite specimen from Cu–1·0Cr pre-alloyed powders after 40 h milling was prepared by the internal oxidation process. The Cr₂O₃ particles with an average size of 2–5 μm in diameter and about 5–10 μm in particles space were found by a microstructure examination, and they were uniformly dispersed in the Cu matrix.     

Isothermal and thermomechanical fatigue behaviour of a high temperature titanium alloy

Abstract

Isothermal and thermomechanical fatigue (TMF) behaviour (including cyclic stress response and number of cycles to failure) of a Ti – 5.6Al – 4.8Sn – 2.0Zr – 1.0Mo – 0.32Si – 0.8Nd (wt-%) hightemperature titanium alloy was examined. The purpose of the present investigation was to understand the effect of temperature fluctuation on the cyclic behaviour and fatigue life of this alloy and to test the suitability of lifetime prediction based on isothermal laboratory data. The results indicated that both the level of peak stress and fatigue life were decreasing with increasing test temperature from 400°C to 650°C in isothermal fatigue (IF) tests. In TMF tests run between 400°C and 600°C, the peak stresses corresponding to 600°C coincide well with that found in IF tests run at 600°C, while a slight increase in cyclic hardening was found for peak stress corresponding to 400°C compared to that found in a 400°C/IF test. This increase in cyclic hardening became more pronounced when the maximum temperature increased to 650°C. Fatigue life in 'out of phase' (OP) condition was found to be shorter than under an equivalent 'in phase' (IP) condition, and this gap increased with decreasing mechanical strain amplitude. The results indicate that lifetime prediction based on isothermal laboratory data may lead to non-conservative results if thermal fluctuations are present in components made of the present alloy.     

Effect of process parameters on microstructural variables of a commercial TC6 titanium alloy disc

Abstract

The interaction between the deformation behaviour and the microstructure evolution is the main characteristic in the forging process of titanium alloy and this interaction is researched using finite element (FE) simulation. Coupled simulation of deformation behaviour with microstructure evolution has been carried out by means of a new constitutive equation presented by Li et al. (Mater. Sci. Technol., 2004, 20, 1256–1260). The effect of deformation temperature, hammer velocity,height reduction and shear factor on the microstructure variables, including grain size and volume fraction, has been studied in the forging process of the TC6 titanium alloy disc with deformation temperatures of 880–940°C, hammer velocities of 1·2–12 000 mm min^?1 and shear factor (m) of the friction of 0·1–0·4. The simulated results show that deformation temperature, hammer velocity and height reduction have a significant effect on themicrostructure evolution and this effect is more significant on the microstructure evolution in hot forging than that in isothermal forging. The simulated results are in good agreement with the experimental results.     

Surface relief in dynamically embrittled low alloy steels with varied flow stress

Abstract

The dynamic embrittlement of low alloy steels with two different flow stresses at a low partial pressure of oxygen is presented. The low alloy steel with a higher flow stress experienced a relatively higher degree of dynamic embrittlement compared with the steel with a lower flow stress. Pronounced surface relief originated on the surface of intergranular facets, and is defined in terms of a surface deformation parameter determined from atomic force microscopy.     

Directional solidification of Ni base superalloy IN738LC to improve creep properties

Abstract

The high Cr, Ni base superalloy IN738LC has been directionally solidified on both laboratory and industrial scales using Bridgman and liquid metal cooling (LMC) methods respectively. In the Bridgman experiments, cylindrical rods were grown using a graphite chill with temperature gradient G = 5·0 K mm^-1 and a water cooled copper chill with G = 8·5 K mm^-1, and a wide range of withdrawal rates of R = 60, 120, 240, 600, and 1200 mm h^-1. In the LMC rigs, several turbine blades were grown using a wide range of withdrawal rates of R = 120, 225, 330, 420, and 630 mm h^-1. Grain and dendritic structures in both cylindrical and turbine blade specimens were evaluated in longitudinal and transverse directions. Dendritic segregation of rods was determined with SEM as a function of processing parameters. Some specimens were given a two stage heat treatment followed by tension tests at 25 and 650°C and creep tests at 152 MPa and 982°C, 340 MPa and 850°C, and 586 MPa and 760°C. It was shown that at R = 600 mm h^-1 with water cooled copper chill, directionally solidified rods with a well orientated dendritic structure and better segregation pattern gives higher tensile properties at 25°C and creep properties at 340 MPa and 850°C. Tension and creep tests of turbine blades showed that although the yield and tensile strength of directionally solidified specimens are in the range of conventionally cast ones, the creep properties of the blades have been significantly improved using the LMC process.     

Effect of preheat treatment on ingot structure and recrystallisation of brass component of rolling texture in hot rolled AA 5182

Abstract

Two different preheating treatments were used to vary the Al₆ Mn dispersoid characteristics in AA 5182. High temperature followed by slow cooling produced coarse, needlelike dispersoids which allowed rapid recrystallisation following hot rolling, whereas a low temperature preheat produced afine dispersion of low aspect ratio particles which retarded recrystallisation. Long, unrecrystallised bands persisted in the hot rolled material subected to the low temperature preheat even after holding for 24 h at the final pass temperature. Micro-orientation determinations within the bands showed that they were predominantly of the brass (Bs) orientation, {110}〈112〉, confirming the results of X-ray bulk texture analyses. The results are considered conclusive evidence of the widely reported higher resistance to recrystallisation of the Bs orientation compared with other orientations in rolled high stacking fault energy fcc metals. The Bs oriented bands could be removed by annealing at a temperature substantially greater than that experienced in the final hot rolling pass.

MST/1475     

Interfacial precipitation in hot isostatically pressed diffusion bonds of 17-4 PH stainless steel

Abstract

The embrittlement of hot isostatically pressed (hipped) diffusion bonds manufactured from 17-4 PH stainless steel has been investigated by Auger electron spectroscopy (AES) of in situ fracture specimens. Depth profiling by AES has revealed copper precipitation at the interface of the diffusion bond. This precipitation, up to a few monolayers in thickness, occurs during the ramp up to temperature and pressure of the hot isostatic pressing (hipping) cycle and is not readily removed by subsequent heat treatment. This effect is explained in terms of the metallurgical characteristics of copper within the steel. Results suggest that the extent of the precipitation decreases with increasing process temperature. In the case of PH 13-8 Mo stainless steel, where the precipitation hardening phase is NiAl, the interface is weakened by sulphur segregation and the formation of oxide particles.     

Effects of Temperature and Loading Rate on the Mechanical Properties of a High Temperature Epoxy Adhesive

The variation of the mechanical properties of adhesives with temperature and strain rate is one of the most important factors to consider when designing a bonded joint due to the polymeric nature of adhesives. It is well known that adhesive strength generally shows temperature dependence. Moreover, in many structural applications, the applied loads can be dynamic and the design of the joint requires the knowledge of the high loading rate mechanical behaviour of the adhesive. In this study, the combined effect of the temperature and test speed on the tensile properties of a high temperature epoxy adhesive was investigated. Tensile tests were performed at three different test speeds and various temperatures (room temperature (RT) and high temperatures (100, 125 and 150°C)). The glass transition temperature (T _g) of the epoxy adhesive investigated is approximately 155°C. The ultimate tensile stress decreased linearly with temperature (T) while increased logarithmically with the loading rate, which is in the accord with the Airing's molecular activation model.     

Tribological roles of nanometre thick Ag layers on Hertzian macroscopic contacts

Abstract

Tribological performance of subnano to nanometre thick Ag layers deposited on Si(111) has been examined under ultra high vacuum conditions to understand effect of surface thin layers on the wear and friction characteristics. The slider was made of a diamond sphere 3 mm in radius. As a result, a minimum of the coefficient of friction 0·007 was observed over a film thickness range of 1·5–10 nm. The sliding planes were observed by Auger electron spectroscopy, reflection high energy electron diffraction (RHEED), synchrotron orbital radiated X-ray diffraction (SOR-XD) and scanning tunnelling microscopy (STM). No worn particles were found after 100 reciprocal sliding cycles, and the very low friction coefficient lasted for at least 1000 sliding cycles. Observations using STM on the sliding surfaces confirmed that the stacking Ag(111) planes slid. The SOR-XD and RHEED verified that a tribo-induced orientation of polycrystal film occurs as Ag(111) sliding planes are oriented parallel to the sliding direction on the track. The friction force of as deposited epitaxial Ag films as a function of the load was constant. On the other hand, in the 5 nm thick Ag films annealed to form complete single crystals, the friction coefficient showed a strong load dependency. At a load of 250 mN or more, the annealed films showed a low and static friction coefficient. These results suggested that the shearing resistance of nanometre thick Ag layers exhibits a strong anisotropic performance within the thickness range of nanometres, along with an orientation of Ag during sliding. Experimental results of sliding tests were discussed on the contribution of surface atoms to the friction, an extraordinarily low wear rate of the Ag layers, and the relationship between the nanoscopic structure and macroscopic tribological performance.     

LUBRICATION FILM FORMATION MECHANISM OF SLIPPER PAIRS IN LOW SPEED HIGH TORQUE HYDRAULIC MOTORS

Pressure-flow analytical formulas of lubrication film of slipper pairs on camshaft connect- ing rod type low speed high torque (LSHT) hydraulic motors are put forward. The bottom surface of slipper pairs is rectangle, and the effect of squeeze flow and pressure differential flow is considered. The dynamic process of lubrication film formation through squeezing is numerically studied by com- puter simulation. Effects of supply pressure, initial lubrication film thickness, velocity damping coef- ficient, loading impact and gravity, etc are studied. Advantages of novel slipper pairs with large oil cavity area are pointed out.