基于条件风险价值的零售商创新投资决策研究

研究了由风险中性制造商和风险规避零售商构成的供应链创新投资问题。通过运用条件风险价值（CVaR）对企业的风险偏好进行测度,构建了分散供应链和集中供应链两种情况下的企业决策模型,并根据数值实验对模型作了进一步的分析。研究结果表明：零售商越担心风险,其对创新的投入越少,并会减少销售量以应对市场风险,从而使得供应链的整体收益下降;分散供应链下的创新投入、销售量和供应链的期望收益低于集中供应链下的创新投入、销售量和供应链的期望收益。施行收益共享契约后,分散供应链下的创新投入和销售量达到了集中供应链下的决策水平,制造商和零售商的期望收益均得到提高。     

实时数据仓库中一种改进的数据流更新算法

为实现数据仓库中数据的高效集成,针对数据偏斜分布现象,提出一种改进的数据流更新算法EH-JOIN。该算法对传统散列连接方法进行改进,利用索引将部分频繁使用的主数据存储在内存中,解决了高速数据流下的磁盘频繁访问问题。实验结果表明,与MESHJOIN算法和R-MESHJOIN算法相比,EH-JOIN算法的服务速率在磁盘存储关系集保持适当大小时分别提高了96%和81%,在内存大小不同时提高了57%和48%。     

Coordination between strategic forest management and tactical logistic and production planning in the forestry supply chain

In this paper, we study the coordination mechanism in the forestry supply chain between strategic forest management and tactical production planning. We first formulate an integrated model to establish a theoretical benchmark for performance of the entire supply chain. It is a mixed integer programming model that involves harvesting, bucking, transportation, production, and sales decisions for both tactical and strategic planning levels. We then present two sequential approaches S‐A and S‐B where the coordination is done through internal pricing. S‐A is the approach currently used in practice where harvesting in the forest is the main driver of the supply chain activities and internal pricing is introduced to control bucking decision in a separate stage. In contrast, S‐B takes downstream demand information into consideration and internal pricing directly influences harvesting decision in the first stage. In order to find the appropriate setting of internal pricing that leads to the system optimum, we suggest two heuristics H‐I and H‐II. The internal pricing in H‐I is based on dual values and in H‐II, it is derived from a Lagrangian decomposition. A real‐life case study in the Chilean forestry industry is used to compare the results of different approaches. It is shown that the new sequential approach S‐B generates as good feasible solution as that obtained from the integrated approach but in much less time. Both heuristics H‐I and H‐II bring about near‐optimal feasible solutions. H‐II also provides optimistic bound of the optimal objective function value, which can be used as a measure of the solution quality.     

动态受限区域内的单纯型连续近邻链查询方法

受限区域内的单纯型连续近邻链查询在空间数据挖掘、数据的相似分析和推理、空间数据库等方面具有重要的作用。为了弥补已有方法的不足,详细研究了动态受限区域内的单纯型连续近邻链查询方法。基于计算几何中的Voronoi图给出了VOR_IN_CRSCNNC算法、VOR_EX_CRSCNNC算法和VOR_DE_CRSCNNC算法。进一步进行了实验比较和分析。理论研究和实验分析表明,所提出的算法在查询过程中减少了数据逐一筛选和判断的冗余计算,在处理空间数据量较大、初始受限区域数据量较多、受限区域形状较为复杂的单纯型连续近邻链查询方面具有较大的优势。     

基于逐层剪枝的中文高频重复模式快速提取算法

为了从大规模语料中快速提取高频重复模式,以递增n-gram模型为基础,使用散列数据结构提取重复串,并提出了一种基于低频字符和层次剪枝的逐层剪枝算法,用于过滤低频垃圾字串,减少I/O读写次数。在此基础上,应用改进的字串排序算法,使字符串排序可在O(n)时间内完成,从而有效提高重复模式的提取效率。实验表明,该算法是一种有效的重复模式提取算法,其I/O读写次数同语料规模呈线性关系,远小于使用首字符进行语料划分的方法,能快速有效地从规模远大于内存容量的文本语料中提取重复模式,特别适合于大规模语料的高频重复模式提取,对以重复模式为基础的新词识别、术语抽取等具有重要的支撑作用。     

Synthesis of water-soluble single-walled carbon nanotubes by RAFT polymerization

Water-soluble single-walled carbon nanotubes (SWNTs) were synthesized by grafting poly(acrylamide) (PAM) from the surface of SWNT via reversible addition-fragmentation chain transfer (RAFT) polymerization. The RAFT agents were covalently attached to the SWNTs by functionalizing SWNTs with in situ generated diazonium compounds. The product was characterized by means of FT-IR, Raman, ¹H NMR, TGA and TEM. The results showed that PAM chains had successfully grafted from SWNT by RAFT polymerization. The amount of PAM grown from SWNT increased with the polymerization time. The acrylamide conversion increased linearly with the polymerization time, indicating the “living” characteristics of the RAFT polymerization. TEM was utilized to image PAM-g-SWNT, showing relatively uniform polymer coatings present on the surface of individual, debundled nanotubes.     

应用高分子分子设计合成节能丁苯橡胶：Ⅱ.链结构形成机理

用阴离子法合成ＳＢＲ，多官能团锂为引发剂，环已烷为熔剂，极性添加剂为无规化剂和结构调节剂。对苯乙烯、１．２－结构单元在分子链上的分布情况进行了研究。对丁苯共聚物的共聚组成，序列分布、微观结构 形成机理进行了探讨。认为在聚合体系中同时存在有丁二烯的π烯丙基活性种、σ烯丙基活性种及苯乙烯活性种。丁二烯与σ烯丙基活性中心反应主要形成１．４－结构，同π烯丙基中心反应主要形成１．２－结构。对于π烯丙基活性中     

Effects of the o‐aromatic ring in the molecular chain on the properties of polyester polyols

A series of liquid polyester polyols from adipic acid (AA), phthalic anhydride (PA), ethylene glycol, propanediol‐1,2, and trihydroxymethylpropane, varying in the molar ratio of PA to AA, were prepared. The effects of the o‐aromatic ring in the molecular chain, which came from PA, on the viscosity, glass‐transition temperature, and thermal degradation temperature of the polyester polyols were studied with viscometry, differential scanning calorimetry, and thermogravimetry. The intrinsic viscosity and glass‐transition temperature increased with the concentration of the o‐aromatic ring increasing. The temperature of the maximum thermal degradation rate for aliphatic polyester polyols was 434.20°C. Two steps of thermal degradation were found when there were o‐aromatic rings in the molecular chain. One thermal degradation temperature was 358.36–360.48°C, and the other was 412.85–427.18°C. Polyester polyols with o‐aromatic rings had higher stability at lower temperatures (<240.00°C). However, aliphatic polyester polyols had higher stability at higher temperatures (300.00–480.00°C). The activation energy and order of degradation were calculated from thermogravimetric curves. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1617–1624, 2002     

石化企业供应链管理研究

介绍了国内外石化行业的供应链管理现状，对中石化电子化供应链方案进行了分析，并就中石化供应链管理存在的问题提出解决方案。     

PROBING HIDDEN POLYMERIC INTERFACES USINGIR-VISIBLE SUM-FREQUENCY GENERATION SPECTROSCOPY

Understanding the molecular-level processes underlying interfacial phenomena is important in the area of adhesion. We briefly introduce IR-visible sum-frequency generation spectroscopy (SFG) using a total-internal-reflection geometry for the study of polymer-air, polymer-solid, and polymer-polymer interfaces. The following examples, predominantly of work done in our lab, illustrating differences in molecular structure and dynamic properties at interfaces are presented: the air- and solid-interface structure of an amorphous polystyrene (PS) and a semicrystalline polymer with side-chain crystallinity, poly(octadecyl acrylate) (PA-18); structure of a polymer-polymer interface between thin films of a semicrystalline polymer with side-chain crystallinity, poly(vinyl-N-octadecylcarbamate- co-vinyl acetate), and an amorphous PS; thermal order-to-disorder transitions of the air and solid interface of PA-18, and the interface of this polymer with PS; and dynamic surface-relaxation studies of a rubbed PS film.