远红外织物的保健性能

远红外织物是８０年代中期研究开发出的一种通过高效吸收和发射远红外线而具有改善微循环、促进血液循环等功能的新型纺织品。本文通过研究实例综述了国内外近年来对远红外织物保健性能的研究成果。     

The adsorption characteristics of two Mo sites on a sulfided MoO3/γ-Al2O3 surface

The surface structure of the oxidized and ammonia dissolved MoO₃/-Al₂O₃ samples and the adsorption characteristics of the sulfided samples were investigated by Laser Raman Spectroscopy (LRS) and Low Temperature Infrared Spectroscopy (LTIR) techniques.It was verified that there were two kinds of coordinated unsaturated Mo sites (denoted as Mo_A(CUS) and Mo_B(CUS)) on the surface and the precursors of Mo_A(CUS) and Mo_B(CUS) were Mo(O) and Mo(T), respectively. It was also concluded that Mo_A(CUS) sites could adsorb NO and CO, while Mo_B(CUS) could adsorb CO only. The surface concentration of Mo_A(CUS) might be far smaller than that of Mo_B(CUS).     

涤纶帘子线的等离子体改性

运用等离子体对涤纶帘子线进行改性处理，从而提高涤纶帘子线与橡胶的粘合性，并用X光电子能谱和红外光谱表面分析技术分析改性后的涤纶帘子线表面结构所发生的变化。     

Preparation and Characterization of K_n|Ga(H_2O)MW_(11)O_(39)|·xH_2O

In this paper the heteropoly complexes K_n[Ga(H_20)MW_(11)O_39)]·xH_20 [M=Cu(Ⅱ), Co(Ⅱ), Cr(Ⅲ),Fe(Ⅲ), Mn(Ⅳ)] have been prepared in this laboratory firstly. The products were characterized by chemicalanalysis, ionexchange, IR, UV and X-ray powder diffraction.     

工业石蜡的结构分析

采用核磁共振（NMR），红外吸收光谱（IR）和色－质联用（GC－MS）方法，测定了弓弩用工业石蜡的^13C-NMR谱、反转门控^13C-NMR谱、IR光谱、气相色谱和各组分的质谱，确定了该石蜡9种主要组分及其相对含量。     

Propane oxydehydrogenation reaction on a VPO/TiO2 catalyst. Role of the nature of acid sites determined by dynamic in-situ IR studies

A VPO/TiO₂ catalyst tested in the oxydehydrogenation reaction (ODH) of propane between 300 and 400°C shows satisfactory performances (up to 80% of propene selectivity at 2% of propane conversion at 300°C or 56% of propene selectivity at 9% of propane conversion at 400°C). Addition of water or pyridine in the feed gas tends to decrease the propane conversion and enhances the propene selectivity. It is shown that water increases the number of Brönsted surface acid sites by dissociative adsorption which, in turn, enhances propene selectivity at the expense of the CO_x selectivity. These results are in good agreement with spectroscopic IR observations performed under catalytic conditions showing that the Lewis acid sites are linked to CO_xformation, whereas it seems that Brönsted sites would rather be linked to propene formation.     

IR Spectroscopic Study of the Organic Component of Ultrafine Diamond Produced by Detonation Synthesis

IR spectra of ultrafine diamonds produced by different teams of researchers are studied. The effects of heating and radiation on the properties of ultrafine diamonds are studied. Quantitative assumptions on the kinetics of formation of ultrafine diamonds are made from analysis of IR spectra.     

Thermal degradation behaviors of polypropylene with novel silicon‐containing intumescent flame retardant

The N‐[3‐(dimethoxy‐methyl‐silanyl)‐propyl]‐N′‐ (9‐methyl‐3,9‐dioxo‐2,4,8,10‐tetraoxa‐3,9‐diphospha‐spiro[5.5]undec‐3‐yl)‐ethane‐1,2‐diamine/dimethoxy dimethyl silane copolymer (PSiN II), which simultaneously contains silicon, phosphorus, and nitrogen, is synthesized and incorporated into polypropylene (PP). The flame retardancy is evaluated by the limiting oxygen index value, which is enhanced to 29.5 from 17.4 with 20% total loading of PSiN II. The thermal degradation behavior of PP/PSiN II is investigated by thermogravimetric analysis under N₂ and air. The PP/PSiN II sample degrades at 400°C for different amounts of time, and the process of degradation is studied by Fourier transform IR. The morphology of the char formed at 400°C for 10 min is investigated by scanning electron microscopy. The swollen inner structure, close, and smooth outer surface provide a much better barrier for the transfer of heat and mass during fire and good flame retardancy. The thermal stability of PP is improved by incorporation of PSiN II. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 2487–2492, 2005     

Surface chemistry and mechanical property changes of wood‐flour/high‐density‐polyethylene composites after accelerated weathering

Although wood–plastic composites have become more accepted and used in recent years and are promoted as low‐maintenance, high‐durability building products, they do experience a color change and a loss in mechanical properties with accelerated weathering. In this study, we attempted to characterize the modulus‐of‐elasticity (MOE) loss of photostabilized high‐density polyethylene (HDPE) and composites of wood flour and high‐density polyethylene (WF/HDPE) with accelerated weathering. We then examined how weathering changed the surface chemistry of the composites and looked at whether or not the surface changes were related to the MOE loss. By examining surface chemistry changes, we hoped to begin to understand what caused the weathering changes. The materials were left unstabilized or were stabilized with either an ultraviolet absorber or pigment. After 1000 and 2000 h of accelerated weathering, the samples were tested for MOE loss. Fourier transform infrared (FTIR) spectroscopy was employed to monitor carbonyl and vinyl group formation at the surface. Changes in the HDPE crystallinity were also determined with FTIR techniques. It was determined that structural changes in the samples (carbonyl group formation, terminal vinyl group formation, and crystallinity changes) could not be reliably used to predict changes in MOE with a simple linear relationship. This indicated that the effects of crosslinking, chain scission, and crystallinity changes due to ultraviolet exposure and interfacial degradation due to moisture exposure were interrelated factors for the weathering of HDPE and WF/HDPE composites. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2263–2273, 2004