Surface designing of polypropylene by critical monitoring of the grafting conditions

The grafting of acrylic acid onto electron beam‐irradiated polypropylene was carried out using preirradiation method. The stability of peroxy radicals was investigated by electron spin resonance. It was found that the decay of peroxy radicals is much faster at 70°C than at 40°C and ambient temperature. The grafting has been observed to be strongly dependent on the monomer dilution in the reaction medium. The grafting was ascertained by attenuated total reflectance (ATR). The distribution of grafts across the samples was monitored by infrared microscopy. It was found that the graft management is considerably influenced by composition of the grafting medium. The grafting involving pure monomer leads to the surface enrichment with the polyacrylic acid chains. The samples grafted in pure monomer led to much lower contact angles as compared to the diluted monomer solution. The swelling of the grafted samples also showed a trend that was governed by the graft management. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 546–553, 2006     

红外目标模拟器校准系统的研制与应用

采用标准辐射和红外目标模拟器的辐射交替折转进入红外光谱辐射计的方法，研制的红外目标模拟器校准系统可以对红外目标模拟器进行直接校准．该系统由标准准直辐射源，光束偏转装置和红外光谱辐射计组成．标准准直辐射源由工作温度为50℃～1050℃的标准黑体和口径300mm的离轴抛物面作主镜的准直光管组成．光束偏转装置由口径465mm的反射镜和定位精度5″的转台组成．红外光谱辐射计采用圆形渐变滤光片CVF对入射的辐射分光，3个光谱工作区间为1μm～3μm，3μm～5μm和8μm～14μm。3个区间的测试数据显示了最小可校准的光谱辐照度低于10^-11／cm^2，系统的相对标准不确定度为2％．     

UO_2(HCOO)_2·H_2O在290K-10K的红外光谱及~(235)U-~(238)U同位素位移的研究

本文通过测定甲酸铀酰[UO_2(HCOO)_2·H_2O]在290K-10K的红外光谱,确定了该化合物铀酰基团(O-U-O)v_(as)振动峰位,研究了温度对峰宽、峰位的影响,并采用差减及峰内标法估算了甲酸铀酰在290K-10K的同位素位移值。测得290K,77K及10K时~(238)U的v_(as)值分别为931.90cm~(-1),930.82cm~(-1)和930.74cm~(-1),~(235)U-~(238)U同位素位移△v分别为0.63cm~(-1),0.67±0.18cm~(-1)和0.71±0.21cm~(-1),位移值与理论计算值接近。     

Control of polymerization processes of 10,12-pentacosadiynoic acid LB films

Studies have been carried out on KrF excimer laser light (EX), X-ray or electron beam (EB) induced polymerization of 10,12-pentacosadiynoic acid (PDA) Langmuir-Blodgett (LB) films in relation to molecular density or molecular arrangement of the films using X-ray diffraction analysis, infrared (IR) spectroscopy and Raman spectroscopy. The molecular arrangement or density of the PDA LB films was controlled by subphase conditions when the films were built up, such as pH, temperature of a subphase or salt concentration in the subphase. Polymerization sensitivity of the PDA LB film was affected by the arrangement or molecular density. On low density (A type) films the polymerization occurred by irradiation with EX, X-ray or EB, but on high density (B type) films the polymerization occurred only when the irradiation was carried out by high energy beams such as X-ray or EB. Decomposition of polymerized films was observed further by excessive irradiation of EX or X-ray, but not on the B type films. It was revealed by X-ray diffraction analysis that in the A type film, the PDA molecules bent to a larger extent than those in the B type film and the polymerization proceeded topochemically, that is, the thickness decreased little after EB irradiation in a helium atmosphere. On the other hand, in the B type film, the thickness decreased by about 10% as a result of EB irradiation. By IR reflection-absorption (RA) and Raman measurements, it was confirmed that conjugated diacetylenic bonds disappeared and conjugated double and new conjugated triple bonds appeared after high energy beam irradiations. These results support the supposition that 1,4-polymerization, i.e. polydiacetylene type polymerization, occurs easily in the A type film and 1,2- or 3,4-polymerization, i.e. polyacetylene type polymerization, occurs in the B type film, and that the polymerized A type film was decomposed at the polydiacetylenic bond when the irradiation continued further. It was also shown that the polyacetylene type polymer was obtained only when the B type film was irradiated with the high energy beam.     

DCS在采暖锅炉房中的应用

介绍了Jx—300X DCS系统的组成、功能、特点以及热水锅炉主要控制方案及其在锅炉测控方面的应用。     

Organic‐acid‐catalyzed sol–gel route for preparing poly(methyl methacrylate)–silica hybrid materials

In this study, a series of organic–inorganic hybrid sol–gel materials consisting of a poly(methyl methacrylate) (PMMA) matrix and dispersed silica (SiO₂) particles were successfully prepared through an organic‐acid‐catalyzed sol–gel route with N‐methyl‐2‐pyrrolidone as the mixing solvent. The as‐synthesized PMMA–SiO₂ nanocomposites were subsequently characterized with Fourier transform infrared spectroscopy and transmission electron microscopy. The solid phase of organic camphor sulfonic acid was employed to catalyze the hydrolysis and condensation (i.e., sol–gel reactions) of tetraethyl orthosilicate in the PMMA matrix. The formation of the hybrid membranes was beneficial for the physical properties at low SiO₂ loadings, especially for enhanced mechanical strength and gas barrier properties, in comparison with the neat PMMA. The effects of material composition on the thermal stability, thermal conductivity, mechanical strength, molecular permeability, optical clarity, and surface morphology of the as‐prepared hybrid PMMA–SiO₂ nanocomposites in the form of membranes were investigated with thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, gas permeability analysis, ultraviolet–visible transmission spectroscopy, and atomic force microscopy, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis and thermomechanical characterization of polyurethane elastomers extended with α,ω‐alkane diols

A series of polyurethane (PU) elastomers was prepared by the reaction of poly(?‐caprolactone) and 4,4′‐diphenylmethane diisocyanate, which was extended with a series of chain extenders (CEs) having 2–10 methylene units in their structure. The completion of the reaction was confirmed by Fourier transform infrared spectroscopy. The chemical structures of the synthesized PU samples were characterized with Fourier transform infrared, ¹H‐NMR, and ¹³C‐NMR spectroscopy, and the thermal properties were determined by thermogravimetric analysis, DSC, and dynamic mechanical thermal analysis techniques. The mechanical properties were also studied and are discussed. The thermogravimetric analysis and DSC analysis showed that CE length had a considerable effect on the thermal properties of the prepared samples. The dynamic mechanical thermal analysis and damping peaks were also affected by the number of methylene units in the CE length. The elastomer extended with 1,2‐ethane diol exhibited optimum thermal properties, whereas the elastomer based on 1,10‐decane diol displayed the worst thermal properties. Tensile strength and elongation at break decreased with increasing CE length, whereas hardness showed the opposite trend. The glass‐transition temperature moved toward lower temperatures with increasing CE length. The decrease in the glass‐transition temperature and tensile properties were interpreted in terms of decreasing hard segments and increasing chain flexibility. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

氯氧镁水泥对不饱和树脂的阻燃性能与阻燃机理研究

采用极限氧指数法、热重分析和烟密度测试法研究了氯氧镁水泥在不饱和树脂（UP）中的阻燃作用和阻燃机理。研究表明经偶联剂处理后的氯氧镁水泥对UP具有良好的阻燃抑烟效果，并通过增加UP在高温下的热稳定性和降低热失重速率等机理发挥阻燃作用：氯氧镁水泥含量在40％内对UP的力学性能影响较小，是一种新型的无机添加型阻燃剂。     

用热分析法研究硝化棉的熔化过程

用ＭＤＳＣ，显微镜温台熔点测定仪和固体原位反应池／快速扫描傅立叶变换红外光谱联用装置考察了硝化棉的熔化过程。ＭＤＳＣ曲线表明吸热过程是可逆的，它系由ＮＣ和部分分解凝聚相产物的混合物的固液相变所引起。由ＮＣ的ＭＤＳＣ曲线得到的熔点，熔化含，熔化熵，分解含和分解反应热温熵分别为４７６．８４Ｋ，２０５．６Ｊ．ｇ＾－１，０．４３１２Ｊ．ｇ＾－１．Ｋ＾－１，－２４７５．０Ｊ．ｇ＾－１，－５．２４２Ｊ．ｇ＾－     

Platinum promoted zirconia-sulfate catalysts: one-pot preparation,physical properties and catalytic activity

A new innovative methodology for the single-stage preparation of ZrO₂-SO₄ and Pt/ZrO₂-SO₄ catalysts is reported, based on the sol-gel technique. Catalysts are characterized by analysis, XRPD, BET and IR methods and are tested in the isomerization of butane.