Dynamics of fluid circulation in coupled free and heterogeneous porous domains

Fluid flow in coupled free and porous domain, particularly when the porous medium is heterogeneous, is encountered in many hydro-environmental conditions, e.g., leakage from underground pipe, combined groundwater lake-subsurface interactions. One of the most difficult problems in the study of coupled flow behaviour has been the development of a universally applicable modelling scheme for combining the flow regimes. This is because the free/porous interfacial properties (e.g., shear-stress; velocity slip) that govern the coupled flow behaviour are difficult to determine experimentally under hydro-environmental conditions. On the other hand, the implications of various forms of heterogeneity in the porous media properties can be very different on the fluid-flow behaviour. Difficulties may also arise in direct coupling of the model equations that govern the fluid flow in the individual regions (e.g., Navier-Stokes for free-flow region and the Darcy's equation for the porous flow region). Consequently, models of coupled free and porous flow for hydro-environmental conditions are not very well developed at the moment. While there are some indications that fluids in coupled free and porous domains may circulate (i.e., development of flow cells), there is a lack of appropriate 3D analysis on how heterogeneities in porous media may affect such flow patterns. In this paper, we aim to analyse how porous media heterogeneity affects the dynamics of flow circulation in the porous side of a coupled free and porous domain. For this purpose, we analyse flow patterns in several model domains made up of two porous layers with differing permeabilities. The governing model equations are discretised and solved using the standard finite volume method on a staggered cell-centred mesh. The temporal discretisation is done using the explicit method. An in-house graphical user interface (GUI) has been created specifically to aid in the visualisation of otherwise complex flow patterns. The GUI contains many post-processing options and provides a comprehensive tool for the analysis of hydrodynamics and contaminant motion (not discussed in this paper) in coupled free and porous flow domains. This GUI is described in this paper briefly. The effects of altering the aspect ratio (i.e., multi-scale) of the domain on the coupled flow pattern have also been discussed.     

聚氨酯涂料中游离甲苯二异氰酸酯(TDI)单体的测定方法

研究了在GB/T18446-2001方法基础上改变内标物(使用无毒性记录的十二烷代替毒性大的1,2,4-三氯代苯)测定样品中游离TDI的方法。该方法简捷、快速、准确度高、精确度高、更环保。本方法的适用范围同GB/T18446-2001。     

两种聚氨酯防水涂料的比较

对焦油型和非焦油水固化型聚氨酯防水涂料B组分的生产工艺、配方特点，施工操作工艺、固化时间、涂膜性能等方面进行了比较，指出新开发的非焦油型聚氨酯涂料生产周期短、能耗少、气味小，是环保型聚氨酯防水涂料。     

一次风机节能改造

为解决一次风机出口风压低、火焰无力度、系统功耗高等问题,采用空气悬浮风机对其进行节能改造。拆除原有的一次风机备用风机,在原有底座上安装空气悬浮风机,整体设计安装悬浮风机出口管道。改造后,一次风机出口风压明显增大,煤粉燃烧充分,火焰调整灵活,每小时可节电30kWh,两处对空排放管道加装消声器,降噪效果显著。     

分子蒸馏技术与日用化工(Ⅰ)——分子蒸馏技术的原理及特点

介绍了分子蒸馏技术发展简况，并从分子运动平均自由程的定义出发，介绍了分子蒸馏技术的基本原理、特点以及与常规蒸馏、超临界萃取与层析分离等方法的不同。分子蒸馏操作温度低、受热时间短及分离效率高，特别适用于热敏性物质的提纯，有广阔的应用前景。     

End-capped polystyrene with 8-hydroxyquinoline group by ATRP method

8-Hydroxyqunioline end-capped polystyrene was prepared through atom transfer free radical polymerization (ATRP) with 8-(5-chloromethyl) quinolyl acetate as initiator. The results indicated that this polymerization is a first order reaction with respect to monomer conversion. The molecular weight increased linearly with monomer consumption and very narrow distribution of molecular weight was obtained (polydispersity index less than 1.2). The FT-IR and NMR results show that the 8-hydroxyquinloine group was chemically bonded to the polymer end and there is nearly one 8-hydroxyquinoline group in per polymer chain. All those data show that polymerization of styrene at such conditions displayed living characters. The polymer with 8-hydroxyqquinoline end group reacted with triethylaluminum to form polymeric light-emitting complex and single layer LED was prepared by common spin-coating method. The peak wavelength of LED based on synthesized polymeric complex was around 570 nm.     

煤中吡啶型氮热解机理的量子化学研究

用密度泛函 ( DFT)方法 ,在 UB3LYP/6- 31 G( d)水平上研究了煤中吡啶型氮的热解机理 ,对热解过程中由于官能团周围环境的不同而形成的三类吡啶自由基进行了量子化学计算 ,通过对键的 Mulliken布居数等计算结果的分析 ,分别得到了这三类自由基的热解途径 .并优化得到了反应物、中间体和产物的几何构型 .计算结果表明 ,吡啶型氮主要是以 HCN的形式释放出来的 .NH3 是 HCN二次反应的产物 .     

基于自由运动一维标定物的多摄像机参数标定方法与实验

一维标定方法易于实现且标定效率高,为了克服现有一维标定方法的一些不足,本文提出一种用一维标定物标定多摄像机内外参数的方法,首先进行两两标定,在此过程中,假定主点坐标近似已知而仅考虑畸变、焦距、旋转和平移等参数,接着利用基本矩阵及一维标定物上特征点之间的几何约束,估计两摄像机的内外参数,两两标定完成后,采用Dijkstra最短路径法和捆绑调整对多摄像机系统进行全局标定(含主点坐标),仿真和真实实验表明本文的方法是切实有效的.     

角蛋白基药物载体的发展及应用探讨

从毛发中提取角蛋白，开发具有独特功能的角蛋白基药物载体材料，提高药物的活性和生物利用率，既能够增加毛发的利用价值，又能够实现节能减排，符合可持续发展战略要求。对毛发中提取角蛋白进行二硫键重建、自由基聚合、多糖改性和烷基化等改性处理，赋予角蛋白基药物载体优异地功能特性，进一步拓宽其作为角蛋白基药物载体的应用范围。角蛋白基药物载体可被加工成纳米粒子、纤维支架、水凝胶等各种形式用于药物的递送。作为一种高硫含量且具有良好细胞相容性的结构蛋白，角蛋白基药物载体在组织工程、再生医学等领域扮演着重要的角色。     

原子磁强计检测光闭环稳定系统设计

SERF态原子磁强计已实现人类历史上最高的0.16fT/Hz1/2的灵敏度。其检测方法主要是法拉第调制法。但法拉第调制法中光电流摄动或环境温度变化等干扰导致的检测光强的起伏会造成检测结果的不准确。为抑制检测光强起伏,设计了闭环原子磁强计检测光稳定系统。在法拉第调制法的基础上,增加了光路子系统和控制子系统对检测光强进行闭环稳定控制。通过对随机干扰进行闭环控制仿真与实验,验证本系统可以有效抑制各种干扰引起的光强起伏,使系统抗干扰能力提高1.2%,从而提高原子磁强计的检测精度。