二苯并-18-冠-6的合成条件的优化

通过改变溶剂的极性、离子性、离去基团的活性及反应温度等方法,对传统的Pedersen冠醚合成法进行了优化,使目标产物的最高产率达到71%以上.产物通过IR、1H NMR及元素分析等方法进行结构表征.     

A Survey of Inverse Surface Design From Light Transport Behavior Specification

Inverse surface design problems from light transport behavior specification usually represent extremely complex and costly processes, but their importance is well known. In particular, they are very interesting for lighting and luminaire design, in which it is usually difficult to test design decisions on a physical model in order to avoid costly mistakes. In this survey, we present the main ideas behind these kinds of problems, characterize them, and summarize existing work in the area, revealing problems that remain open and possible areas of further research.     

热力学相图计算技术在闪速燃烧合成氮化硅铁中的应用

将热力学相图计算技术应用于Si-Fe-O-N体系,以评估由FeSi75粉闪速燃烧合成氮化硅铁的条件和目标产物。结果表明:将闪速燃烧温度控制在1200～1500℃之间较为适宜,此时平衡态产物中除主要含有Si3N4以外,还有一定量的Fe与Si间化合物和少量稳定的SiO2存在。此计算结果与实际试验结果吻合良好。     

Investigation of texture effect on visual colour difference evaluation

The texture effect on visual colour difference evaluation was investigated in this study. Five colour centers were selected and textured colour pairs were generated using scanned textile woven fabrics and colour‐mapping technique. The textured and solid colour pairs were then displayed on a characterized cathode ray tube (CRT) monitor for colour difference evaluation. The colour difference values for the pairs with texture patterns are equal to 5.0 CIELAB units in lightness direction. The texture level was represented by the half‐width of histogram, which is called texture strength in this study. High correlation was found between texture strength and visual colour difference for textured colour pairs, which indicates that an increasing of 10 units of texture strength in luminance would cause a decreasing of 0.25 units visual difference for the five colour centers. The ratio of visual difference between textured and solid colour pairs also indicates a high parametric effect of texture. © 2005 Wiley Periodicals, Inc. Col Res Appl, 30, 341–347, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.     

A New Image Analysis Based Method for Measuring Electrospun Nanofiber Diameter

In this paper, a new image analysis based method for electrospun nanofiber diameter measurement has been presented. The method was tested by a simulated image with known characteristics and a real web. Mean (M) and standard deviation (STD) of fiber diameter obtained using this method for the simulated image were 15.02 and 4.80 pixels respectively, compared to the true values of 15.35 and 4.47 pixels. For the real web, applying the method resulted in M and STD of 324 and 50.4 nm which are extremely close to the values of 319 and 42 nm obtained using manual method. The results show that this approach is successful in making fast, accurate automated measurements of electrospun fiber diameters.     

锂离子电池正极材料锂锰氧化物的固相合成研究进展

阐述了固相合成反应的原理，综述了锂锰氧化物的几种固相合成方法，并着重介绍了熔融渍法，多步加热法，机械化学法和微波化学法等在锂锰氧化物合成中的研究进展。     

Influence of Ti Powder Characteristics on Combustion Synthesis of Porous NiTi Alloy

Porous NiTi shape memory alloy (SMA) is a novel biomedical material used for human hard tissue implant .The influence of elemental titanium powder characteristics such as powder morphology, particle size and specific surface area( SSA) on the minimal ignition temperature ,combustion temperature and final product of porous Ni-Ti SMA fabricated by combustion synthesis method was investigated in this paper by scanning electron microscopy (SEM) and laser diffraction.The preliminary data indicated that the titanium powder characteristics had a strong effect on combustion synthesis of porous NiTi SMA.     

Thermal Expansion Behavior of La1—xSrxMn1—yCoyO3—δ Perovskites

The thermal expansion behavior of La1-xSrxMn1-yCoyO3-δ (x=0.2-0.4, y=0.1-0.3) perovskites in air has been investigated. The average linear thermal expansion coefficients increased with increasing Sr content up to 40 mole fraction or Co content up to 30 mole fraction. The expansion is generally attributed to an increase in the average cation radius as some of the cations in the perovskite are reduced in valence when oxygen ions are removed from the structure.     

基于图像的虚拟环境建模技术

综述了基于图像的虚拟现实环境的建模技术，并给出了各种模型表示的理论依据和建模过程的定义。把环境表示分为四类：全景图，光场数据库，深度图像和多投影中心图。全景图的生成包括基于图像相关性和基于图像整合变换的算法。光场数据库的分类主要依据全光函数。同时论述了在各种表示下的采样和建模技术。最后讨论了当前建模技术研究的热点及所需要解决的问题。     

刚性棒状全芳香液晶聚酯的合成及性质的研究

以溴和苯基取代的对苯二甲酰氯及2，2′-二甲基联苯-4，4′-二甲酰氯作为单体，分别与甲基、叔丁基、苯基取代的对苯二酚经熔融缩聚反应，合成一类具有刚性棒状结构的全芳香液晶聚酯。聚酯的热性质以TGA、DSC，热台偏光显微镜研究。所有的聚酯均为热致性液晶，它们具有相对较低的转变温度，在普通的有机溶剂中具有较好的溶解性质。