高温超高压处理HDPE的WAXD及FT－IR研究

用ＷＡＸＤ和ＦＴ－ＩＲ对高温超高压处理前后的ＨＤＰＥ进行了研究。发现经５．０ＧＰａ的高压处理或２００℃下４．０ＧＰａ的高压同时处理后的ＨＤＰＥ分子链的化学结构未发生变化。ＨＤＰＥ晶体中（２００）面与（１１０）面衍射峰的峰高比（γ）随着压力的升高而增大，表明ＨＤＰＥ分子链在超高压作用下发生了取向排列，且升高温度更有利于这种取向排列，但当压力增大至５．０ＧＰａ及温度升高至２００℃时，γ反而大幅度下降。     

A Novel Method Of Transport Barrier Formation

A novel technique is proposed for creating transport barriers by the rf waves. This is that the transport barriers can be created by the rf induced ponderomotive force itself and no rf induced flow shear generation is necessary. It is demonstrated that the ponderomotive force of the rf waves can stabilize the ion temperature gradient (ITG) mode, considered nowadays as the dominant source of anomalous energy losses in the low confinement (L) mode. It is also shown that this stabilization can be achieved for rather modest values of the rf power and hence should be easily obtained in actual experiments.      

Acidic and basic hydrolysis of poly(N‐vinylformamide)

Poly(N‐vinylformamide) (PNVF) was synthesized and hydrolyzed to poly(vinylamine) (PVAm) in both HCl and NaOH solutions. The hydrolysis kinetics and the equilibrium hydrolysis were examined experimentally at different temperatures, polymer concentrations, and acid‐ or base‐to‐amide molar ratios. The hydrolysis kinetics strongly depended on temperature, polymer, and HCl or NaOH concentrations, but showed little dependence on PNVF molecular weight. The acid hydrolysis of PNVF exhibited limited conversions because of the electrostatic repulsion among the cationic amine groups generated during hydrolysis and proton hydrates. In the basic hydrolysis, complete amide conversions were observed when the NaOH/amide molar ratios were greater than unity. The effects of temperature and PNVF concentration on the equilibrium amide conversion appeared to be negligible in both acidic and basic hydrolysis. The equilibrium conversions of base hydrolysis were higher than those of acidic hydrolysis under the same reaction conditions. At NaOH/amide ratios of less than unity, the equilibrium hydrolysis experiments revealed that one base molecule could induce the hydrolysis of more than one amide group. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3412–3419, 2002     

Parallel integration of ODEs based on convolution algorithms

We consider parallel computing methods for ODEs based on the potential parallelism of convolution algorithms. Detailed presentations of fast convolution algorithms are provided. Implementations of our methods on signal processors and special processors are described. The main emphasis is concentrated on applications of powerful parallel signal processing facilities in ODE computations. By using convolution algorithms we show some treatments of parallel computing in finite fields. As an example of our approach we discuss integrating Lorenz's model.

---

Zusammenfassung Wir behandeln parallele numerische Methoden für gewöhnliche Differentiagleichungen, die auf Parallelismus von konvolutiven Algorithmen basieren. Ausführliche Darstellungen der schnellen konvolutiven Berechnungen mit spezieller Hardware werden präsentiert. Der Schwerpunkt dieser Arbeit ist die Anwendung von leistungsfähigen parallelen Signal-Prozessoren in der Berechnung gewöhnlicher Differentialgleichungen. Unter Verwendung von Konvolutiven Algorithmen erläutern wir einige Anwendungen von parallelem Rechnen in endlichen Körpern. Als Beispiel unseres Zugangs diskutieren wir die Integration des Lorenz-Modells.

     

A polynomial factorization approach to the discrete time GI/G/1/(N) queue size distribution

The queue of a single server is considered with independent and identically distributed interarrivai and service times and an infinite (GI/G/1) or finite (GI/G/1/N) waiting room. The queue discipline is non-preemptive and independent of the service times.

A discrete time version of the system is analyzed, using a two-component state model at the arrival and departure instants of customers. The equilibrium equations are solved by a polynomial factorization method. The steady state distribution of the queue size is then represented as a linear combination of geometrical series, whose parameters are evaluated by closed formulae depending on the roots of a characteristic polynomial.

Considering modified boundary constraints, systems with finite waiting room or with an exceptional first service in each busy period are included.     

水稻强化栽培下不同氮肥管理对产量与氮素利用的影响

以籼型单季超级杂交稻中浙优1号为材料,研究水稻强化栽培氮肥管理对产量与氮素利用率的影响。结果表明:水稻强化栽培与常规栽培对照比较,增产达11.1%-15.2%,氮肥回收率比对照高5.3%~26.9%,农学利用率比对照高67.2%~92.2%,生理利用率比对照高6.0%~80.5%。因此,在水稻生产上应用水稻强化栽培可以提高氮肥的利用,降低氮肥在环境中积累及对环境造成污染。此外,本文对水稻强化栽培下氮肥管理的高产机理进行了探讨。     

Colour measurement of fish minces using hunter L,a, b values

Hunter L, a and b values are used to order fish mince colour according to species or processing parameters. Mince colour difference (ΔE) or statistical examination of L, a and b values are used to establish a 3-dimensional plot to illustrate colour differences between samples.     

Consumer preference not to choose: Methodological and policy implications

Residential consumers remain reluctant to choose new electricity suppliers. Even the most successful jurisdictions, four US states and other countries, have had to adopt extensive consumer education procedures that serve largely to confirm that choosing electricity suppliers is daunting. Electricity is not unique in this respect; numerous studies find that consumers are generally reluctant to switch brands, even when they are well-informed about product characteristics. If consumers prefer not to choose, opening regulated markets can reduce welfare, even for some consumers who do switch, as the incumbent can exploit this preference by raising price above the formerly regulated level. Policies to open markets might be successful even if limited to industrial and commercial customers, with residential prices based on those in nominally competitive wholesale markets.     

Alkylated ureas: mineralization and evaluation as N sources

An incubation experiment was conducted for 11 weeks to study the mineralization of ten alkylated ureas and urea in soil. Six of the alkylated ureas viz. methylurea(MU), 1,3-dimethylurea(1,3DMU), 1,1-dimethylurea(1,1DMU), ethylurea(EU), 1,3-diethylurea(1,3DEU) and butylurea(BU) and urea mineralized during the experiment. Urea mineralized immediately, while alkylated ureas mineralized after an incubation period ranging from less than a week to four weeks (delay period of mineralization). The delay period increased in the following sequence MU < 1,3DMU < EU < BU < 1,1DMU < 1,3DEU, but after the delay period was over the compounds mineralized almost as rapidly as urea. The delay period varied according to the number of carbon atoms in the alkyl group and their position with respect to each other on the molecule. It appeared to be specific for each compound and was apparently not influenced by the presence of urea or other alkylated ureas. This character can be used to develop mixture of various alkylated ureas to obtain N mineralization at the desired time. Rapid evolution of CO₂ and N₂O was observed during the mineralization of urea as well as alkylated ureas. Increase in soil pH was also observed during this period. The simultaneous ocurrence of these events suggested the formation of urea as an intermediate during the mieralization of alkylated ureas. None of the alkylated ureas showed adverse affect on emergence of wheat seedlings and except DEU and BU at high concentration no other alkylated urea showed any adverse effect on initial growth of wheat seedlings.     

合成亚磷酸三乙酯的吡啶法

用吡啶代替Ｎ，Ｎ－二乙基苯胺吸收反应过程中产生的氯化氢合成亚磷酸三乙酯，反应收率为８４％。