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81.
M. Mar López-González 《Polymer》2005,46(12):4322-4329
This work reports the experimental isotherms describing the concentration of oxygen and nitrogen in poly(bisphenol A carbonate-co-4,4′-(3,3,5-trimethylcyclohexylidene) diphenol carbonate) vs pressure, at 30 °C. The solubility coefficients are interpreted in terms of the Flory-Huggins theory, obtaining reasonable values for the enthalpic polymer-gas parameter. A new method is outlined to simulate the probabilities of inserting/removing a gas molecule in a host matrix already containing n molecules of gas. The simulated isotherms representing the pressure dependence of the concentration exhibit the same pattern as those experimentally obtained. 相似文献
82.
We introduce a new probabilistic approach to dealing with uncertainty, based on the observation that probability theory does not require that every event be assigned a probability. For a nonmeasurable event (one to which we do not assign a probability), we can talk about only the inner measure and outer measure of the event. In addition to removing the requirement that every event be assigned a probability, our approach circumvents other criticisms of probability-based approaches to uncertainty. For example, the measure of belief in an event turns out to be represented by an interval (defined by the inner and outer measures), rather than by a single number. Further, this approach allows us to assign a belief (inner measure) to an event E without committing to a belief about its negation -E (since the inner measure of an event plus the inner measure of its negation is not necessarily one). Interestingly enough, inner measures induced by probability measures turn out to correspond in a precise sense to Dempster-Shafer belief functions. Hence, in addition to providing promising new conceptual tools for dealing with uncertainty, our approach shows that a key part of the important Dempster-Shafer theory of evidence is firmly rooted in classical probability theory. Cet article présente une nouvelle approche probabiliste en ce qui concerne le traitement de l'incertitude; celle-ci est basée sur l'observation que la théorie des probabilityés n'exige pas qu'une probabilityé soit assignée à chaque événement. Dans le cas d'un événement non mesurable (un événement pour lequel on n'assigne aucune probabilityé), nous ne pouvons discuter que de la mesure intérieure et de la mesure extérieure de l'évenément. En plus d'éliminer la nécessité d'assigner une probabilityéà l'événement, cette nouvelle approche apporte une réponse aux autres critiques des approches à l'incertitude basées sur des probabilityés. Par exemple, la mesure de croyance dans un événement est représentée par un intervalle (défini par la mesure intérieure et extérieure) plutǒt que par un nombre unique. De plus, cette approche nous permet d'assigner une croyance (mesure intérieure) à un événement E sans se compromettre vers une croyance à propos de sa négation -E (puisque la mesure intérieure d'un événement et la mesure intérieure de sa négation ne sont pas nécessairement une seule et unique mesure). II est intéressant de noter que les mesures intérieures qui résultent des mesures de probabilityé correspondent d'une manière précise aux fonctions de croyance de Dempster-Shafer. En plus de constituer un nouvel outil conceptuel prometteur dans le traitement de l'incertitude, cette approche démontre qu'une partie importante de la théorie de l'évidence de Dempster-Shafer est fermement ancrée dans la theorie classique des probabilityés. 相似文献
83.
This study was motivated by some difficulties encountered by the authors when trying to express temporal knowledge using Sowa's conceptual graph (CG) approach. An overview of Sowa's approach is given and the difficulties encountered when trying to model temporal knowledge are outlined: the disparity of notations allowed by CG theory for expressing temporal information; the ambiguity and incompleteness of tense sspecification; the difficulty of harmonizing tenses and intergraph temporal relations. Various approaches suggested for representing time both in artificial intelligence and linguistics are presented, and an extension to Sowa's approach is proposed in which temporal and nontemporal knowledge are differentiated. In this model points in time are represented as well as time intervals. A semantic interpretation of verbs is provided based on an extension of Reichenbach's model of temporal markers. The authors show how their approach enables the representation of tenses as well as the aspectual properties of natural language sentences. 相似文献
84.
The Design of Discrimination Experiments 总被引:1,自引:0,他引:1
Experimentation plays a fundamental role in scientific discovery. Scientists experiment to gather data, investigate phenomena, measure quantities, and test theories. In this article, we address the problem of designing experiments to discriminate between two completing theories. Given an initial situation for which the two theories make the same prediction, the experiment design problem is to determine how to modify the situation such that the two theories make different predictions for the modified situation. The modified situation is called a discrimination experiment. We present a knowledge-intensive method called DEED for designing discrimination experiments. The method analyzes the differences in the two theories' explanations of the prediction for the initial situation. Based on this analysis, it determines modifications to the initial situation that will result in a discrimination experiment. We illustrate the method with the design of experiments to discriminate between several pairs of qualitative theories in the fluids domain. 相似文献
85.
We derive a general equation relating probability densities and as special cases we the obtain Gram-Charlier and Edgeworth series. This allows us to generalize these methods and clarify a number of issues pertaining to both probability theory and time-frequency analysis. In particular we show how the Gram-Charlier and Edgeworth series are related to the kernel method of time-frequency analysis. The approach allows us to construct densities that satisfy given constraints such as joint moments or conditional moments. Also, we show that the kernel has to be signal dependent and that to obtain a proper distribution it should be the ratio of two characteristic functions. 相似文献
86.
87.
Uwe Helmke Robert C. Williamson 《Mathematics of Control, Signals, and Systems (MCSS)》1995,8(1):27-49
The problem of parametrizing single hidden layer scalar neural networks with continuous activation functions is investigated. A connection is drawn between realization theory for linear dynamical systems, rational functions, and neural networks that appears to be new. A result of this connection is a general parametrization of such neural networks in terms of strictly proper rational functions. Some existence and uniqueness results are derived. Jordan decompositions are developed, which show how the general form can be expressed in terms of a sum of canonical second order sections. The parametrization may be useful for studying learning algorithms.This work was supported by the Australian Research Council, the Australian Telecommunications and Electronics Research Board, and the Boeing Commencai Aircraft Company (thanks to John Moore). 相似文献
88.
Counting Objects 总被引:1,自引:0,他引:1
89.
90.
本文围绕基因枪技术中用高速微粒向植物细胞中导入外源基因的速度条件,分析了其中的三个动力学过程:发射宏弹、加速微弹、侵入细胞.提出了气动撞击发射式基因枪中弹簧刚度应满足的条件;得到了一种用理论分析与试验测试相结合确定微弹出射速度的方法;找到了微弹侵入植物细胞的最小速度条件。从而为基因枪的设计提供了理论依据。 相似文献