Synergistic effect of co-alloying elements on site preferences and elastic properties of Ni3Al: A first-principles study

The site preferences of co-alloying elements (Mo–Ta, Mo–Re, Mo–Cr) in Ni₃Al are studied using first-principles calculations, and the effects of these alloying elements on the elastic properties of Ni₃Al are evaluated by elastic property calculations. The results show that the Mo–Ta, Mo–Re and Mo–Cr atom pairs all prefer Al–Al sites and the spatial neighbor relation of substitution sites almost has no influence on the site preference results. Furthermore, the Young's modulus of Ni₃Al increases much higher by substituting Al–Al sites with co-alloying atoms, among which Mo–Re has the best strengthening effect. The enhanced chemical bondings between alloying atoms and their neighbor host atoms are considered to be the main strengthening mechanism of the alloying elements in Ni₃Al.     

Electromagnetic shielding properties of iron oxide impregnated kenaf bast fiberboard

The electromagnetic shielding effectiveness of kenaf fiber based composites with different iron oxide impregnation levels was investigated. The kenaf fibers were retted for removing the lignin and extractives from the fibers and magnetized. Using the unsaturated polyester and the magnetized fibers, kenaf fiber based composites were manufactured by the compression molding process. The transmission energies of the composites were characterized when the composite samples were exposed under the irradiation of electromagnetic (EM) wave with a variable frequency from 9 GHz to 11 GHz. Using the Scanning Electron Microscope (SEM), the iron oxide nanoparticles were observed on the surfaces and inside the micropore structures of single fibers. As the Fe content increased from 0% to 6.8%, 15.9% and 18.0%, the total surface free energy of kenaf fibers with the magnetizing treatments increased from 44.8 mJ/m² to 46.1 mJ/m², 48.8 mJ/m² and 53.0 mJ/m², respectively, while the modulus of elasticity reduced from 2875 MPa to 2729 MPa, 2487 MPa and 2007 MPa, respectively. Meanwhile, the shielding effectiveness was increased from 30–50% to 60–70%, 65–75% and 70–80%, respectively.     

Burkholderia thailandensis E264/pBMTL3-tdpR发酵生产抗癌药物ThailandepsinA的研究

在伯克氏菌Bth264野生株产新型抗癌药物Thailandepsin A以及调节基因tdp R正向调控Thailandepsin A生物合成的基础上,利用基因工程菌Bth264/p BMTL3-tdp R发酵生产Thailandepsin A,以提高产量。以0.5%乳糖为诱导剂,确定最佳诱导条件:发酵15 h添加乳糖,诱导时间6 h;通过单因素实验,确定葡萄糖和胰蛋白胨作为碳氮源、装液量65/250 m L以及接种量1%;同时结合优化发酵培养基进行发酵,Thailandepsin A产量达到252.14 mg·L-1,比优化前的产量提高56%;另外在发酵过程中,添加大孔树脂HP-20原位吸附产物,Thailandepsin A产量可达283.75 mg·L-1,比不加树脂提高13.8%;最后,基于RT-PCR和比较Ct值法,基因工程菌和野生菌相比,Thailandepsin A生物合成基因tdp B、tdp C1的转录水平分别提高11.4倍和6.0倍,对应的产量增加4.6倍,从而在很大程度上说明调节基因tdp R的过表达促进生物合成基因转录水平的提高以及产量的增加。     

Mechanical properties of graphene films enhanced by homo-telechelic functionalized polymer fillers via π–π stacking interactions

Most researches on graphene/polymer composites are focusing on improving the mechanical and electrical properties of polymers at low graphene content instead of paying attention to constructing graphene’s macroscopic structures. In current study the homo-telechelic functionalized polyethylene glycols (FPEGs) were tailored with π-orbital-rich groups (namely phenyl, pyrene and di-pyrene) via esterification reactions, which enhanced the interaction between polyethylene glycol (PEG) molecules and chemical reduced graphene oxide (RGO) sheets. The π–π stacking interactions between graphene sheets and π-orbital-rich groups endowed the composite films with enhanced tensile strength and tunable electrical conductivity. The formation of graphene network structure mediated by the FPEGs fillers via π–π stacking non-covalent interactions should account for the experimental results. The experimental investigations were also complemented with theoretical calculation using a density functional theory. Atomic force microscope (AFM), scanning electron microscope (SEM), X-ray diffraction (XRD), nuclear magnetic resonance (NMR), thermal gravimetric analysis (TGA), UV–vis and fluorescence spectroscopy were used to monitor the step-wise preparation of graphene composite films.     

Flexural behaviour of RC slabs strengthened with prestressed CFRP strips using different anchorage systems

The Externally Bonded Reinforcement (EBR) technique using Carbon Fiber-Reinforced Polymers (CFRP) has been commonly used to strengthen concrete structures in flexure. The use of prestressed CFRP material offers several advantages well-reported in the literature. Regardless of such as benefits, several studies on different topics are missing. The present work intends to contribute to the knowledge of two commercially available systems that differ on the type of anchorage: (i) the Mechanical Anchorage (MA), and (ii) the Gradient Anchorage (GA). For that purpose, an experimental program was carried out with twelve slabs monotonically tested under displacement control up to failure by using a four-point bending test configuration. The effect of type of anchorage system (MA and GA), prestrain level (0 and 0.4%), width (50 mm and 80 mm) and thickness (1.2 mm and 1.4 mm) of the CFRP laminate, and the surface preparation (grinded and sandblasted) on the flexural response were the main studied parameters. Better performance was observed for the slabs: (i) with prestressed laminates, (ii) for the MA system, and (iii) with sandblasted surface preparation.     

Facile growth of novel morphology correlated Ag/Co-doped ZnO nanowire/flake-like composites for superior photoelectrochemical water splitting activity

In this paper, novel morphology correlation between silver nanowires (AgNWs) and cobalt (Co)-doped ZnO (Co-ZnO) flake-like thin films (nanowire/flake-like) has been proposed for enhanced photoelectrochemical (PEC) water splitting activity. Here in, high-quality AgNWs/Co-ZnO heterostructures enabled superior visible light water splitting activity compared to the pure ZnO and AgNWs/ZnO. To address the strategic effect of AgNWs coupling and transition metal (Co-2?at%) doping into the ZnO host lattice, we have carried out the X-ray diffraction, field emission scanning microscopy, X-ray photoelectron spectroscopy, UV–Vis transmittance, water contact angle and PEC analyses. In this way, PEC water splitting activity was mainly examined by linear sweep voltammetry (I-V), amperometric I-t and photoconversion efficiency (η) studies. The experimental results provide clear evidence of morphology correlation between AgNWs and Co-ZnO flake-like structures for strong visible light absorption. Specifically, AgNWs/Co-ZnO composites exhibited significant enhancement in the photocurrent density (7.0?×?10^?4 A/cm²) than AgNWs/ZnO (3.2?×?10^?4 A/cm²) and pure ZnO (1.5?×?10^?6 A/cm²). As a result, detailed AgNWs/Co-ZnO geometry has great potential for photoconversion efficiency (0.73%). In a word, the merits of controllable AgNWs/Co-ZnO heterostructure are proposed to improve the visible light harvesting and charge carrier generation for energy conversion devices.     

Evaluation of standard and real fire exposures on thermal response of rail car floor assembly

This work developed a computational methodology to evaluate and compare standard fire exposures such as those outlined in ASTM E119 with real fire exposures and determine the difference in the temperature rise of a rail car floor assembly. The real fire exposures simulated in this work were identified in a review of incidents and consisted of a constantly-fed diesel fuel spill, a localized trash fire, and a gasoline spill simulated from a collision of the railcar with an automobile. These realistic fire exposures were applied to a variety of exemplar rail cars representative of single-level and bi-level passenger cars. These floor assembly models exposed to realistic fires were simulated in Fire Dynamics Simulator (FDS). The thermal exposure at the underside of railcar provided by FDS was coupled with a thermal model in ABAQUS, which provided the evolution of temperature in different components of the floor assembly. The standard scenarios were simulated for 2 hours instead of the typical 30 minutes to identify the appropriate exposure duration in ASTM E119, which can better represent a real fire scenario. The average and maximum temperatures predicted at the unexposed surface for both scenarios were compared with the threshold values given in NFPA 130.     

Calorimetric study of ytterbium orthovanadate YbVO4 polycrystalline ceramics

The heat capacity of ytterbium orthovanadate was first measured by adiabatic calorimetry in the temperature range T?=?12.28–344.06?K. No obvious anomalies were observed on the curve obtained. The values of standard thermodynamic functions in the temperature range T?=?0–400 K were calculated. Based on low-temperature calorimetry data obtained, previously published data on the high-temperature heat capacity of ytterbium orthovanadate were corrected. The anomalous contribution to heat capacity for YbVO₄ was compared with the data known for YbPO₄.     

Measuring changing strain fields in composites with Distributed Fiber-Optic Sensing using the optical backscatter reflectometer

Background/purposeMeasurements of strains in critical components are often required in addition to finite element calculations when evaluating a structure.MethodsThis paper describes how standard optical fibers, bonded to the surface or embedded in a laminate, can measure strain fields along the entire length of the fiber, using the optical backscatter reflectometer.ResultsA strain field measurement can be much better compared to simulations than the more common single point measurements with strain gauges or Bragg Gratings. Changes of the strain field can be related to damage development and can be used for structural health monitoring. Practical aspects of using the fibers are also discussed.ConclusionDistributed Fiber-Optic Sensing was successfully embedded and bonded to a composite joint. Adhesive damage was identified and the strain field agreed well with FE-Analysis.     

Microwave and conventional treatment of low-cement high-alumina castables with different water-to-cement ratio; Part II. Dehydration

Modern refractory castables contain between 3.5 and 5?wt.-% water that is necessary for sufficient flow during emplacement and for the formation of hydrate phases, necessary for the green strength of the material. Prior to the high temperature use of this material, it must be dried very carefully to avoid explosive spalling.This paper will demonstrate that beside conventional drying of pre-shaped materials in resistance furnaces microwave radiation is an energy saving and rapid method to remove pore water as well as hydrate bond water from the castable. In comparison to resistance furnaces, the use of microwave radiation does not affect the castable properties as there are mechanical strength (MOR, CCS), open porosity and pore size distribution. This study proved microwave radiation as valuable alternative with a series of tabular alumina based low cement castables (LLC) in which the water-to-cement-ratio (wcr = 0.64, 0.75, 0.82 and 1.13) was systematically altered by changing the cement concentration at constant mixing water concentration of 4.5%.