H-bond and conformations of donors and acceptors in model polyether based polyurethanes

The molecular mechanics (MM) method with COMPASS force field was used to study the H-bonds in the polyether based polyurethane model molecules. Availability of the calculation was firstly verified in comparison of some H-bonded model molecules, which were studied by using ab initio calculation, and those calculated by MM. Based on a urethane model molecule 1,3-dimethylcarbamate, which can be donor or acceptor and behaves in various conformations, it is reasonable to have a large number of H-bond interactions between various conformational donors and acceptors. For examining all the possible interaction patterns, we studied 57H-bond complexes. This systematic modeling covers well-known four types of interaction patterns, such as NH?OC (Type I), NH?O-CO (Type II), NH?NH (Type III), NH?COC (Type IV) in the system. Obtained H-bond energies were used to analyze the probabilities of the complexes. For the interaction within the hard segments, or Type I, Type II and Type III, a predominant H-bond complex has been found in the present study, which belongs to Type I. For the interaction between the hard segment and the soft segment, two conformations of Type IV were calculated to be existed.     

人工神经网络理论及其应用

简要介绍了人工神经网络的发展过程和基本理论，从神经网络具有自学习功能、联想存储功能和高速寻找优化解的能力三个方面论述了其特点和优越性，详细阐述了在模式识别、信号处理、自动控制、人工智能、自适应的人机接口、优化计算、通信以及其它方面的应用，探讨和分析了其发展前景。     

灰色信息及其运算研究

本文提出了全真信息、信息的亲善性等概念,讨论了信息的有关性质及运算的关系,得到了信息的运算与普通集合运算之间存在着差异的结论,说明了引起该差异的原因.同时,以认知模式为基础,定义了信息函数,并得到了有关的命题及运算.     

The Cooperative Molecular Field Effect

Two‐dimensional arrangements of molecules can show remarkable cooperative electronic effects. Such effects can serve to achieve direct electronic sensing of chemical and physical processes via electrostatic effects, i.e., without transfer of charge or matter between the locus of sensing and that of detection.     

川西马井构造下白垩统含气性识别与评价

川西马进地区下白垩统含气性识别在测井解释上 ,主要在于储层含气水差异分辨较困难 ,气和水在测井曲线上的响应比较接近 ,过去解释的部分气层经测试却产水 ,常规的测井解释方法很难将二者区分开。以钻井录井显示和测试结果为依据 ,利用交会图分析技术 ,成功地对储层含气、水性质进行了识别 ;利用模糊聚类分析技术对含气性差异与含水性差异进行了判别。在此基础上 ,对含气性进行评价。     

数字散斑干涉技术及应用

介绍了数字散斑干涉技术在位移、应变、振动和医学诊断等领域中的应用和国内外发展状况。提出了一种新的应用领域—数字散斑干涉技术在语音识别中的应用,并对该方法作了介绍,讨论了它的特点。     

Classification of hand postures against complex backgrounds using elastic graph matching

A system for person-independent classification of hand postures against complex backgrounds in video images is presented. The system employs elastic graph matching, which has already been successfully applied for object and face recognition. We use the bunch graph technique to model variance in hand posture appearance between different subjects and variance in backgrounds. Our system does not need a separate segmentation stage but closely integrates finding the object boundaries with posture classification.     

Highly Efficient Orange and Green Solid‐State Light‐Emitting Electrochemical Cells Based on Cationic IrIII Complexes with Enhanced Steric Hindrance

Highly efficient orange and green emission from single‐layered solid‐state light‐emitting electrochemical cells based on cationic transition‐metal complexes [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ (where ppy is 2‐phenylpyridine, dFppy is 2‐(2,4‐difluorophenyl)pyridine, and sb is 4,5‐diaza‐9,9′‐spirobifluorene) is reported. Photoluminescence measurements show highly retained quantum yields for [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂ sb]PF₆ in neat films (compared with quantum yields of these complexes dispersed in m‐bis(N‐carbazolyl)benzene films). The spiroconfigured sb ligands effectively enhance the steric hindrance of the complexes and reduce the self‐quenching effect. The devices that use single‐layered neat films of [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ achieve high peak external quantum efficiencies and power efficiencies of 7.1 % and 22.6 lm W^–1) at 2.5 V, and 7.1 % and 26.2 lm W^–1 at 2.8 V, respectively. These efficiencies are among the highest reported for solid‐state light‐emitting electrochemical cells, and indicate that cationic transition‐metal complexes containing ligands with good steric hindrance are excellent candidates for highly efficient solid‐state electrochemical cells.     

基于双因子认证技术的网络身份识别

本文提出了一种基于动态双因子认证技术的网络身份识别方法,用户每次登录的口令是利用系统时间和用户ID通过MD5加密算法计算得到,其通过MD5加密后生成的登录口令是随机的,这将进一步提高开放网络环境下身份识别的可靠性和安全性。同时,本文还提出网络身份识别技术可以应用到各类网站的服务器上,用来完成对用户身份的识别,以提高网络系统的安全性。     

应用遗传神经网络研究低渗透储层成岩储集相—以胜利渤南油田三区沙河街组为例

以渤南油田三区沙河街组为例,应用遗传人工神经网络模式识别方法,开展了低渗透储层成岩储集相的研究。该工作是在储集层沉积相、成岩作用研究的基础上,选用流动层带指标、孔隙度、渗透率、粒度中值、泥质含量、孔喉半径均值和变异系数等7项参数,采用神经网络模式识别方法,通过建立遗传神经网络的学习及预测模型,对渤南油田三区沙河街组进行了成岩储集相识别,识别出4类成岩储集相:不稳定组分强溶解次生孔隙成岩储集相、碳酸盐胶结物溶解次生孔隙成岩储集相、强压实强胶结残余粒间孔成岩储集相和极强压实强胶结致密成岩储集相。Ⅰ类储集相的储集性能最好,Ⅳ类最差,为非储层或差储层。