基于CDT2000 I/O口的A/D转换系统设计

为实现传感器数据快速、高精度地转换,提出了一种采用AD7891芯片的A/D转换系统的设计方法。数据读、写和并行工作时序通过CDT2000 I/O口控制,CDT2000 I/O口的电位变化由PC/104通过总线操作。在AD7891与CDT2000之间添加JK触发器实现对A/D转换完成的识别。试验结果表明,这种方法能够满足数据采集系统的设计要求,并且在硬件上较容易实现。     

The effects of Cl-induced alloying in Pt–Sn/Al2O3 catalysts on butane/H2 reactions

The effects of oxidation/reduction regeneration treatments, with and without 1,2-dichloropropane present as a chlorinating agent, on the structure of Pt(3%)–Sn(4.5%)/Al₂O₃ catalysts have been correlated with selectivities for butane/H₂ reactions. Particles of Pt⁰ fin Cl-free catalysts were partly covered by Sn⁰, but retained exposed ensembles of Pt atoms which were active for isomerisation, hydrogenolysis and dehydrogenation reactions, the latter becoming dominant at high reaction temperatures. Coking reduced Pt ensemble size and, hence, also favoured high selectivities for dehydrogenation as hydrogenolysis and isomerisation sites became poisoned. In contrast, the addition of 1,2-dichloropropane in an oxychlorination step before reduction promoted 1:1 Pt⁰–Sn⁰ alloy formation after reduction, the proportion of the total Pt in alloy being enhanced by increasing 1,2-dichloropropane concentration and oxychlorination temperature. The alloy surfaces were inactive for isomerisation and hydrogenolysis reactions, giving dehydrogenation as the sole catalytic reaction.     

基于S3C6410的远程无线环境监测系统设计

从实际应用出发并结合近年来环境监测技术的发展趋势,设计了一套以S3C6410为主要硬件平台、以嵌入式Linux为主要软件平台的远程环境监测系统。该系统采用B/S架构,具有低成本、低功耗、高稳定的特点。用户通过Internet上的任何终端(如电脑、手机等)来访问该系统,可非常方便地对监测区域进行实时的监测。该系统支持多个用户同时登陆,兼容多种浏览器,具有较高的安全性,在环保行业、制造行业、交通行业的环境监测方面具有一定的推广应用价值。     

低(等)压合成氨的最佳H2/N2与催化活性的关系

采用高压催化剂性能评价实验装置，在压力分别为7.0,10.0和15.0MPa，温度分别为350,400和450℃条件下，在H2／N2为1.6-3.0范围内研究了H2／N2对A301，ZA－5和A110－2型催化剂的活性和合成塔出口氨浓度的影响。在压力和空速一定的条件下，最佳H2／N2随反应温度而异。在350，400和450℃下，最佳H2／N2分别为1.8-2.2,2.2-2.5和2.5-3.0。由此可见，合成氨反应的速率达到最大值时的最佳H2／N2值与反应的进程有关。为此提出了催化剂效率K（Catalysis efficiency)的概念来表征在催化剂作用下反应器出口氨浓度趋近平衡的程度，即K＝CNH3／C^*NH3。根据实验结果，得到了最佳H2／N2与催化剂效率的定量关系：（H2／N2）m=1.5(1 CNH3/C^*NH3)=1.5(1 K)。由此可以根据催化剂在不同反应条件下的催化剂效率来确定最佳H2／N2。凡是会降低催化剂效率的因素，都会使最佳H2／N2降低。各种影响因素对最佳H2／N2的影响中，反应温度的影响最大，其次是空速和催化剂的活性，而压力和惰性气体含量的影响相对较小。在低温（低压）下合成氨，宜采用较低的H2／N2。     

基于浏览器 /服务器的橡胶加工网络测控系统

通过对客户机／服务器模式和浏览器／服务器模式的比较，选择浏览器／服务器模式组建了基于Internt/Intranet的远程橡胶加工网络测控系统，并介绍了系统的开发模式、方法和注意事项。     

Molecular dynamics model structures for the molten globule state of {alpha}-lactalbumin: aromatic residue clusters I and II

To model the molten globule structure of -lactalbumin, moleculardynamics (MD) simulations were carried out for the protein inexplicit water at high temperature. In these simulations, long-rangeCoulomb interactions were evaluated explicitly with an originalmethod (particle–particle and particle–cell: PPPC)to avoid artifacts caused by the cut-off. The MD simulationswere started from two initial conditions to verify that similarresults would be obtained. From the last 150 ps trajectoriesof the two MD simulations, two partially unfolded average structureswere obtained. These structures had the following common structuralfeatures which are characteristic of the molten globule state.The radii of gyration for these conformations were 7.4 and 9.6%larger than that of the native state. These values were almostthe same as the experimental value (9.6%) observed recentlyby small-angle X-ray scattering (Kataoka,M., Kuwajima,K., Tokunaga,F.and Goto,Y., 1997, Protein Sci., 6, 422–430). Furthermore,aromatic residues of clusters I and II in these structures werefar apart from each other except for Try103–Trp104. Thisresult is in good agreement with NMR experimental results forthe acid-denatured molten globule state (Alexandrescu et al.,1992, 1993); that is, NOE signals between the aromatic residueswere not observed, except for that of Try103–Trp104 inthe molten globule state. Other structural features of thesemodels for the molten globule state are discussed with referenceto native state structures.     

Effects of prior knowledge on learning from different compositions of representations in a mobile learning environment

Two experiments examined the effects of prior knowledge on learning from different compositions of multiple representations in a mobile learning environment on plant leaf morphology for primary school students. Experiment 1 compared the learning effects of a mobile learning environment presenting text and photos of plants on a tablet PC, either in combination with or without real plants in the physical environment. Results indicated that there were no interactions between prior knowledge and experimental condition. Students who learned with tablet PCs only outperformed students who additionally learned with real plants on a comprehension and an application test. In addition, high prior knowledge students outperformed low prior knowledge students on both tests. To investigate whether these effects were caused by the specific characteristics of the combination of photos of real plants and real plants, Experiment 2 compared the differential effects of prior knowledge on learning with the combination of texts, photos and real plants to a combination in which the photos were replaced by schematic hand drawings. Results indicated that both low and high prior knowledge students, who learned with the combination of texts, schematic hand drawings and real plants performed better on a comprehension and an application test. High prior knowledge students performed better on both tests. It is concluded that the number and type of representations used is critical for the effectiveness of mobile learning environments.     

有机改性蒙脱土／木粉／PVC复合材料的阻燃性研究

将有机改性蒙脱土（OMMT）加入PVC木塑体系，制备了有机蒙脱土／木粉／聚氯乙烯（OMMT／WF／PVC）纳米复合材料。采用锥形扫描量热测试法研究了OMMT用量对WF／PVC复合材料阻燃性能的影响。结果表明，添加OMMT可明显降低木塑的初始热失重率，但使快速热分解的开始时间提前，大大提高样品的燃烧残余率，显著延迟木塑的点燃时间和燃烧热峰值产生时间，OMMT起到了有效的阻燃作用。OMMT的加入还降低了总燃烧热，但燃烧热峰值有所增加，并使发烟量有所增加，CO和CO2产率也随之提高，增加了木塑燃烧的烟气危害性。     

乙醇对溶胶-凝胶法制备SiO_2溶胶性能的影响

以HNO3为催化剂,用正硅酸乙酯(TEOS)溶胶-凝胶工艺制备纳米多孔二氧化硅薄膜。较详细地研究了工艺参数乙醇/TEOS摩尔比对溶胶性能的影响.结果表明,随着乙醇/TEOS摩尔比的增大,溶胶粘度减小,凝胶时间变长,胶体粒径有变小趋势。     

基于Pro／E参数化斜齿轮建模技术

应用Pro／E软件的参数化造型功能，不需要二次开发，直接创建渐开线斜齿圆柱齿轮模型，对直齿、人字齿齿轮的建模具有借鉴作用。