Plasma Induced Degradation of Benzidine in Aqueous Solution

The degradation of benzidine in aqueous solution by the low temperature plasma was examined. The results showed that the concentration of medium and the value of pH have an appreciable effect on the degradation of benzidine. What is more important is that iron ions acting as a catalyst play an important role in this reaction. For exploring the degradation mechanism of benzidine, some of the intermediate products were recorded by HPLC (high performance liquid chromatography).     

易染性共聚醚酯热氧化稳定性研究

分析了高聚物的氧化裂解机理及抗氧化剂的作用原理。选择了对提高共聚醚酯的热稳定性较为有效的复合抗氧化剂，用测定该共聚醚酯的特性粘度和端羧基含量改变的方法来表征分子量的变化，证实了抗氧剂的作用机理和复合抗氧化剂之间的协同效应     

臭氧降解低浓度四溴双酚A及生物毒性控制

为考察臭氧氧化技术对水中低质量浓度四溴双酚A的降解和毒性控制效能,利用臭氧反应装置研究不同pH和臭氧投加量条件下四溴双酚A(质量浓度为0.15 mg/L)的降解效果,考察反应过程中水样的急、慢性毒性和遗传毒性的变化规律及控制效果,分析毒性变化内在原因,并提出可能性降解机理.结果表明,当溶液pH为7.0、臭氧投加量为0.12 mg/L,四溴双酚A可被完全降解.反应初期,水样的急、慢性毒性迅速升高,原因主要是产生了毒性更高的有机中间产物;随着反应的进行,有毒中间产物被深度降解,急、慢性毒性均得到有效控制,且随着臭氧投加量的增加毒性控制得更快、更显著.当臭氧投加量为0.12 mg/L时,急性毒性在反应20 min时即可被完全控制,慢性毒性在反应60 min也被控制至0.76 TU,反应后水样的急、慢性毒性均满足排放标准.反应过程中水样的致突变比均小于2.0,不具有基因水平的遗传毒性.降解机理分析表明,臭氧降解四溴双酚A主要包括脱溴、β位断裂、加成、去羟基化、甲基化等反应过程.     

十红滩铀矿床有机地球化学特征及与铀成矿作用

十红滩铀矿床属层间氧化带砂岩型铀矿床,赋存于中侏罗统西山窑组含煤碎屑岩中。容矿层岩石中富含有机质,有机碳、可溶有机物、酸解吸附烃在不同地球化学分带的岩石中含量大小不同,尤以氧化还原过渡带含量最高。矿石有机质母质类型为腐殖型,处于未成熟演化阶段,酸解吸附烃为煤成气型。统计计算表明:容矿层中铀和可溶有机物、酸解吸附烃含量之间具明显的相关关系。分析了有机质在砂岩型铀矿床形成过程中的作用,认为容矿层中有机质在含氧环境下分解的产物利于铀在水中的溶解和迁移,而在缺氧条件下分解的产物,构成铀沉淀的还原和吸附地球化学障,在铀的成矿过程中发挥重要的作用。     

重庆市荆襄式磷矿地质特征及成矿规律分析

重庆市荆襄式磷矿主要分布在渝东北的城口—巫山一带。评述了该类磷矿地层、构造、成矿特征等,总结了荆襄式磷矿成矿规律,为重庆市磷矿资源找矿及预测提供参考。     

PTFE的辐射裂解、交联及其应用

聚四氟乙烯（PTFE）是一种性能优异的工程塑料,通常被认为是典型的辐射裂解材料。PTFE可以在不同条件下实现裂解并生成PTFE微粉。在高于PTFE的熔点即温度为330～340℃,真空或惰性气氛下进行辐照,可实现PTFE的交联。本工作综述了PTFE辐射裂解和交联研究的历史和最新进展,并对交联PTFE在润滑材料、燃料电池、光刻等领域的应用进行了介绍。     

Gamma过程退化模型估计中测量误差影响的仿真研究

研究产品性能退化规律并评估其剩余寿命和可靠性特征是维修决策的重要前提和依据。Gamma过程退化模型在性能退化建模和维修最优化方面得到了广泛研究和重视。但是很少考虑测量误差对模型估计的影响。由于观测数据常常受到测量不确定性的影响,所以如果在Gamma退化过程的构造中没有考虑测量误差的影响,就会导致退化动力学的有偏估计。为此,利用EM算法提出了1种统计方法,利用了可以获取的量测信息来克服以上不足。仿真研究说明了考虑测量不确定性的重要性和提出方法的有效性。另外,提出的统计方法也可以被应用于许多类型的随机过程退化模型。     

A π-extended tetrathiafulvene derivative: Synthesis and photoluminescence properties

Solid-state emissive organic materials have received increasing attention due to their prospective applications in large-area. Here, a novel π-extended tetrathiafulvene derivative DPD with donor-π-donor structure has been newly developed to produce the prominent characteristic of aggregation-induced enhanced emission (AIEE) that exhibits higher fluorescence quantum efficiency in solid film compare to its solutions. The AIEE mechanism of DPD was studied in detail through photophysical investigations and can be dominant attributed to the formed excimer state of DPD and J-aggregates in solid state.     

纳米钛酸锶的制备及超声降解碱性品红废水研究

以硝酸锶、钛酸四丁酯、柠檬酸和乙二醇为原料,采用络合溶胶-凝胶法制备钛酸锶纳米粉体,借助粉末X射线衍射仪(XRD)、扫描电子显微镜(SEM)对产物进行表征。对产品降解碱性品红的性能进行研究,对比试验了无钛酸锶、不同钛酸锶添加量、不同双氧水加量对一定浓度碱性品红降解率的影响。结果表明:碱性品红浓度为40mg/L,钛酸锶用量为1g/L,双氧水为5mL/L时,超声降解10min,碱性品红降解率达97.7%,且回收7次重复使用降解效果仍在95%以上。这种方法对处理三苯甲烷类染料废水有一定实用参考意义。     

Binuclear aluminum complex as an efficient orange emitter in single-layer electroluminescent devices

A binuclear aluminum complex with a chelating anilido-imine conjugated Schiff base ligand, 1,4-{o-C₆H₄[N(2,6-ⁱPr₂C₆H₃)][CH  N]Al(CH₃)₂}₂C₆H₄ (3), was synthesized from the alkane elimination reaction of trimethylaluminum with the free ligand, 1,4-{o-C₆H₄[NH(2,6-ⁱPr₂C₆H₃)][CH  N]}₂C₆H₄ (2), at room temperature. The photophysical properties of complex 3 were briefly examined and it was found that complex 3 displays bright orange luminescence in solution and in solid state. Electroluminescent devices were fabricated by doping complex 3 in polymer blend host of poly(vinylcarbazole) and 2-tert-butylphenyl-5-biphenyl-1,3,4-oxadiazol using simple solution spin-coating technique. Efficient orange light emission was obtained from the fabricated single-layer organic light-emitting devices with a maximum current efficiency of 3.2 cd/A.