单元系T—p相图的数学结构

作者以化学元素的稳定单质为基准,推演出了任意物质M_i(相态Ω)的热力学生成活度{相态Ω)的函数形式:?D_Ω数值的大小体现着相态Ω的热力学相对稳定性.根据集合论原理沿D(稳定性)座标取极大值的方法把物理性质互不连续的各个异相态连结在一起,建立了单元系在T-p面上的优势分布方程(PSDE):■作者以H_2O为实例,计算了T-p相图,与实验相图基本一致.     

Continuous formation of slurry ice by cooling water–oil emulsion in a tube

Water-silicone oil emulsion with an additive, (C₂H₅O)₃SiC₃H₆NH₂, was examined as a heat storage material. A spiral tube used as a heat exchanger was immersed in a low temperature bath and the emulsion was circulated in the tube to make ice continuously. Ice was separated from the ice–liquid suspension in an outlet tank. The amount of formed ice, the temperatures of the inlet and the outlet of the heat exchanger, and the temperatures in the tube wall were measured and the overall heat transfer coefficient and the heat flux through the tube were calculated. Experiments were carried out, varying the flow rate, the temperature of cooling brine, and the thickness of tube wall. The condition under which slurry ice was formed continuously without adhesion of ice to the cooling wall was clarified. Though decrease in the thermal resistance of the tube increased the rate of ice formation or raised the brine temperature, it narrowed the range of the flow rate and of the brine temperature in which slurry ice was formed continuously.     

自适应相位制中波同步广播及现场试验

在本试验中，采用智能同步广播激励器和ＣＣＴＶ传输的１ＭＨｚ标频，实现了中波同步广播同频保护率趋于０ｄＢ．并提出了自适应相位跟踪同步的概念。     

一种混沌信号去噪方法的研究

以Takens嵌入定理和影子定理为理论依据，提出一种能对混沌信号去噪的局部投影方法。该方法不需潜在动力学系统的先验知识，符合工程实用的要求。通过实验结果表明这种方法对混沌信号去噪很有效。     

受干扰波相位测量的一种新方法

为了测量受噪声和谐波干扰的两个信号间的相位差，基于自适应带通滤波器（ABF）和测量信道交换技术，提出了一种新的测量方法。ABF采用可编程开关电容滤波器（PSCF）和锁相环，明显地抑制了噪声和谐波干扰，频率跟踪范围超过四个倍频程（0．5Hz-6kHz）。用微处理器控制4个开关来交换测量信道，可以基本上消除测量通道引入的附加相位移。两种方法结合提高了相位差的测量精度。实验说明了该测量方法的有效性，该方法也适合于被测信号为慢时变情况。     

中频数字化及数字式正交解调

本文介绍用数字式下变频法实现中频正交解调的基本原理及主要性能。     

Impurity Distribution Behavior in Caprolactam Extraction with Environmentally Benign Mixed Solvents

In a previous study a solvent mixture of heptane containing 40 mass % heptanol was selected as an alternative in the industrial extraction of caprolactam to replace benzene, toluene, or chlorinated hydrocarbons. This work reports the equilibrium distribution ratio of caprolactam and four model impurities of organic nature, namely, cyclohexanone, aniline, n‐methylcaprolactam, and cyclohexane‐carboxamide, comparing the mixed solvents with toluene as a reference. The resulting phase equilibria were interpreted using the equilibrium stage model. Based on these calculations it was found that, compared to toluene, the co‐extracted fraction of cyclohexanone and aniline was higher, that of n‐methylcaprolactam was comparable, and that of cyclohexane‐carboxamide was lower using the mixed solvent. Overall, the mixed solvent reduced the fraction of co‐extracted impurities by almost 10 %.     

Studies on the corrosion behavior of cerium-implanted zircaloy-4 with GAXRD

In order to study the influence of cerium ion implantation on the aqueous corrosion behavior of zircaloy-4, specimens were implanted by cerium ions with a fluence range from 1×10¹⁶ to 1×10¹⁷ ions/cm² at maximum 150°C, using MEVVA source at an extracted voltage of 40 kV. The valence and elements penetration distribution of the surface layer were analyzed by X-ray photoelectron spectroscopy (XPS) and auger electron spectroscopy (AES) respectively. Glancing angle X-ray diffraction (GAXRD) was employed to examine the phase transformation due to the cerium ion implantation in the oxide films. Three-sweep potentiodynamic polarization measurement was employed to value the aqueous corrosion resistance of zircaloy-4 in a 1 N H₂SO₄ solution. It was found that a significant improvement in the aqueous corrosion behavior of zircaloy-4 implanted with cerium ions compared with that of the as-received zircaloy-4. The improvement effect will declined with raising the implantation fluence. The bigger is the fluence, the less is the improvement. Finally, the mechanism of the corrosion behavior of the cerium-implanted zircaloy-4 is discussed.     

高频地波雷达相位补偿系统

OSMAR2000采用的是“一发八收,收发共用”模式的相控阵高频地波雷达.为了扩大其探测的范围,在新的雷达系统中将采用多发多收的模式,从而导致当信号通过通道后,信号的相位会因受到通道的调制而发生改变,使得雷达无法正常工作,因此需要对通道的相位进行实时监控和补偿.在参考了低频段的相位测量原理和射频段的相移电路的设计理论的基础上,该文提出了基于差分放大器、容阻和容感器件的高频地波雷达收发通道的相位控制系统.