Laser irradiation of oligosiloxane copolymer thin films functionalized with side chain bulky carbosilane moieties

Linear oligosiloxanes functionalized with bulky side chain tris(trimethylsilyl)hexyl (TTSH) substituents were transformed into cross-linked materials by UV 193 nm excimer pulsed laser ablation. The process occurred without any catalyst, by reactions of radicals formed in UV laser induced photolysis of side tris(trimethylsilyl)hexyl groups. Chemical changes were monitored by FTIR, LC/UV, GC/MS and solubility tests.     

Correlation of vibrational intensity with fluorescence lifetimes in π conjugated polymers

A series of novel pi (π) conjugated polymers, originating from the archetypical Polyphenylene vinylene, in which the phenyl units are successively replaced by the larger naphthyl and anthryl acene units, were previously found to have a well-defined relationship between their relative fluorescence yields and their vibrational characteristics, as determined by Raman spectroscopy. In this study the Strickler-Berg equation is used to probe the influence of continual substitution of higher order acene units into the conjugated backbone in terms of the variation of the radiative and non-radiative rates. The deconvolution of the radiative and non-radiative rates enables the correlation of the reduction of the Raman intensity and concomitant increase in the fluorescence yield with the reduction of the non-radiative rate. This confirms that the reduction of the non-radiative rate is the dominant process introduced by the vibrational confinement originating from systematic substitution of higher order acene units into the polymer backbone.     

无氢类金刚石碳膜的研究进展

介绍了无氢类金刚石碳膜的制备方法 ,它们的机械、光学、电学性能 ,将无氢与含氢的类金刚石碳膜进行了简单比较 ,总结及探讨了它们的应用     

短脉冲激光与岩石相互作用机理初探

石油开采过程中，为增大原始岩体的渗流速度，一般采用水压致裂或射孔弹的方法来加以实现，但两种方法都存在一定缺陷。为探索一种新概念石油开采技术，即采用激光技术增大原始岩体的渗透率，对短脉冲激光辐照自然、饱水和饱油状态的花岗岩、大理岩和红砂岩的响应作了初步研究。得到了激光辐照下，岩石试样内烧蚀坑的三维形态以及烧蚀状态与脉冲数的初步关系。结果表明：脉冲激光可以在试样局部产生一定的裂纹；饱油试样的烧蚀情况较饱水和自然状态更严重。但对于产生的裂纹数量，尺寸以及方向等方面的控制尚需进一步的工作。     

激光角膜矫正术中所用激光波长的选择

用分光光度计测定了12例兔角膜和1例人角膜的吸收光谱,结果表明波长小于300nm的准分子激光和波长在1.88μm～2.64μm,2.36μm～40μm的激光,均可对角膜进行切割并可望用于激光角膜矫正术。     

激光束偏转法检测金属表面层的缺陷

本文编程计算了由激光光热应产业的金属表面的温度分布和泵浦光的调制频率、金属层厚度等的关系，预言检测浓度缺陷的能力。用激光光束偏转法检测到表面下不同深处的缺陷，并把面扫描幅值信号以三维象和灰度象显示。     

铸铝激光熔融处理后的组织与性能

应用光学和电子显微镜及显微硬度计研究了铸造Al-Si合金经激光表面熔融处理后的组织和性能。指出,组织分熔化区、过度区和基体三层。在熔化区中树枝状先共晶α相的平均宽度由原始组织的20～40μm细化到2～3μm,同时共晶组织也被大大细化。这些变化使显微硬度值由67.4提高至109～115.     

自聚焦光纤对半导体激光束的准直研究

介绍了一种新颖的利用自聚焦光纤对半导体激光束的准直技术。该方法结构简单、调整方便。实验研究表明其可使大发散角的半导体激光束压缩到0.01º的数量级,适合作半导体激光器的准直元件而运用于精密测试领域。     

激光诱导H_2S催化裂解制备H_2的研究

在室温常压静态条件下研究了以Ｖ２Ｏ５／ＴｉＯ２为催化剂，紫外脉冲激光诱导Ｈ２Ｓ催化分解为Ｈ２和Ｓ的反应及其机理。考察了产氢量与激光不同照射条件之间的关系。     

人造导星技术及导星用激光系统

论述了自适应光学系统对人造导星的需要;简单介绍了两类激光导星;重点描述了销激光导星的产生机理及可用于销激光导星的一些激光系统.