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SCR烟气脱硝自动控制系统及其在三河电厂的应用 总被引:1,自引:0,他引:1
论述了国华三河电厂二期2×300MW机组脱硝工程采用的选择性催化还原脱硝工艺。对脱硝系统的工艺环境、控制方案等进行了详细的介绍。 相似文献
105.
孙燕朴 《青岛大学学报(工程技术版)》1989,(2)
本文主要介绍了一种三相可逆可控硅速调数字触发电路的原理。其特点是结构简单可靠,精度较高,体积小。用脉冲列触发可控硅。 相似文献
106.
Ammonium bisulfate formation temperature in a bench-scale single-channel air preheater 总被引:2,自引:0,他引:2
Ammonium bisulfate (ABS) forms in coal-fired power plant exhaust systems when ammonia slip from the NOx control system reacts with the sulfur oxides and water in the flue gas. The critical temperature range for ABS formation occurs in the air preheater, where ABS is known to cause corrosion and pluggage that can require unplanned outages and expensive cleaning. To develop mitigation strategies for the deleterious effects of ABS in air preheaters, it is important to know its formation temperature and deposition process. This paper describes a bench-scale experimental simulation of a single-channel air preheater, with the appropriate temperature gradient, used in conjunction with simulated coal combustion flue gas, including sulfur oxides, ammonia, and water vapor, to investigate the formation of ABS. Formation was observed optically, and the formation temperature, as well as deposition characteristics for a realistic range of reactant concentrations are presented and compared with previous studies on ABS formation. This study presents data at realistic concentrations not earlier tested, and the reported data has smaller experimental uncertainty than previously obtained. We found that the measured ABS formation temperatures under air preheater channel conditions lies between the temperatures reported by others, and is in the range of 500-520 K for typical flue gas concentrations of ammonia and sulfur oxide species. The results also show that, at least for this experimental configuration, ABS forms predominantly as an aerosol in the gas phase rather than as a condensate on the channel walls. 相似文献
107.
The UV spectra of tungsten oxide catalysts supported on alumina, titania and zirconia, and on titania–alumina and titania–zirconia mixed oxides are reported and discussed. Evidence is provided for the different electronic structure of supports and catalysts, which could affect the behavior of the tungsten oxide centres in the different cases. On alumina, tungsten oxide centres are “isolated” by the insulating support, while on titania-based materials they are likely in electronic contact with each other and with Ti centres through the support conduction band. In the case of WOx2013;ZrO2, the 5d levels of tungsten ions fall just below of the lower energy limit of the support conduction band. This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
108.
Reduction of NOx over Fe/ZSM-5 catalysts: mechanistic causes of activity differences between alkanes
Fe/ZSM-5 catalysts prepared by sublimation of FeCl3 onto H/ZSM-5 catalyze the selective reduction of NOx by hydrocarbons to N2. The order of the relative rates and N2 yields obtained with different alkanes reveals a non-trivial chemistry. The maximum yield is lower for propane than for n-butane but about the same for n- and iso-butane. However, at temperatures below this maximum, the N2 yield is higher for propane and n-butane than for iso-butane. Deposits are formed on the catalyst that contain N atoms in a low-oxidation state which are able to react with NO2 to form N2. TPO and FTIR results show that the amount and also the character of the deposits depend on the nature of alkanes. The change of the oxidation state of nitrogen from a high value in NO or NO2 to a lower value in nitrile and amino groups of the deposit is rationalized by applying mechanistic concepts of organic chemistry, including the Beckmann rearrangement and fragmentation. FTIR spectra and the observed oxygen- and nitrogen-containing compounds by GC-MS are potential clues to the reaction mechanism. 相似文献
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Selective catalytic reduction as one of the secondary NOx control technologies is widely used in industrial sources including coal-fired power plants and large boilers. The performance of an SCR-DeNOx system is sensitive to the installment of its components such as turning vanes and hybrid grids. In this work, three-dimensional CFD simulations are carried out to analyze the breakage failure of an SCR-DeNOx system for a certain 350 MW coal-fired power plant. Research results are consistent with the phenomena that occur in the industrial application. It reveals that the breakage failure in the industrial application is likely to be caused by the inappropriate installation of the turning vane 3 locating closest to the catalyst, especially the angle of the turning vane 3. The analysis further shows that the lifetime or the breakage of the catalyst layers depends highly on the gas velocity, the fly ash distribution and its particle velocity. 相似文献