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71.
The effect of NiCoCrAlY overlay coatings on the oxidation resistance of γ-TiAl was studied at 900 ℃ in static air. To hinder the interdiffusion of the elements, the Al/Al2O3 layer was added between the coating and the alloy. The results show that the TiAl alloy exhibits poor oxidation resistance. NiCoCrAlY coating can not effectively protect the γ-TiAl substrate from high temperature oxidation because of the serious interdiffusion between the coating and the substrates. With Al/Al2O3 diffusion barrier, the NiCoCrAlY coating exhibits excellent oxidation protection on γ-TiAl alloy. 相似文献
72.
To testify to the advantage of large ceramic powder spraying, numerical simulations and experimental studies on the behavior
of large yttria-stabilized zirconia (YSZ) powder in a high-power hybrid plasma spraying process have been carried out. Numeric
predictions and experimental results showed that, with the high radio frequency (RF) input power of 100 kW, the most refractory
YSZ powder with particle sizes as large as 88 μm could be fully melted and well-flattened splats could be formed. A large
degree of flattening (ξ) of 4.7 has been achieved. The improved adhesive strength between the large splat and the substrate
was confirmed based on the measurement of the crack density inside of the splats. A thick YSZ coating >300 μm was successfully
deposited on a large CoNiCrAlY-coated Inconel substrate (50×50×4 mm in size). The ultradense microstructure without clear
boundaries between the splats and the clean and crack-free interface between the top-coat and the bond-coat also indicate
the good adhesion. These results showed that highpower hybrid plasma spraying of large ceramic powder is a very promising
process for deposition of highquality coatings, especially in the application of thermal barrier coatings (TBCs). 相似文献
73.
T.J. Nijdam 《Surface & coatings technology》2006,201(7):3894-3900
A combined pre-annealing and pre-oxidation treatment was developed for the processing of partially yttria stabilized (PYSZ) thermal barrier coatings (TBC) on top of NiCoCrAlY bond coatings (BC). To develop this pre-treatment, the influence of the oxygen potential during pre-annealing and pre-oxidation on the life span and failure mechanisms of the entire high temperature coating system upon thermal cycling was investigated. The results of this study showed that the service life of the coating system depended strongly on the composition and microstructure of the thermally grown oxide (TGO) after pre-oxidation. The longer life spans were obtained if the TGO thickened very slowly during thermal cycling due to a large α-Al2O3 grain size. Such a slow-growing TGO corresponded with a pre-treatment for which θ-Al2O3 was formed during pre-oxidation and for which the yttrium was located within a high density of pegs along the TGO/BC interface after pre-oxidation. If the yttrium was present on top of the TGO after pre-oxidation, a thick mixed alumina-zirconia layer formed upon thermal cycling. This mixed oxide layer contributed significantly to the total oxide layer thickness, resulting in short life spans. The formation of NiAl2O4 spinel in between the TBC and the α-Al2O3 should be avoided, since this can lead to premature failure along the spinel/α-Al2O3 interface. 相似文献
74.
75.
A durable ceramic thermal barrier coating is applied directly to a smooth, highly oxidation resistant intermetallic alloy
in two layers. The first layer of ceramic is applied by low pressure plasma spraying and the second layer is applied by conventional
atmospheric pressure plasma spraying. This approach would allow the use of plasma sprayed ceramic coatings in applications
where a metallic bond coat is not desirable. 相似文献
76.
The mismatch between the thermal expansion coefficients of ceramics and metals and the differential stresses it causes at
the interface create problems in metal to ceramic joining. Research has been con-ducted to solve this problem in thermal barrier
coating technology. Previous studies have considered met-al-ceramic multilayers or graded-coatings, which include a metallic
bond coat. In this study, a graded plasma-sprayed metal-ceramic coating is developed using the deposition of premixed metal
and ceramic powders without the conventional metallic bond coat. Influences of thickness variations, number, and composition
of the layers are investigated. Coatings are prepared by atmospheric plasma-spraying on In-conel 718 superalloy substrates.
Ni-Cr-Al and ZrO2 -8 % Y2O3 powders are used for plasma spraying. Ad-hesive and cohesive strength of the coatings are determined. The concentration profile
of the elements is determined by x-ray energy-dispersive analysis. The microstructure and morphology of the coatings are investigated
by optical and scanning electron microscopy (SEM). Results show that the mixed metal-ce-ramic coating obtained with the deposition
of premixed powders is homogeneous. The morphology and microstructure of the coatings are considered satisfactory. 相似文献
77.
Thin DLC films coated on polymer surfaces are attracting considerable attention due to their wide applications and their interesting surface properties. When DLC films were coated on polymers, the resulting DLC-polymer composites are highly functionalized materials, some of which presenting dramatically improved gas barrier properties.In this paper, we will introduce several commonly used polymers including polyethylene terephthalate (PET), polyethylene (PE) and polypropylene (PP) for semi-crystalline polymers, and polymethyl methacyrlate (PMMA) for an amorphous polymer. The polymers were coated with thin DLC films and the gas barrier properties of the resulting DLC-polymer composites were investigated. Some of the DLC-polymer composites dramatically improved their gas barrier properties while they presented horizontal crack lines and vertical micro-buckling lines on the DLC surface when stretched to a certain strain. The gas barrier properties of the DLC-polymer composites with fractured DLC surface were also studied. It was found that the gas barrier property of the polymer substrates with lower residual strains was less damaged, when the substrates were mechanically deformed, than that of the polymer substrates with higher residual strains. When the number of the cracks increases, the strain imposed on each crack decreases, since the overall deformation is almost equally distributed to each crack while the crack spacing of each crack becomes shorter. Thus, it was found that the degradation of the gas barrier property after mechanical deformation is dependent on the residual strain of the polymers and the number of cracks on DLC films. 相似文献
78.
Life time dependency on the pre-coating treatment of a thermal barrier coating under thermal cycling
A thermal barrier coating system consisting of the single crystalline Ni-based superalloy CMSX 4, a Pt aluminide bond coat and an EB-PVD processed ceramic top coat was thermally cycled in order to study the influence of three different treatments prior the deposition of the ceramic top coat. Besides the standard treatment, one type of treatment was annealing in vacuum, while the other was annealing in an O containing ArH atmosphere; in both cases for 4 h at 1080 °C.Compared to the standard treatment, annealing in vacuum almost doubled and annealing in ArH atmosphere almost tripled the cyclic life time of the ceramic coating. The improvement was related to the creation of a defined alumina scale before and during TBC deposition. 相似文献
79.
TBC experience in land- based gas turbines 总被引:1,自引:0,他引:1
This paper summarizes prior and on-going machine evaluations of thermal barrier coatings (TBC) for power generation, that
is large industrial gas turbine applications. Rainbow testing of TBCs on turbine nozzles, shrouds, and buckets are described
along with a test of combustor liners. General Electric Power Generation has conducted more than IS machine tests on TBC turbine
nozzles with various coatings. TBC performance has been quite good, and additional testing, including TBCs on shrouds and
buckets, is continuing. Included is a brief comparison of TBC requirements for power generation and aircraft turbines. 相似文献
80.
氧化物掺杂YSZ热障涂层的最新研究进展 总被引:1,自引:0,他引:1
随着先进航空发动机涡轮叶片热障涂层服役温度、服役寿命以及隔热性能的不断提升,研制温度高、使用寿命长和隔热性能优异的热障涂层材料,已成为国际高温防护涂层领域的研究热点。氧化物掺杂YSZ涂层因其良好的热学性能,成为最有可能替代YSZ涂层在航空发动机热端部件表面获得应用的热障涂层材料。综述了氧化物掺杂YSZ热障涂层研究取得的成果和存在的问题,重点阐述了不同氧化物掺杂对YSZ涂层性能的影响机理,并简述了目前国内外对该类涂层相关制备技术的研究进展。提出未来关于热障涂层的研究,应在进一步优化设计多元氧化物掺杂改性YSZ涂层的基础上,结合计算模拟,对多元氧化物掺杂的耦合作用机制进行深入剖析,同时结合新一代高温合金的性质,发展高温合金-粘结层-陶瓷层相匹配的新型热障涂层体系,从热力学-动力学两个方面考察其使役行为和失效机制,最终促进该类涂层的实际应用。 相似文献