2,2,6,6-四甲基-4-甲氧基哌啶氮氧自由基制备方法的改进

阐述了一种制备 4 -甲氧基 -2 ,2 ,6 ,6 -四甲基哌啶氮氧自由基的改进方法 :以四氢呋喃为溶剂 ,0℃时 ,在N2 的保护下和NaH的存在下 ,2 ,2 ,6 ,6 -四甲基 -4 -羟基哌啶氮氧自由基与MeI在室温反应 5h。分离混合物 ,得到粘稠状红色液体 ,加入正己烷 ,在 -2 0℃条件下储存 ,结晶出针状深红色的晶体。熔点 :4 2～ 4 3℃ ,产率 70 %以上     

Structural characterization of Ti centres in Ti-silicalite and reaction mechanisms in cyclohexanone ammoximation

The main results obtained by means of many physical methods (IR, Raman, UV-Vis and XAFS spectroscopies) concerning the structure of the Ti centre in titanium silicalite and the reaction intermediates in the ammoximation of cyclohexanone are concisely reviewed.

The Ti is in tetrahedral coordination in vacuo and expands its coordination sphere upon interaction with adsorbates. In the presence of H₂O and H₂O/H₂O₂ solutions one of the SiOTi bridges is hydrolyzed with formation of (SiO)₃L₂TiOH (LH₂O) and (SiO)₃L₂TiOOH species, respectively. When NH₃ is dosed on (SiO)₃L₂TiOOH structures (SiO)₃L₂TiOO⁻NH₄⁺ species are formed. These species are thought to play an important role in the ammoximation reaction. The geometries of the peroxidic species (open or bridged) are discussed also on the basis of ab initio calculations.     

Kinetics of the selective catalytic reduction of NO by NH3 on a Cu-faujasite catalyst

The kinetics of the selective catalytic reduction (SCR) of NO by NH₃ in the presence of O₂ has been studied on a 5.5% Cu-faujasite (Cu-FAU) catalyst. Cu-FAU was composed of cationic and oxocationic Cu species. The SCR was studied in a gas phase-flowing reactor operating at atmospheric pressure. The reaction conditions explored were: 458<T_R<513 K, 2503 (ppm) < 4000, 12 (%) < 4. The kinetic orders were 0.8–1 with respect to NO, 0.5–1 with respect to O₂, and essentially 0 with respect to NH₃. Based on these kinetic partial orders of reactions and elementary chemistry, a wide variety of mechanisms were explored, and different rate laws were derived. The best fit between the measured and calculated rates for the SCR of NO by NH₃ was obtained with a rate law derived from a redox Mars and van Krevelen mechanism. The catalytic cycle is described by a sequence of three reactions: (i) Cu^I is oxidized by O₂ to “Cu^II-oxo”, (ii) “Cu^II-oxo” reacts with NO to yield “Cu^II-N_xO_y”, and (iii) finally “Cu^II-N_xO_y” is reduced by NH₃ to give N₂, H₂O, and the regeneration of Cu^I (closing of the catalytic cycle). The rate constants of the three steps have been determined at 458, 483, and 513 K. It is shown that Cu^I or “Cu^II-oxo” species constitute the rate-determining active center.     

一种改进的VI CFAR检测器

为得到不同杂波背景下的良好检测性能,给出了一种改进的VI CFAR检测器.该检测器主要利用均值类可变性指示（MLVI）CFAR检测器和有序统计类可变性指示（OSVI）CFAR检测器的各自优点以及VI CFAR的以背景均匀程度自动选择不同检测器思想.理论分析和仿真结果表明：该检测器在均匀背景下性能基本与MLVI CFAR重合;多目标背景下具有较强的抗多目标能力;杂波边缘背景下有较好的虚警概率控制能力且运算量小,是一种稳健的检测器.     

高速机车车辆的车轴数字化超声波探伤系统

针对高速机车车辆车轴的超声波探伤提出一种新的超声波探伤方案．将组合探头装置安装在车轴的端面上,用机油作耦合剂,准确定位,保证探头在扫查时超声波主声束始终穿过车轴的中心线,使主声束与裂纹相交,便可对车轴进行探伤．该系统检测机车车轴具有准确度高,精度高,效率快的特点．     

停车诱导信息系统信息采集技术研究

信息采集是停车诱导信息系统的重要组成部分,准确可靠的信息是停车诱导信息系统实现诱导功能的重要前提,文章对停车诱导信息系统的采集技术进行了综合比较和分析,总结了各种采集技术的优缺点和适用范围,并提出了采集技术的选择流程。     

简易人体穴位识别治疗仪

为了解决非专业人群寻找穴位难、不准确、不易操作等难题,设计了一种以SPCE061A为核心MCU（Micro Control Unit）的简易人体穴位识别治疗仪。给出了系统结构和实现流程,提出了一种基于层次分析原理的新型穴位检测方法,并讨论了环境因素对穴位识别结果的影响。通过人体穴位检测实验表明,本系统的穴位与非穴位正确识别率可分别达到95%和98%以上,且输出频率可调、波形可变的脉冲电压可达到模拟中医针灸治疗的作用。与传统找穴位方法相比,该方案具有操作简单、功耗低、性价比高等优点。     

湿度对CR-39固体核径迹探测器测量^220Rn／^222Rn水平的影响研究

在可调控温度、湿度及氡浓度的南华大学氡实验室对不同的湿度条件下CR-39固体核径迹探测器测量^220Rn、^222Rn的探测效率进行了测定,分析了湿度对CR-39固体核径迹探测器测量^220Rn、^222Rn探测效率的影响．实验结果表明：相对湿度在35％-95％范围内,当湿度为50％左右时,CR-39固体核径迹探测器测^222Rn,探测效率最高,标准偏差为2．0％;相对湿度在30％-100％范围内,当湿度为75％时,CR-39固体核径迹探测器测^220Rn的探测效率最低,标准偏差达到78．4％．     

混合匹配规则的否定选择算法

针对目前基于免疫的检测器生成算法中,匹配规则单一造成的检测器质量低下的问题,提出一种基于混合匹配规则的否定选择算法,采用海明距离整体匹配的各段内R连续比特匹配的否定选择算法,即混合匹配否定选择算法,对算法的性能进行了分析．实验结果表明,该算法能够高效地产生所需要的检测器,提高了检测率,且降低了误报率．     

ZYBG型矿用瓦斯输送管道自动抑爆装置研制

为了保障瓦斯输送管道的安全性,采用主动抑爆技术研制了ZYBG型矿用瓦斯输送管道自动抑爆装置。该装置利用火焰探测器探测瓦斯爆炸信号,并将信号通过光电转换传输给控制器,控制器对信号进行判定和分析,在爆炸接近防护区间的瞬间快速打开高压抑爆器,释放抑爆介质,熄灭火焰,阻断爆炸的进一步传播。抑爆性能试验结果表明,该抑爆装置能够在5ms内快速捕捉火焰信息,并在35ms内迅速喷洒抑爆介质。