“四缘”文化视域下的景德镇民窑生产

景德镇是移民城市,在千年陶瓷业生产历史中,来自＂四方八域＂的移民为景德镇陶瓷生产做出了重大贡献,成就了千年＂瓷都＂辉煌。在陶瓷生产中,来自各地的瓷业从业人员按照地缘、血缘、业缘、志缘结合起来,实现自身利益的最大化。     

高拉伸强度高伸长率丁羟弹性体的研究进展

综述了影响丁羟弹性体力学性能的几种关键因素,包括固化参数、固化剂类型、扩链剂类型等,对比了几种提高丁羟弹性体力学性能的方法及其研究进展。提出了通过合成具有不同官能度的窄分子质量分布的丁羟液体橡胶,并进行复配研究,将是制备高拉仲强度、高伸长率丁羟弹性体的研究方向。     

淀粉基生物降解塑料吹膜工艺及性能研究

通过挤出吹膜的方法制备PBSA/TPS淀粉基生物降解塑料,研究了不同风环结构及吹胀比和牵引比对于吹膜及性能的影响。结果表明:双风口风环可以极大提高PBSA/TPS材料的吹膜膜泡稳定性,而随着吹胀比和牵引比的增大,薄膜的拉伸强度、断裂伸长率和耐撕裂力先增大再减小。     

对甲苯磺酸多聚甲醛固体酸催化Micheal加成的研究

对甲苯磺酸直接缩聚合成聚合物型高酸值的碳基固体磺酸催化剂。用Michael加成反应对催化剂的催化性能进行了研究。结果表明,该催化剂具有适用范围广泛、重用性好、化学选择性高等优点。     

实验实训室建设方案的整体设计与探索

为适应区域经济发展,满足我省化工行业的技术升级以及产业结构调整,适应"工学结合、学岗直通"人才培养模式的改革要求,加强专业内涵建设成为当务之急,而实验实训室建设是专业内涵建设的重中之重。为了使专业实验实训室建设有计划、按步骤进行,避免低层次重复建设,并满足职业岗位的技能需要,基于工作过程,我们对应用化工技术专业实验实训室建设方案进行了整体规划设计,并对实验实训室建设具体内容进行了探索与研究。     

沥青基炭复合材料的制备及力学各向异性性质的探讨

采用新型的模压半炭化成型工艺在大气环境下制备出了高密度、低成本的焦炭颗粒增强沥青基炭复合材料（CRPCC）。研究了焦炭颗粒的种类对CRPCC材料的力学各向异性性质的影响。结果表明：由于沥青焦Ⅰ的颗粒形状系条状或棒状，故用其制备的CRPCC材料的力学性能具有明显的各向异性，且各向异性系数高达25％；而沥青焦Ⅱ和冶金焦的颗粒形状为多角形或准球形，故用它们制备的CRPCC材料基本上都是各向同性的。     

粉煤灰基沸石用于飞行器尾焰红外抑制的分析与展望

颗粒介质的抗红外辐射方式是飞行器尾焰隐身的重要手段之一。为促进颗粒系材料抑制红外辐射的研究和发展,对尾焰隐身进行了系统分析。红外辐射抑制的内涵在于改变红外波段和削弱红外辐射的强度。通过综述粉煤灰基沸石的研究进展、颗粒材料气溶胶抑制红外辐射和喷射方式的研究进展,结合飞行器尾焰辐射组分分析,总结了目前存在的问题和日后的发展方向。粉煤灰作为火力发电厂产生的固体废弃物之一,具有产量高、成本低的特点。提出将粉煤灰在一定条件下合成沸石分子筛,并进一步制备粉煤灰基沸石负载改性二氧化钛材料,将其作为颗粒系应用材料,用于尾焰红外辐射的抑制,可以实现变废为宝,在降低制备成本的前提下保护了环境与人类健康,促进社会的可持续发展。对目前沸石各成分抑制红外辐射效果的研究进行了综述,利用其对高红外辐射气体的强吸附性以及改性二氧化钛的光催化性能进行可行性分析,设计了颗粒吸附和遮蔽喷射结构,充分展示了粉煤灰基沸石的优势,并对该材料在飞行器尾焰隐身方面的应用前景提出展望。     

正丁烷及丁烯-1在不同硅铝比ZSM-5分子筛上吸附的实验与模型

Four ZSM-5 zeolite catalysts with different Si/Al ratios for the catalytic cracking of C4 fractions to produce ethylene and propylene were prepared in this study.First,the adsorption isotherms of pure n-butane and butene-1 and their mixtures on these catalysts at 300K and p=0—100kPa were measured using the intelligent gravimetric analyzer.The experimental results indicate that the presence of Al can significantly affect the adsorption of butene-1 than that of n-butane on ZSM-5 zeolites.Then,the double Langmuir（DL）model was applied to study the pure gas adsorption on ZSM-5 zeolites for pure n-butane and butene-1.By combining the DL model with the ideal adsorbed solution theory（IAST）,the IAST-DL model was applied to model the butene-1（1）/n-butane（2）binary mixture adsorption on ZSM-5 zeolites with different Si/Al ratios.The calculated results are in good agreement with the experimental data,indicating that the IAST-DL model is effective for the present systems.Finally,the adsorption over a wide range of variables was predicted at low pressure and 300K by the model proposed.It is found that the selectivity of butene-1 over n-butane increases linearly with the decrease of Si/Al ratio.A correlation between the selectivity and Si/Al ratio of the sample was proposed at 300K and p=0.08MPa.     

基于案例推理的HAZOP分析自动化框架

危险与可操作性（HAZOP）分析是一种广泛应用于化学流程工业的危险分析方法。为克服现有的HAZOP分析专家系统在“非常规”分析方面的局限性,提出了基于案例推理（CBR）的HAZOP分析自动化方法,描述了案例库及案例结构,给出了案例搜索策略。为便于案例库的知识管理,开发了案例构造器。工业实例应用结果表明,基于CBR的HAZOP专家系统突破了现有HAZOP专家系统没有学习能力和不能进行“非常规”分析的技术瓶颈。     

Peptide Bioconjugates of Electron‐Poor Metallocenes: Synthesis,Characterization, and Anti‐Proliferative Activity

We report the synthesis of metallocene compounds Cp₂M with two different electron‐withdrawing substituents on both cyclopentadienyl rings (hexafluoroacetone (HFA) and chlorobenzoyl ( 1 – 5 ); HFA and COOH ( 6 and 7 ), M=Fe or Ru). The COOH‐containing derivatives were used to synthesize peptide bioconjugates with enkephalin ( 8 and 9 ) and neurotensin ( 10 and 11 ) as well as fluorescein‐labeled neurotensin ( 12 ). All the molecules were fully characterized, including X‐ray structures for 6 and 7 . The physicochemical properties (lipophilicity and electrochemistry) and cytotoxicity on MCF‐7, HT‐29, and PT‐45 cancer cells were evaluated for selected compounds. Electrochemical investigation by cyclic voltammetry revealed that all bis‐substituted metallocenes are up to 300 mV harder to oxidize compared to the monosubstituted 2‐ferrocenylhexafluoropropan‐2‐ol (FcHFA: Δ${E{{{\rm f}\hfill \atop 0\hfill}}}$ =214 mV; disubstituted derivatives: up to Δ${E{{{\rm f}\hfill \atop 0\hfill}}}$ =512 mV; both vs. FcH^0/+). For the bis‐substituted compounds, log P determinations by RP‐HPLC showed increased lipophilicity in comparison to the monosubstituted FcHFA and RcHFA. Cellular uptake was investigated by fluorescence microcopy, and this revealed endosomal entrapment for 12 .