On the optimum plunger acceleration law in the slow shot phase of pressure die casting machines

The objective of this paper is to analyse a plunger acceleration law that is expected to minimize air entrapment in the slow shot phase of pressure die casting in horizontal cold chambers, and thus to reduce porosity in manufactured parts. The study is carried out using results from an analytical model of the flow of molten metal in the shot sleeve, which is based on the shallow-water approximation, and whose predicted optimum acceleration parameters are in good agreement with available experimental results. The results for the surface profiles of the wave formed during plunger movement using plunger acceleration laws which are typically used in pressure die casting are compared with those corresponding to the proposed law. Some analytical predictions for the wave profiles and for the mass of trapped air are compared with numerical results obtained from a finite-element code, which solves momentum and mass conservation equations. The limiting values of the initial filling fraction required for appropriate operating conditions are determined for wide ranges of acceleration parameters and pouring hole locations.     

基于核的慢特征分析算法

提出一种基于核的慢特征分析算法。通过引入核技巧,既充分扩充特征空间,又避免直接在高维空间中运算的困难。由于充分利用数据所隐含的非线性信息,所得到的解是稳定的。同时基于对慢特征分析算法目标函数的分析,给出一个对算法结果的评价准则,并用以指导核参数的选择。实验结果验证算法的有效性。     

Effect of diffusion on slowing the velocity of a bell-shaped wave in slow axonal transport

This paper models transport of organelles by slow axonal transport utilizing the stop-and-go hypothesis, which postulates that in slow axonal transport the motion of organelles does not occur continuously; instead, organelles move along microtubules (MTs) alternating between short periods of rapid movement, short on-track pauses, and prolonged off-track pauses, when they temporarily disengage from MTs. The model considers six kinetic states of organelles: anterogradely moving state, retrogradely moving state, anterogradely pausing state, retrogradely pausing state, off-track anterograde state, and off-track retrograde state. The paper extends the existing model of slow axonal transport by accounting for the diffusivity of off-track organelles and investigates how the diffusivity of these organelles affects the amplitude, velocity, and rate of change of the variance of the bell-shaped wave which describes the probability density function (PDF) corresponding to the ratio of the chance of finding an organelle within an infinitesimal interval in the axon to the length of this interval. The velocity of this wave characterizes the average effective velocity (calculated including pauses) of an organelle in slow axonal transport while the rate of change of the variance characterizes the rate of spread of the initial packet of organelles transported in the axon. The goal of this research is not only to develop a more accurate transport model, but also to understand fundamentally the effects of diffusion on slow axonal transport. It is demonstrated that diffusion decreases the amplitude of the wave and increases the rate of its spread but does not affect wave's velocity.     

慢扫速示波计时电位法同时测定合金中的铅与锌

采用慢扫速示波计时电位法同时测定铝合金中的铅与锌。该方法具有简便、快速,干扰小,选择性高等优点,特别适合于在其它离子共存条件下,测定合金样品中某种金属元素的含量。通过对铝合金样品中铅、锌测定,平均回收率和RSD分别为99.18%,99.00%和11%,16%。     

Thermal characterization of the HDPE/LDPE blend (10/90) irradiated using γ-rays

Gamma irradiation effect over the properties of slow cooled and fast cooled HDPE/LDPE 10/90 blend was studied. The blend and the neat polyethylenes were irradiated at room temperature in the presence of air using the following doses (4.8 kGy/h): 0, 50, 150, 400 and 1000 kGy. Differential scanning calorimetry (DSC) experiments were carried out using the following heating rates: 5, 10 and 20 °C/min. DSC results for the slow and fast cooled blend showed traces with three melting peaks and with increasing irradiation dose two melting peaks were obtained, i.e. the high melting peak shifts toward lower temperatures to merge with the intermediate melting peak into one endotherm. No changes in crystal structure by X-ray diffraction were found as a result of samples irradiation. Radiation crosslinking prevents crystal rearrangements during heating in the DSC. Gel content and melt flow index (MFI) measurements showed that radiation induced a high degree of crosslinking for all samples; gel content values were above 50% and a drop of more than 90% in the MFI was found. Irradiation of slow cooled samples resulted in larger values of gel content and lower MFI values than for fast cooled samples, mainly because of the higher degree of crosslinking for the former.     

Evaluation of susceptibility of high strength steels to delayed fracture by using cyclic corrosion test and slow strain rate test

To evaluate susceptibilities of high strength steels to delayed fracture, slow strain rate tests (SSRT) of notched bar specimens of AISI 4135 with tensile strengths of 1300 and 1500 MPa and boron-bearing steel with 1300 MPa have been performed after cyclic corrosion test (CCT). During SSRT the humidity around the specimen was kept high to keep absorbed diffusible hydrogen. The fracture stresses of AISI 4135 steels decreased with increment of diffusible hydrogen content which increased with CCT cycles. Their delayed fracture susceptibilities could be successfully evaluated in consideration of both influence of hydrogen content on mechanical property and hydrogen entry.     

Manufacture of slow-release matrix granules by wet granulation with an aqueous dispersion of quaternary poly(meth)acrylates in the fluidized bed

Slow-release matrix granules were manufactured in the fluidized bed using an aqueous dispersion of quaternary poly(meth)acrylates (Eudragit® RS 30 D) as binder for granulation. A factorial design was carried out to investigate the influence of the following parameters, spraying rate, applied polymer amount, and inlet air temperature, on various granule properties. Prerequisites for a slow release of the model drug theophylline are high spraying rate, high amount of polymer, and low inlet air temperature. No considerable decrease of the drug release rate can be achieved without a subsequent curing of the dry granules. A clear correlation exists between the moisture content of the fluidized bed, indicated by the terminal moisture content (TMC), and the mean dissolution time for 80% of the drug (MDT₈₀).     

Modeling the sorption kinetics of divalent metal ions to hematite

The sorption kinetics of the divalent metals Zn, Co, Ni, and Cd to hematite were studied in single sorbate systems with high sorbate/sorbent ratios (from 1.67 to 3.33mol sorbate/mol sorption sites) in 10mM Na-piperazine N,N'-bis 2-ethane sulfonic acid (Na-PIPES) solution at pH 6.8. The experimental data showed a rapid initial sorption (half-time about 1min) followed by slower sorption that continued for 1-5 days. The sequence of fast to slow sorption kinetics was modeled by slow inner-sphere (IS) complexation in equilibrium with outer-sphere (OS) complexes. Although the OS reaction was fast and considered to be in equilibrium, the extent of OS complexation changed over time due to increased surface potential from the IS complexes. For example, the model showed that the dimensionless OS complexation function, K(os), decreased from 0.014 initially to 0.0016 at steady state due to sorption of 4x10(-5)M Zn(II) to 2gL(-1) hematite. Sorption rate constants, k(ads), for the various divalent metals ranged from 6.1 to 82.5M(-1)s(-1). Desorption rate constants, k(des), ranged from 5.2x10(-7) to 6.7x10(-5)s(-1). This study suggests that the conversion from OS to IS complex was the rate-determining step for the sorption of divalent metals on crystalline adsorbents.     

用低应变速率方法测定919铝合金的应力腐蚀敏感性

用低应变速率方法测定了３种热处理状态的９１９铝合金的应力腐蚀敏感性，结果表明，３种状态合金的应力腐蚀敏感性顺序与在恒载荷试验中获得的结果具有很好的相关性。因而，低应变速率方法适用于９１９及其同类合金的应力腐蚀性能研究。     

飞行时间法测量真空电子偶素产额研究低能离子溅射诱导的缺陷损伤

利用飞行时间谱直接测量了低能正电子与表面相互作用时的真空Ｐｓ产额．该方法比通常的峰法和峰－谷法准确、简单：利用该方法研究了Ａｒ＋溅射在Ｓｉ（１００）面上诱导的缺陷损伤及退火行为。