Biodiesel, an “alternative” diesel fuel derived from vegetable oils, animals fats or used frying oils, largely consists of the mono-alkyl esters of the fatty acids comprising these feedstocks. One of the major technical issue facing biodiesel is its susceptibility to oxidation upon exposure to oxygen in ambient air. This susceptibility is due to its content of unsaturated fatty acid chains, especially those with bis-allylic methylene moieties. Oxidation of fatty acid chains is a complex process that proceeds by a variety of mechanisms. Besides the presence of air, various other factors influence the oxidation process of biodiesel including presence of light, elevated temperature, extraneous materials such as metals which may be even present in the container material, peroxides, and antioxidants, as well as the size of the surface area between biodiesel and air. Approaches to improving biodiesel oxidative stability include the deliberate addition of antioxidants or modification of the fatty ester profile. This article discusses some factors influencing biodiesel oxidative stability and their interaction. Resulting approaches to improving this property of biodiesel are related to these factors and the corresponding mechanisms. 相似文献
Across the world, energy planners and transmission system operators are faced with decisions on how to deal with challenges associated with high penetration levels of intermittent energy resources and combined heat and power (CHP). At the same time, distributed plant operators are eager to reduce uncertainties related to fuel and electricity price fluctuations. These interests meet-up for options in distributed supply that introduces the principle of storage and relocation, typically by integrating heat pumps (HP) or electric boilers (EBs) into the operational strategies of existing CHP plants. This paper introduces the principle of storage and relocation by energy system design, and proposes for the storage and relocation potential of a technology option to be found by comparing options by their storage and relocation coefficient Rc, defined as the statistical correlation between net electricity exchange between plant and grid, and the electricity demand minus intermittent renewable electricity production. Detailed operational analyses made for various CHP options within the West Danish energy system, point to the concepts of CHP-HP and CHP-HP cold storage for effectively increasing energy system flexibility. For CHP-HP cold storage, Rc increases from 0.518 to 0.547, while the plant's fuel efficiency increases from 92.0% to 97.2%. These findings are discussed within frameworks of renewable energy systems, suggesting principles for 1st, 2nd, and 3rd generation system designs. 相似文献
The research cooperation in this activity has shown a fundamentally different attitude between the participating scientists in the scientific line of procedure considered.
One group proceeds pragmatically. The group has the opinion that drying progress in big chip stacks is determined by so many intercorrelated factors that it is practically impossible to work out mathematical models of the drying progress. Therefore, the group conducts full scale field trials.
Contrary to this attitude a more scientific line of procedure is maintained by other scientists. This line of procedure tries to establish the natural laws which determine drying of comminuted wood fuels. This is done by mathematical modelling and controlled laboratory experiments.
Both types of experiment are described in this paper. 相似文献