Experimental evidence for enhanced copper release from domestic copper plumbing under hydrodynamic control

We present experimental results to analyze copper release from biotic and abiotic pipe surfaces and its relation to flow parameters, from Reynolds Number (Re) 1027–11,618.For abiotic and biotic surfaces, increasing the flow velocity affected the time scale of the copper release but not necessarily the net amount of total copper incorporated into the bulk flow.For biotic conditions the total copper concentration in the bulk flow was an order of magnitude higher than for abiotic surfaces (3.65 mg/L vs. 0.32 mg/L). Similarly, higher flow velocities enhance the presence of larger size copper nanoparticles in the bulk flow.     

Electrochemical corrosion performance of Cr and Al alloy steels using a J55 carbon steel as base alloy

Cr- and Al-modified alloy steels using J55 carbon steel as base alloy were produced by remelting in a vacuum. Their corrosion resistance was estimated by open circuit potential, electrochemical polarisation measurements and immersion tests in a 3.5 wt.% NaCl solution. The modified alloy steels exhibit higher corrosion resistance with a more positive open circuit potential, lower corrosion current density and higher impedance than J55 steel. The immersion tests showed that the new alloy steels have lower corrosion rates and smaller pitting depth than J55 steel and a low-Cr steel.     

Synthesis and characterization of EuBa2Ca2Cu3O9−x: The influence of temperature on dielectric properties and charge transport mechanism

High dielectric constant materials have a crucial importance for various microelectronic applications such as memory devices, supercapacitors etc. Among other insulators, perovskite structured oxide materials attract great interest not only for their high dielectric constants but also their unique electrical and magnetic properties such as superconductivity etc. From this point of view, a new Europium based copper oxide layered material with perovskite structure (EuBa₂Ca₂Cu₃O_9−x coded as Eu-1223) has been synthesized by solid state reaction method in this work. The physical and chemical properties of Eu-1223 have been determined by FTIR, SEM, XRF, XRD, TGA and DTA techniques. The influence of temperature on impedance and dielectric properties of Eu-1223 has been investigated by impedance spectroscopy measurements performed within the frequency interval of 5 Hz–13 MHz between 298 K and 408 K temperatures. It has been found that the Eu-1223 material has high dielectric constants at each temperature operated. In addition, Eu-1223 sample behaves as a colossal dielectric material up to 300 kHz for 408 K due to observation of dielectric constant values which are greater than 10³. Furthermore, it has been revealed that Eu-1223 material can be used as thermally sensitive resistors in electronic circuits due to its decreasing resistance with increasing temperature. Moreover, it has been observed that the relaxation frequency of the system shifts from 46.5 kHz (low frequency radio wave band) to 1.57 MHz (mid frequency radio wave band) as the temperature increasing from 298 K to 408 K. According to dc conductivity investigations, the variation of dc conductivity with the inverse of temperature satisfies linear relationship that indicates a thermally activated nearest neighbor hopping conduction. On the other hand, it has been determined that ac conductivity has frequency dependent relation which obeys ω^s for the high frequency region. Furthermore, the frequency exponent, s, which takes values between 0.7 and 0.4, shows a decreasing behavior with increasing temperature. In conclusion, ac charge transport mechanism has been predicted as correlated barrier hoping for Eu-1223.     

Preparation, characterization and application of advanced isoconversional kinetics to epoxy/1,4-Bis(3-aminopropoxy) butane/MWCNT nanocomposite

A novel nanocomposite consisting bisphenol A diglycidyl ether/1,4-Bis(3-aminopropoxy) butane (1,4-APB)/multiwall carbon nanotube (MWCNT) was synthesized and characterized. Kinetics of the reaction was described by applying differential scanning calorimetry (DSC) data to isoconversional methods of Flynn-Wall-Ozawa (FWO), advanced isoconversional method of Vyazovkin, and non-linear integral isoconversional algorithm (NLN). It was found that at the presence of MWCNT the thermal decomposition temperature increased by rising the curing temperature and time. Data from dynamic mechanical thermal analysis (DMTA) showed that the glass transition temperature of the cured nanocomposite is 7 °C higher than that value found for the system without carbon nanotube. Scanning electron microscopy (SEM) was used to observe the fracture surface morphology and results indicated evidence of the interfacial interaction improvement and adhesion strength due to good dispersion of MWCNT.     

Cross-layer optimized authentication and error control for wireless 3D medical video streaming over LTE

3D video for tele-medicine applications is gradually gaining momentum since the 3D technology can provide precise location information. However, the weak link for 3D video streaming is the necessary wireless link of the communication system. Neglecting the wireless impairments can severely degrade the performance of 3D video streaming that communicates complex critical medical data. In this paper, we propose systematic methodology for ensuring high performance of the 3D medical video streaming system. First, we present a recursive end-to-end distortion estimation approach for MVC (multiview video coding)-based 3D video streaming over error-prone networks by considering the 3D inter-view prediction. Then, based on the previous model, we develop a cross-layer optimization scheme that considers the LTE wireless physical layer (PHY). In this optimization, the authentication requirements of 3D medical video are also taken into account. The proposed cross-layer optimization approach jointly controls and manages the authentication, video coding quantization of 3D video, and the modulation and channel coding scheme (MCS) of the LTE wireless PHY to minimize the end-to-end video distortion. Experimental results show that the proposed approach can provide superior 3D medical video streaming performance in terms of peak signal-to-noise ratio (PSNR) when compared to state-of-the-art approaches that include joint source-channel optimized streaming with multi-path hash-chaining based-authentication, and also conventional video streaming with single path hash-chaining-based authentication.     

Determination and Analysis of Ustiloxins A and B by LC-ESI-MS and HPLC in False Smut Balls of Rice

Ustiloxins are cyclopeptide mycotoxins produced by the pathogenic fungus Villosiclava virens of rice false smut. Ustiloxins A and B as two main mycotoxins were determined conveniently by LC-ESI-MS in the water extract from rice false smut balls which were mostly composed of the chlamydospores and mycelia of the pathogen. Both ustiloxins A and B in the water extract were also quantitatively analyzed by HPLC. This is the first report on the determination and analysis of ustiloxins A and B simultaneously by LC-ESI-MS and HPLC in false smut balls of rice.     

Electromagnetic shielding effectiveness and mechanical property of polymer–matrix composites containing metallized conductive porous flake-shaped diatomite

The porous flake-shaped diatomite particles with different micropores diameter were used as forming templates for the fabrication of the conductive core–shell functional fillers by electroless silver plating. The surface morphologies and phase structures of the surface coatings onto diatomite particles with different micropores diameter were evaluated. The effects of micropores diameter on electrical resistivity, electromagnetic shielding effectiveness and mechanical property of polymer–matrix composites containing silver-coated diatomite particles were also investigated in detail. The results show that the micropores onto initial diatomite particles after plating are completely covered with the coating, while the micropores onto diatomite particles with expanding pores are still visible. The expanding micropores onto diatomite particles in certain size range have less impact on the phase structures, electrical resistivity and electromagnetic shielding effectiveness. However, the mechanical properties of composites are improved significantly after expanding micropores by HF acid corrosion.     

Numerical optimization of strengthening disturbed regions of dapped-end beams using NSM and EBR CFRP

This paper presents a parametric investigation, based on non-linear finite element modeling, to identify the most effective configuration of carbon fiber-reinforced polymers (CFRP) for strengthening reinforced concrete (RC) dapped-end beams. Following a field application and laboratory tests, it focuses on effects of 24 externally bonded (EBR) and near surface mounted reinforcement (NSMR) configurations on yield strain in steel and the capacity and failure mode of dapped-end beams. The investigated parameters were the mechanical properties of the CFRP, the strengthening procedure and the inclination of the fibers with respect to the longitudinal axis. Two failure scenarios were considered: rupture and debonding of the FRP. The results indicate that high-strength NSM FRPs can considerably increase the capacity of dapped-end beams and the yielding strains in reinforcement can be substantially reduced by using high modulus fibers.