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31.
J.H Xiang 《Corrosion Science》2004,46(8):2025-2039
The oxidation of the ternary alloys Ni-45Cu-10Al and Ni-30Cu-10Al has been studied at 800-900 °C under 1 atm O2. The presence of 10 at.% Al reduces significantly the oxidation rate of the corresponding Cu-Ni alloys during the initial oxidation stages, even before the establishment of a complete Al2O3 layer. The weight of individual sample of the two ternary Ni-Cu-10Al alloys at 800 °C increases more rapidly than at 900 °C during the initial oxidation stage. As oxidation proceeds, the weight gain at 800 °C slows down to a degree that the total weight gain after 24 h oxidation at 800 °C is less than that at 900 °C. Due to a faster formation of the Al2O3 layer, which suppresses earlier the further oxidation of Cu and Ni, the external region of the scales grown on Ni-45Cu-10Al contain much less Cu and Ni oxides than those grown on Ni-30Cu-10Al. The transition from the internal oxidation to the selective external oxidation of the most reactive component Al in Ni-Cu-Al alloys is favored by higher values of the Al content, of temperature and of the Cu/Ni ratio. 相似文献
32.
Knowledge of phase equilibria in the Ru–Al–Ni ternary system is relevant to the development of new single crystal Ni-based superalloys as well as to new high temperature protective coating systems for these alloys. A series of diffusion couple investigations have been performed across the Ru–Al–Ni ternary system in order to establish phase fields and possible diffusion paths. A continuous B2 phase has been shown to exist across the Ru–Al–Ni ternary between the RuAl and NiAl phases at temperatures of 1000 and 1100 °C. Ternary isothermal sections for Ru–Al–Ni at 1000 and 1100 °C are presented. 相似文献
33.
L.Q. Xing P. Ochin M. Harmelin F. Faudot J. Bigot J.P. Chevalier 《Materials Science and Engineering: A》1996,220(1-2)
Cylindrical bulk amorphous samples with diameters up to 10 mm have been prepared by casting ZrTiAlCuNi alloys in a copper mould. In order to rank glass-forming ability as a function of alloy composition, alloys were also cast into wedge-shaped moulds; to a first approximation, the thickness of the amorphous region obtained can be taken as an indication of glass-forming ability. The compositions which lead to the production of bulk glasses all have reduced glass transition temperatures in excess of 0.65 and the extremely high glass-forming ability of these compositions is discussed. We suggest that both the Al and Ti contents are determining factors for the production of bulk amorphous samples and these are believed to reduce the driving force for, and hence the rate of, crystallisation. These amorphous alloys have been found to display high thermal stability and can be annealed for several minutes in the supercooled liquid region. They are ductile at room temperature and have a high value of yield stress. 相似文献
34.
随着电力和电子技术的飞速发展,相应的元器件向高频化,小型化,高效率和节能的方向发展,从而对元器件用材料也提出了更高要求。为此,本文概述了冶金部钢铁研究总院近年来所研究的用于开关电源,脉冲变压器,传感器,电流互感器和电感器等方面的非晶软磁合金的性能及其应用概况。 相似文献
35.
马道章 《有色金属材料与工程》2007,28(3):129-131
哈兹列特铝板带连铸连轧工艺已被成功地用于铝和铝合金冲击挤压用坯料的生产。在对哈氏四个有关用户扫描的基础上,列举了其产品及其用途,并介绍了相关工艺及其优点。 相似文献
36.
A. Goldman 《Journal of Materials Engineering and Performance》1995,4(4):395-400
Iron-based metallic strip materials such as iron, silicon-iron, and amorphous metal are used for low frequency (50–60 Hz.
line) power applications. Low-loss Nickel-based alloys as high permeability strip or insulated powder cores are the choices
for stable, low-level higher frequency applications. Iron-based powder cores offer low cost as power supply filter chokes.
Ceramic ferrites combine highest frequency operation with low cost and reduced component size as transformers and chokes in
telecommunication and high frequency power supply applications. 相似文献
37.
K. Balcerek Cz. Marucha J. Rafałowicz R. Wawryk 《International Journal of Thermophysics》1992,13(6):1085-1096
A universal curve relating the maximum of thermal conductivity and its respective temperature with the residual electrical resistivity has been proposed for metals and dilute alloys. Based on the equation of that curve, a comparative analysis of selected literature data of thermal conductivity of metals, which have residual electrical resistivity in the range 10–11<0<10–5. cm, have been performed. Using the data for 33 metals, confirmation of the Wiedemann-Franz law for the impurity component/T of thermal conductivity was obtained, which means that th/el1, where
th and
el are the parameters of the electron-lattice defect interaction obtained from measurements of thermal and electrical conductivity, respectively. Examples of the failure of the Wiedemann-Franz law are also presented, exhibiting the values of
th/el in the range 0.16 to 25. Measurements of thermal conductivity in the range 2 to 20 K and determination of the residual electrical resistivity for the samples of Cd doped with Zn and quenched were performed, resulting in values
th/el1. 相似文献
38.
V Chandrasekaran Ch Sreerama Murthy P Subrahmaniam G Venkateswarlu 《Bulletin of Materials Science》1986,8(1):39-48
Iron-chromium-cobalt alloys possess attractive magnetic properties combined with good formability and hence are identified as technologically important magnetic materials. Alloys with compositions Fe-28·9 Cr-15·6 Co and Fe-28·4 Cr-20·1Co (weight percent) have been studied. Heat-treatment parameters during thermomagnetic treatment viz temperature, time and external magnetic field were optimized with reference to magnetic properties. The fully treated anisotropic alloys develop remanence=11·5–12·0 kilo Gauss, coercivity=600–650 Oersted and energy product=4–4·5 million Gauss Oersted. Electron microscopic and Mössbauer spectroscopic techniques were used to identify the original and transformed phases. During the various stages of the development of the alloy, the changes in mechanical hardness were correlated with magnetic hardness. 相似文献
39.
The oxidation behavior of Ti-Si alloys (0.25, 0.5, and 1 Wt. % Si) was investigated between 550 and 700°C; in oxygen by continuous thermogravimetry for a maximum duration of about 500 hr and, in air by daily weighing for durations from a few hundred to several thousand hours. The kinetics results revealed that the presence of silicon leads to a decrease in oxidation rate which is more evident when the temperature is raised and the silicon content is increased. Morphological and structural examinations revealed that silicon modifies the internal architecture of oxide layers when compared with unalloyed titanium; in particular, reduced porosity in the layers is observed. Analysis showed that silicon is uniformly distributed in the oxide layer. However, while part of the silicon is in solid solution in the rutile, some is also precipitated as small crystals ( <1 m at 850°C) of SiO2, of cristobalite structure. The adherence of oxide layers to the metal substrate was measured after cooling of samples; the addition of silicon has been observed to modify, in a manner dependent on its content, the adherence of oxide layers. 相似文献
40.
The attack of nickel, cobalt, iron, and alloys of these metals containing chromium and aluminum, by gases containing sulfur-oxygen,
carbon-oxygen, and nitrogen-oxygen has been studied at temperatures of 600 and 900°C. The degradation of these metals and
alloys was characterized by using standard analytical techniques with emphasis on optical metallography. Three types of accelerated
degradation were identified for the attack of alloys by gases containing another oxidant in addition to oxygen. One type of
degradation occurred because of the formation of reaction products composed of mixtures of phases involving both of the oxidants.
Another type resulted from the reaction of second oxidant phases with oxygen. The third form of degradation involved the development
of less protective phases due to thermodynamic instabilities. Thermodynamic stability diagrams are used to help account for
the effects produced by different elements in the alloys. 相似文献