溶胶-凝胶法制备Na_2WO_4~-Mn/SiO_2催化剂及其甲烷氧化偶联反应性能的研究

采用溶胶-凝胶法制备了一系列5%Na2WO4-2%Mn/SiO2催化剂;用XRD、XPS、BET、O2-TPD和CO2-TPD等方法对催化剂进行了表征,并考察了对甲烷氧化偶联反应的催化性能。结果表明,与常规浸渍法相比,采用溶胶-凝胶法制备的Na2WO4-Mn/SiO2催化剂中W和Mn的原子浓度在催化剂表面和体相分布较为接近,而且两种制备方法所得的催化剂具有相似的催化性能,Na2WO4与α-方石英之间的相互作用,催化剂释放晶格氧的能力,碱性强弱是影响甲烷氧化偶联活性的关键因素。     

High Power Fiber Bundle Array Coupled LDA Module

1 Introduction High power laser diode arrays (LDA) have many advan- tages such as small volume, long working life, high slope efficiency and high optical density, so they have many applications in medical treatment, material pro- cessing, and for the pumping source of solid laser and etc. But unfortunately, the LDA can not be easy to use directly in these fields because of their poor beam quality and extremely asymmetric divergent beams (!x≈ 5°～10°and !y≈20°～35°, for example), so it …     

柔性联轴节在减小转子系统扭转冲击运动中的作用

通过对大型振动磨机运动特性的研究分析,把其旋转系统简化为由两个柔性联轴节连接的三转子系统。建立了柔性连接的三转子系统在冲击转矩作用下的运动方程,对方程求解得到了柔性连接转子系统的扭转冲击响应。通过对冲击响应随柔性联轴节扭转刚度和阻尼变化规律的讨论分析,发现减小柔性联轴节的扭转刚度和增大柔性联轴节的阻尼,可以减小转子系统的扭转冲击响应。     

Computational analysis of thin coating layer failure using a cohesive model and gradient plasticity

Thermal barrier coatings (TBC) are widely used to prevent transient high temperature attack and allow components high durability. Due to strong inhomogeneous material properties the TBC failure often initiates near the interface between the brittle oxide layer and the ductile substrate. A reliable prediction of the TBC failure requires detailed information about the crack tip field and the consequent fracture criteria. In the present paper both cohesive model and gradient plasticity are used to simulate the failure process and to study interdependence of the interface stress distribution with the specific fracture energies. Computations confirm that combination of the two models is able to simulate different failure mechanisms in the TBC system. The computational model has the potential to give a realistic prediction of the crack propagation process.     

Influence of thermal treatments on the elastic parameters in iron rich metallic glasses

The change of magnetoelastic properties after thermal treatments has been investigated for two groups of metallic glasses. (Fe₇₉Co₂₁)_75+xSi_15−1.4xB_10+0.4x (x (at.%)=0, 2, 4, 6, 8, 10) has been studied both in the as-prepared state and after thermal annealing in an applied magnetic field, to achieve a particular domain structure, at temperatures well below the crystallization temperatures. Changes in the ΔE effect, magnetomechanical coupling (k) and internal friction coefficient (Q⁻¹) are reported, reaching values of about 60% of the saturation value E_S. Fe₆₄Ni₁₀Nb₃Cu₁Si₁₃B₉ alloys annealed in vacuum for 1 h in the temperature range 350–550 °C showed maximum values of the ΔE effect and k of 61% and 0.85, respectively, accompanied by a minimum value of Q of around 2 for the sample annealed at 460 °C. These variations are related to the progress of nanocrystalization. The properties achieved are among the best reported for magnetomechanical applications.     

Spectral properties of diesel fuel droplets

Absorption spectra of several types of diesel fuel are studied experimentally. Index of refraction of these fuels is calculated using subtractive Kramers-Krönig analysis. The ageing process of fuels is simulated by prolonged boiling. Radiative properties of diesel fuel droplets are calculated using the Mie theory and a simplified approach, based on approximations of absorption and scattering efficiency factors. It is pointed out that the accuracy of the simplified approach is sufficient for practical applications in the visible and infrared ranges, for various types of diesel fuel, and for droplet radii in the range from 5 to 50 μm. The monodisperse approximation is shown to be applicable for the analysis of infrared radiative properties of realistic polydisperse diesel fuel sprays.     

聚合物分散液晶(PMMA:5CB:C60)光折变特性的实验研究

用溶致相分离方法制备了3种不同组分的聚合物分散液晶薄膜(PMMA：5CB：C60)，C60作为敏化剂。利用二波耦合实验测量了不同样品的衍射效率和响应时间等光折变特性，实验发现，液晶含量不同的薄膜光学性质有很大的不同。     

防止干燥塔塔顶及锥节产生焦粉的方法

描述及分析了干燥塔在生产乳粉过程中出现的塔顶及锥节焦粉现象，并提出了改进方法。     

饼干炉湿度控制的改进方法

在大空间的温度控制系统中 ,采用简单的PID控制规律 ,对空间的温度、湿度进行解藕计算 ,将空间的相对湿度控制转化为送风含湿量的控制。该控制方式稳定、可靠 ,并且节约能源。本方法适用于所有的烘烤炉中     

液力联轴器喷油着火事故的原因分析及预防

以矿用液力联轴器为研究对象 ,阐明其喷油着火的机理 ,分析其喷油着火的原因并作出事故树分析 ,针对现场使用的情况 ,提出预防措施及发展趋势 ,对矿井安全生产具有指导性作用。