深循环地下水作用下红土与黄土成因研究

通过研究阿拉善自流井区出现的红化地层,发现富含Fe~(2+)的井水涌出地表后形成了Fe_2O_3胶膜,铁质胶膜吸附在土颗粒的表面形成了红土层,表明土壤红化作用可以与气候无关。在上地幔高导低速层中可能存在地下水的导水通道,玄武岩中的FeO、MgO中的Fe~(2+)、Mg~(2+)等被超临界水(supercritical water,SCW)萃取带出。深循环地下水维系了黄土高原风尘物的连续堆积,早期渗漏进入上地幔导水通道的地下水被加热成为SCW,被萃取带出地表的Fe~(2+)与空气中的O_2发生氧化反应生成Fe_2O_3胶膜,铁质胶膜吸附在风尘颗粒的表面形成红土。2.5 Ma以来,玄武岩导水通道温度降低到临界点以下,地下水的萃取作用大幅度减弱,风积土显示为黄色,表明黄土高原颜色的转变与气候变化无关。由于深海沉积物δ~(18)O与全球冰量呈正相关,冰量与全球降水量呈负相关,而深循环地下水量与全球降水量呈正相关,由此可知,鄂尔多斯黄土沉积层碳酸盐与全氧化铁含量与深海δ~(18)O呈高度负相关。     

改性蒙脱土处理工业废水的试验研究

将改性蒙脱土与活性炭膜2种材料同时作为生物处理工艺的填料,分别加装在相同条件的2套处理系统中,采用生物处理工艺。在同样的条件下处理工业废水,经过对实验数据的分析得出:以改性蒙脱土为填料,处理工业废水的能力更强,净化效果更好。     

胶片型航空画幅遥感相机中负压展平机构的设计

航拍成像胶片的展平精度是影响相机分辨率的主要因素.长焦距、大画幅、高分辨率的胶片式画幅遥感相机要求在给定的摄影周期内快速、精密地将胶片展平在片台上.为实现画幅尺寸为114 mm×114 mm的胶片展平精度达到0.034 mm,吸附时间为420 ms,提出了一个较完善的胶片展平机构,介绍了利用负压将胶片展平在焦平面板上的方法.阐述了该展平机构的组成和工作原理,给出了片台的结构形式,并通过分析计算得出关键器件的选择依据.提供了一种利用光学技术来定性检测展平精度的方法.经成像试验验证,该方法可满足使用要求.     

结晶器无氟保护渣渣膜的传热性和矿物结构

 结晶器和铸坯间的渣膜直接影响铸坯的润滑和传热,由于无氟保护渣特性不同于传统含氟渣,其传热特性以及它在结晶器内的热行为是研发的关键。因此,对结晶器无氟保护渣渣膜的传热和矿物结构进行了研究。研究结果表明：添加适当的Li2O、TiO2和Fe2O3,可使渣具有较好的流动性和较低的熔化温度,使渣膜的硅灰石相区缩小,黄长石相区扩大,从而减低渣膜的传热系数。     

Influence of Bath Composition on Magnetic Properties of Electrodeposited Co-Pt-W Thin Films

Effect of bath composition （[Co^2＋]/[-Pt^Ⅳ ] and [-WO4^2- ], [cit^-]） and pH on the magnetic properties of electrodeposited Co-Pt-W thin films has been investigated. Electrodeposited Co-Pt-W thin films exhibited strong perpendicular magnetic anisotropy when the ratio of [-Co^2＋ ] to [-Pt^Ⅳ ] was 10 ; cathode current efficiency and perpendicular magnetic anisotropy showed little variations when [WO4^2- ] was lower than 0. 1 mol/L, but perpendicular magnetic anisotropy had strengthened when [WO4^2-] was over 0. 1 mol/L, which could be explained by the fact that the hydrogen evolution could produce pores as magnetic domain pinnings; citrate as complexing reagent can promote the polarization of [Co^2＋] and [Pt^Ⅳ]. As a result, the equilibrium electrode potentials of cobalt and platinum moved to negative direction, which led to the co-deposition of Co, Pt, and W. It was also found out that the as-deposited Co- Pt-W hard magnetic thin films were very homogeneous, smooth, and had the maximum coercivity for the bath pH 8. 5 and the concentration of citrate 0. 26 mol/L.     

一种柔性染料敏化太阳能电池的初步研究

染料敏化太阳能电池(DSSC)与商用硅电池相比,由于具有转化效率较高、制作成本低等一系列优点,近年来已受到人们的广泛关注.简要介绍了DSSC太阳能电池的结构和基本原理,重点分析了DSSC太阳能电池的关键组成和影响光电转化效率的因素.采用胶带涂覆法在柔性ITO衬底上制备了多孔纳米TiO2薄膜,通过给其配置相应的染料和电解...     

退火对Al2O3薄膜结构和发光性能的影响

氧化铝(Al2O3)薄膜具有许多优良的物理化学性能,在机械、光学及微电子等高科技领域有着广泛应用,一直受到人们的高度关注.但Al2O3具有多种物相形态,性质差别很大.因此研究不同结构对其发光性能的影响在Al2O3实际应用中有着重要意义.本文采用射频磁控溅射技术在单晶硅衬底上制备了Al2O3薄膜,并在氮气中进行了不同温度的退火,对比了退火前后薄膜的结构和光致发光特性.观察到了在384nm和401nm附近的两个荧光峰,这两个发光峰都是由色心引起的.随着退火温度的升高,Al2O3薄膜的结晶质量变好,同时荧光峰峰位发生了相应的变化,强度也发生了明显的变化.     

In和Te掺杂PbSe薄膜制备及其对薄膜光电性能的影响机制

采用中频磁控溅射技术制备了PbSeIn和PbSeTe两种掺杂PbSe薄膜, 并采用理论模拟与实际实验相结合的方法研究了In和Te两种元素的掺杂机制及其对薄膜性 能的影响。结果表明,In原子主要通过置换Pb原子的形式进行掺杂,而Te原子则主要置换 Se原子;与未掺杂PbSe薄膜相比,PbSeIn和PbSeTe两种薄膜的光电敏感性均有一定提高, 其中In掺杂PbSe薄膜的平均电阻变化率最高。这是由于In元素在PbSe薄膜禁带内形成深杂 质能级,提高非平衡载流子寿命所导致的。而PbSeTe薄膜的光电敏感性则与未掺杂PbSe薄 膜相近。     

Comparison of Different Mass Spectrometry Workflows for the Proteomic Analysis of Tear Fluid

The tear film is a multi-layer fluid that covers the corneal and conjunctival epithelia of the eye and provides lubrication, nutrients, and protection from the outside environment. Tear fluid contains a high concentration of proteins and has thus been recognized as a potential source of biomarkers for ocular disorders due to its proximity to disease sites on the ocular surface and the non-invasive nature of its collection. This is particularly true in the case of dry eye disease, which directly impacts the tear film and its components. Proteomic analysis of tear fluid is challenging mainly due to the wide dynamic range of proteins and the small sample volumes. However, recent advancements in mass spectrometry have revolutionized the field of proteomics enabling unprecedented depth, speed, and accuracy, even with small sample volumes. In this study using the Orbitrap Fusion Tribrid mass spectrometer, we compared four different mass spectrometry workflows for the proteomic analysis of tear fluid collected via Schirmer strips. We were able to establish a method of in-strip protein digestion that identified >3000 proteins in human tear samples from 11 healthy subjects. Our method offers a significant improvement in the number of proteins identified compared to previously reported methods without pooling samples.     

蒸发速率对ZnS薄膜性能的影响

为了研究蒸发速率对ZnS薄膜的折射率、表面形貌和应力等性能的影响,本文采用电子束蒸发技术进行了ZnS薄膜的制备.首先在K9玻璃基片上镀制薄膜,采用分光光度计进行透射率曲线的测试,利用光谱反演法得出薄膜的折射率,采用原子力显微镜表征了样品的表面形貌.最后在聚酰亚胺基底上镀制薄膜,利用Stoney公式计算出薄膜的应力.结果...