工业用丙烯中微量水的测定

为了保证出厂工业用丙烯中的微量水达到国标或企业标准,准确分析出工业丙烯中的微量水非常重要。用卡尔·费休库仑法测定微量水解决了这一问题,测定数据直接反应着工业用丙烯合格与否。     

Quad-cantilever microsensors with a low-cost single-sided micro-machining technique for trace chemical vapor detection

This paper presents a quad-cantilever microsensor for on-the-spot detection of ultra-low concentration chemical vapors. Compared with conventional dual-cantilever sensors, the quad-cantilever configuration can form a fully cantilever-formed Wheatstone-bridge that possesses a higher sensitivity of twofold and more balanced condition to compensate for environmental noise like temperature fluctuation or air flow. Besides, the four integrated micro-cantilevers are made of SiO₂, with each having a single crystal silicon piezoresistor fully encapsulated by SiO₂. Thus, the quad-lever sensor achieves a very low signal noise of 0.2 μV. For specific detection, sensitive molecule layer is self-assembled on two sensing cantilevers, with another two as reference. The sensors are micro-fabricated with a single-side process from the wafer front-side. With wet anisotropic etch used to release the piezoresistive cantilevers, the new fabrication technique features low-cost and high-yield. Self-assembled with a novel dual-branch specific mono-layer, about 100 ppt level trinitrotoluene (TNT) vapor has been rapidly and repeatedly detected.     

冷原子吸收法测定地化样品中痕量汞

在原子吸收分光光度计上,制定出地化样品中痕量汞的冷原子吸收测定方法。实验结果表明,本方法准确可靠,可测定10-9量级的汞,重现性好,共存元素不干扰汞的测定,可满足地化痕量汞的测定。     

Indications for the applicability of element signature analysis for the determination of the geographic origin of dried beef and poultry meat

In order to determine the geographic origin of poultry and dried beef, concentrations of a total of 72 different elements (occasionally represented with several isotopes) were analyzed by inductively coupled plasma high resolution mass spectrometry (ICP-HRMS). Additionally, gross chemical composition (GCC) was analyzed. The 25 poultry breast filets samples originated from Switzerland, France, Germany, Hungary, Brazil, and Thailand, and the 23 dried beef samples, made from M. biceps femoris and M. semitendinosus, were produced in Switzerland, Austria, Australia, United States, and Canada out of raw meat originating either from these or from other countries. A total of 66 and 46 of the elements and isotopes followed were detected in beef and poultry, respectively. For statistical analyses, only the most abundant isotopes per element were used. For both poultry meat and dried beef, a differentiation of the origins was possible using those elements, which were significantly different across countries (As, Na, Rb, and Tl in poultry; B, Ca, Cd, Cu, Dy, Eu, Ga, Li, Ni, Pd, Rb, Sr, Te, Tl, Tm, V, Yb, and Zn in beef). No sufficient differentiation between origins was possible with GCC. Further studies have to confirm the suitability of this approach for meat authentication with more samples.     

敞口消解-ICP-MS测定微合金钢中4种微量元素的方法研究

采用HNO3＋HCl混合酸消解体系敞口消解试样,选取74Ge作为测定48Ti,52Cr,59Co,61Ni的内标元素,建立了微合金钢中微量元素钛、铬、钴、镍的电感耦合等离子体质谱（ICP-MS）测定方法。该方法线性关系良好（相关系数r=0.99985～0.99998）,检出限为6pg·g-1～39pg·g-1,平均加标回收率达到98%～102%,方法精密度好,相对标准偏差（n=9）在0.47%～2.04%之间。所建立的分析方法实现了对微合金钢样品中4种微量元素的测定,实际样品的测定结果与参考值相符。     

进口螺旋国产部件的研制

介绍了进口螺旋的结构特点 ,阐述了对进口螺旋部件进行测绘和计算的方法 ,并对测绘数据的正确性作出了论证 ,最后总结了国产部件的优点     

Distribution of trace metals in a ling (Genypterus blacodes) fish fillet

The distribution of trace metals in a ling (Genypterus blacodes) fish fillet was determined from ICP-MS measurements of digests prepared using nitric acid and hydrogen peroxide, followed by microwave digestion. Most trace elements were inhomogeneously distributed in the muscle tissue of the ling with a non-linear increase in concentration towards the tail end of the fillet. This distribution pattern may be connected to the size variation of the individual muscle cells or the change in the ratio of connective tissue to muscle tissue, suggesting that the observed inhomogeneity of muscle elemental distribution may be inherent to all fish species. The concentration of an element in a sample of fish muscle tissue thus depends on the physical location within the fish from which the sample was dissected. Significant differences in trace element concentrations were also detected between the red and white muscle fibres of ling, as well as between the belly flap and the rest of the musculature.     

An independent but not identically distributed bit error model for heavy-tailed wireless channels

The error patterns of a wireless channel can be represented by a binary sequence of ones(burst) and zeros(run),which is referred to as a trace.Recent surveys have shown that the run length distribution of a wireless channel is an intrinsically heavy-tailed distribution.Analytical models to characterize such features have to deal with the trade-off between complexity and accuracy.In this paper,we use an independent but not identically distributed(inid) stochastic process to characterize such channel behavior and show how to parameterize the inid bit error model on the basis of a trace.The proposed model has merely two parameters both having intuitive meanings and can be easily figured out from a trace.Compared with chaotic maps,the inid bit error model is simple for practical use but can still be deprived from heavy-tailed distribution in theory.Simulation results demonstrate that the inid model can match the trace,but with fewer parameters.We then propose an improvement on the inid model to capture the ’bursty’ nature of channel errors,described by burst length distribution.Our theoretical analysis is supported by an experimental evaluation.     

Computer Control of the Gilford Model 252-1 Spectrophotometer Modernization System

ABSTRACT

The construction of an interfacing device between a Gilford Model 252-1 Spectrophotometer Modernization System and a Commodore PET microcomputer is described. Modifications to the Gilford automatic cuvette positioner to allow computer control are also described. The program for operation of the modified system is listed. A comparison between computer and manually obtained rates is included.     

定量求解重力谷糙分离机工作面上物料的运动

定量求解重力谷糙分离机工作面上物料的运动较为困难，迄今尚未见有文献报道，但这一问题可采用解析和数值解结合的方法求解。文中详细介绍了具体步骤和实例计算结果。