Contribution of trace metals from atmospheric deposition to stormwater runoff in a small impervious urban catchment

The contribution of atmospheric deposition to emissions of trace metals in stormwater runoff was investigated by quantifying wet and dry deposition fluxes and stormwater discharges within a small, highly impervious urban catchment in Los Angeles. At the beginning of the dry season in spring 2003, dry deposition measurements of chromium, copper, lead, nickel, and zinc were made monthly for 1 year. Stormwater runoff and wet deposition samples also were collected, and loading estimates of total annual deposition (wet+dry) were compared with annual stormwater loads. Wet deposition contributed 1-10% of the total deposition inside the catchment, indicating the dominance of dry deposition in semi-arid regions such as Los Angeles. Based on the ratio of total deposition to stormwater, atmospheric deposition potentially accounted for as much as 57-100% of the total trace metal loads in stormwater within the study area. Despite potential bias attributable to processes that were not quantified in this study (e.g., resuspension out of the catchment or sequestration within the catchment), these results demonstrate atmospheric deposition represents an important source of trace metals in stormwater to waterbodies near urban centers.     

面向制造的弧齿线圆柱齿轮的建模设计

介绍了一种面向制造的设计方法,根据弧齿线圆柱齿轮的加工原理,提出了基于齿轮齿条原理的弧齿线圆柱齿轮的特征建模方法.采用的齿轮实体建模方法与实际齿轮加工方法相同,为精确造型、正确仿真及有限元分析提供了基础.     

非开挖铺管导向孔轨迹三维模拟及辅助设计系统

本文介绍了自主研发的非开挖铺管导向孔三维轨迹优化设计软件——非开挖水平定向钻进导向孔轨迹三维模拟设计及优化辅助决策系统（1．0版）。     

广西箭猪坡矿床首次发现的石英脉型锡矿体特征及 锡石微量元素地球化学意义

箭猪坡矿床是丹池成矿带南端的一个以铅锌锑为主的矿床,随着2012-2014年在箭猪坡矿床钻孔中石英脉型锡矿体的首次发现,打开了箭猪坡矿床新的找矿空间。新发现的锡矿体矿石矿物组合类型主要为锡石+闪锌矿+脆硫锑铅矿+黄铁矿+石英及锡石+脆硫锑铅矿+石英+方解石。箭猪坡矿床锡石呈自形-半自形粒状,锡石粒径多在0.1～0.2mm,少数0.02～0.05mm,分布在含硫化物的石英脉裂隙中。物相分析显示箭猪坡矿床锡主要赋存在锡石中,锡石物相占83.33%～100%。阴极发光（CL）图像显示箭猪坡矿床中的锡石经历了两期结晶作用：早期锡石（Ⅰ）和晚期锡石(Ⅱ）,早期锡石CL荧光亮度较小,呈暗灰色至黑色;晚期CL荧光亮度较大,呈白色至浅灰色。锡石单矿物SnO2含量91.623%～96.288%,平均94.03%,杂质主要有Fe、W、In等,其中FeO含量0.02%～0.52%,WO3含量多在0.02～1.34%,In2O3含量在0.476%～0.954%,Sn与FeO、In2O3呈负相关,锡石中FeO、WO3、Ta2O5、Nb2O5、MnO含量指示箭猪坡锡形成于中低-中温热液环境,成矿热液来源于高度分异演化的花岗质岩浆。通过与大厂矿田西矿带上部脉状锡矿体的类比分析,具有相似的成矿条件及矿物组合,推测所揭露到的脉状锡矿（化）体相当于西矿带上部脉状锡矿（化）体,而下部的网脉状、似层状锡矿体尚未揭露到,由此预测箭猪坡矿床深部找矿空间及找矿潜力大。     

Occurrence and volatilization behavior of Pb, Cd, Cr in Yima coal during fluidized-bed pyrolysis

The volatilization behavior of Pb, Cd, Cr and the influence of coexisting mineral matters were investigated during pyrolysis of Yima coal in a fluidized-bed reactor at temperatures ranging from 500 to 900 °C. The modes of occurrence of Pb, Cd, Cr in Yima raw coal and two char samples were determined using density fractionation, demineralization and sequential chemical extraction methods. Lead in Yima coal is mostly associated with mineral matter in various forms, mainly pyrite, sulfates and monosulfides. Large part of cadmium is associated with pyrite. Chromium in Yima coal is mainly associated with organic matter. Different trends are observed for various forms of trace metals during pyrolysis. Lead associated with pyrite, sulfates and carbonates, lead in water soluble and ion exchangeable forms, and cadmium associated with pyrite are all unstable under pyrolysis conditions. During Yima coal pyrolysis, the volatilities of lead and cadmium vary greatly with pyrolysis temperature, while chromium volatility in Yima raw coal only has slight changes over the temperature range (500-900 °C) studied. The volatility of Pb, Cd, Cr in demineralized Yima coal (YimaD) is much higher than that of Yima coal during pyrolysis. New thermally stable forms of Pb, Cd and Cr are formed during pyrolysis of Yima, whereas the sources of them are different. The interactions between chromium and its coexisting mineral matters in Yima coal retard its vaporization during pyrolysis.     

氢化物发生-原子荧光光谱法测定生活废水中微量汞

研究了用氢化物发生-原子荧光法测定生活废水中微量汞的最佳实验条件及其测定微量汞的方法.此法是在硝酸介质中,以硼氢化钾作还原剂,将被测元素转化为挥发性氢化物,以高纯氩气作为载气将挥发性气氢化物从母液分离,并导入石英炉原子化器中原子化.以空心阴极灯作激发光源,激发被测元素原子发出荧光,其荧光强度在一定范围内与被测元素的浓度成正比.该方法简便、快速、准确.     

高贝利特水泥活化技术的研究

在生料中掺入微量元素及矿化剂来活化β—C2S，经试验确定，BasSO4对高贝利特活化的最佳掺钡量为0．8％，并可将高贝利特水泥的3d强度提高18％，28d强度提高到近120MPa；在掺入氟硫复合矿化剂后，高贝利特水泥的活性更高，更加贴近实际生产，也能达到节约能源、提高早期强度的试验目的。     

Analysis of blood and tissue in gallbladder cancer

Particle induced X-ray emission, particle induced γ-ray emission studies has been carried out to analyse normal and carcinoma tissues and blood samples of gallbladder of both sexes and seventeen trace elements namely Na, Mg, Al, K, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br and Pb were estimated in the tissue and blood samples. In the present study, concentration of Zn in the carcinoma gallbladder tissue is less than that of the normal gallbladder tissue. Tobacco habit could be one of the important factors to decrease the elemental concentrations in blood and tissue samples.     

Geochemical characteristics of Callovian –Oxfordian carbonates in Samandepe gas field,Amu Darya Basin, Turkmenistan

The Callovian-Oxfordian carbonate reservoirs are the most important hydrocarbon reservoir in the Samandepe gas field,Amu Darya basin,Turkmenistan.Based on the analysis of Fe,Mn and Sr trace elements,and carbon,oxygen and strontium isotopes,the genesis and evolutionary characteristics of the carbonate reservoirs were studied,and the conclusions were follows:1) Sustained transgressive-regressive cycles played an important role during Callovian-Oxfordian.The reservoir of reef-bank facies was well developed in the period of transgression,while the regional dense cap rocks developed in the period of regression;2) The 87 Sr/86 Sr ratio measured from rudist shells yields an age of 157.2 Ma according to the global strontium isotope curve;3) As diagenetic intensity increased,δ 13 C changed little,and δ 18 O showed strong negative deviation but was still limited to the range of Late Jurassic seawater.High Fe and Sr contents,and low Mn content,and the evolutionary trend of δ 13 C and δ 18 O all indicate that diagenesis occurred in a relatively confined environment,where the fluids were relatively reducing and contained hot brine.The stage of diagenesis reached is mesodiagenesis,which is very favorable for preservation of primary pores in carbonates;4) Strong dissolution of reef limestones,burial dolomitization and hydrothermal calcite precipitation were all the results of the interaction between the 87 Sr-rich diagenetic fluid and rocks;5) The analysis results of isotopes,fluid inclusions and vitrinite reflectance show that the diagenetic fluid was compaction-released water that originated from the deep,coal-bearing clastic strata.     

周期为p≡7(mod 8)的一类新六次剩余序列的迹表示

构造了一类新的周期为素数 的六次剩余序列,利用有限域和差集理论给出了该序列在周期为素数 情形下的迹函数表示.新序列的线性复杂度为 ,优于Hall六次剩余序列在相同条件下的线性复杂度.