二氨丙基苯固化剂的合成及应用

以无水三氯化铝为催化剂,用苯和1,3-口恶嗪-2-酮进行氨丙基化反应合成了二氨丙基苯。研究了物料物质的量比、反应时间、温度对反应的影响,确定了合成二氨丙基苯的较佳反应条件。通过DSC对环氧树脂中该固化剂的加入量和固化工艺条件进行了研究,对环氧树脂固化物的力学性能等指标进行了考察。     

含柔性链SiO_2/EP纳米杂化材料的固化动力学

采用溶胶-凝胶法制备了聚硅酸溶胶,在其表面接枝柔性链段并以此为前驱物,通过原位聚合法制备了SiO2/EP纳米杂化材料。利用差示扫描量热仪对杂化材料的固化动力学进行了研究。采用Kissinger和Crane等方法,利用不同升温速率下的DSC曲线,分别求出固化体系的表观活化能Ea、反应级数n和频率因子A等参数,得出了固化体系的反应动力学方程。     

Damage and deterioration mechanism and curing technique of concrete structure in main coal cleaning plants

Concrete structures in main coal cleaning plants have been rebuilt and reinforced in the coal mines of the Shanghai Da-tun Energy Sources Co. Ltd., the first colliery of the Pingdingshan Coal Co. Ltd. and the Sanhejian mine of the Xuzhou Mining Group Co. Ltd. In these projects, the operating environment and reliability of concrete structures in the main plants of the three companies were investigated and the safety of the structures inspected. Qualitative and quantitative analyses were made on the spe-cial natural, technological and mechanical environments around the structures. On the basis of these analyses, we discuss the long-term, combined actions of the harsh natural (corrosive gases, liquids and solids) and mechanical environments on concrete structures and further investigated the damage and deteriorating mechanisms and curing techniques of concrete structures in the main coal cleaning plants. Our study can provide a theoretical basis for ensuring the reliability of concrete structures in main coal cleaning plants.     

紫外/臭氧复合杀灭水中细菌性能研究

为开发一种高效灭菌方法,研究了UV/O3的复合灭菌性能,对紫外辐射、臭氧和羟基自由基等在体系中的各自作用进行探讨,同时考察pH值、温度等对灭菌效果的影响.结果表明,UV/O3较单独紫外或臭氧灭菌时效果有所提高,在初始臭氧质量浓度为5.02mg·L-1,液面紫外辐射强度为6.5mW·cm-2,灭菌时间1.5～9.0s时,UV/O3对细菌总数灭菌率达3.6～6.4,单独紫外时为1.8～4.7,单独臭氧时仅为1.6～3.0.羟基自由基的产生是复合灭菌效果增加的主要原因.随紫外辐射强度和臭氧投加量的增加,复合灭菌作用得到提高.pH值在5.5～8.5变化时,UV/O3灭菌效果随原水pH值的增加略有提高.温度由10℃上升到27℃时,灭菌效果稍有下降.由此可见,UV/O3是一种高效可行的水体灭菌技术。     

日盲区紫外光非视线传输模型

为建立一个更接近实际情况的紫外光非视线传输模型,用来处理复杂的大气条件和边界条件,建立了基于Monte Carlo方法的紫外光非视线传输快速算法模型。分析了发射功率为1 W的单色紫外光信号在不同环境条件下的脉冲响应函数和边界条件对信号强度空间分布的影响,以及系统发射仰角和接收仰角与探测信号强度的关系。与单次散射模型比较,该模型具有更高的精度和边界处理能力。对合理涉及通信系统、提高通信质量都有很大提高。     

Single‐pack,self‐curable,aqueous‐based polyurethane dispersion containing a disperse dye

An organic‐solvent‐soluble disperse dye was introduced into an aqueous phase by a reaction with a self‐emulsified, aqueous‐based polyurethane (PU), and this resulted in the formation of a homogeneous, aqueous polymeric dye dispersion. This aqueous polymeric dye was stable in a water phase with excellent color extension upon application. It was formulated with a latent curing agent, polyaziridine (e.g., TMPTA‐AZ), as a single‐component, self‐curable, aqueous polymeric dye. The curing reaction took place between PU carboxylic acid and the latent curing agent upon drying. A self‐cured polymeric dye was obtained with excellent color extension and fastness and resistance to organic solvents and water after drying. This single‐component, self‐curable, aqueous‐based PU system containing a dye has potential for printing, writing, and dyeing applications. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 2006 © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3741–3747, 2006     

Adhesion properties of UV crosslinked polystyrene-block-polybutadiene-block-polystyrene copolymer and tackifier mixture

The peel and tack properties of mixtures of polystyrene-block-polybutadiene-block-polystyrene (SBS) and a tackifier were investigated after these were crosslinked by ultraviolet (UV) irradiation at various amounts of benzophenone (BP) as a photoinitiator and trimethylolpropane mercaptopropionate (TRIS) as a crosslinking agent.The degree of crosslinking of polybutadiene (PB) block in the SBS mixture was qualitatively estimated from the amount of gel fraction as well as the change in the glass transition temperature of the PB block. The crosslinking of the PB block was done within 3 min after UV irradiation and the peel strength of crosslinked specimens was as low as 45[percnt] of specimens without crosslinking. Nano-tack and bulk tack properties as well as the surface tension of mixtures were measured depending upon amounts of BP and TRIS.     

Mechanical characterization and chemical resistances of cured unsaturated polyester resins modified with vinyl ester resins based on recycled poly(ethylene terephthalate)

Unsaturated polyester resin (UP) was prepared from glycolyzed oligomer of poly(ethylene terephthalate) (PET) waste based on diethylene glycol (DEG). New diacrylate and dimethacrylate vinyl ester resins prepared from glycolysis of PET with tetraethylene glycol were blended with UP to study the mechanical characteristics of the cured UP. The vinyl ester resins were used as crosslinking agents for unsaturated polyester resin diluted with styrene, using free‐radical initiator and accelerator. The mechanical properties of the cured UP resins were evaluated. The compressive properties of the cured UP/styrene resins in the presence of different vinyl ester concentrations were evaluated. Increasing the vinyl ester content led to a pronounced improvement in the compression strength. The chemical resistances of the cured resins were evaluated through hot water, solvents, acid, and alkali resistance measurements. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3175–3182, 2007     

Application of Taguchi method in determining optimum level of curing system of NBR/PVC blend

Taguchi method is applied in this study to determine the optimum level of curing system (sulfur, MBTS, and CBS) in a NBR/PVC blend. By considering physicomechanical properties of cured NBR/PVC blend, optimum level of curing system is determined. A fixed master batch formulation of NBR/PVC is used, and the effect of curing system is studied on the physicomechanical properties of NBR/PVC blend, such as tensile strength (TS) and elongation‐at‐break (EB) before and after aging and also hardness and abrasion. The L9 orthogonal array that includes nine rows and four columns is applied. In this matrix, rows show the experiments and three columns show the amount of three factors (sulfur, MBTS, and CBS) and one column is left arbitrarily as an empty column. In this array, the columns are mutually orthogonal. The optimum physicomechanical properties of cured NBR/PVC blend are at 2 phr sulfur, 2 phr MBTS, and 0.5 phr CBS of curing system. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5358–5362, 2006     

Loss of Curing Agent During Thin Film (Droplet) Curing of Thermoset Material

Recently, it has been reported by our group and others^1.2 that loss of curing agent is encountered during the curing of small droplets or thin films of amine cured epoxies. In our earlier study³ results were reported on loss of curing agent in small droplets used in conducting the rnicrobond, single fiber test for determination of interfacial shear strength (ISS). It was reported that use of a volatile curing agent (meta-phenylene diamine (m-PDA) with DGEBA resin) resulted in increasing amounts of curing agent being lost (as measured by T₈ of the cured droplets) with decreasing droplet size during the processing procedure. Droplets smaller than 150 micrometers were seen to lose up to 40% of the curing agent leading to alteration of the mechanical properties of the droplet and, therefore, causing measured values of ISS to be exceedingly low. Use of a less volatile curing agent (Jeffamine 700, a polyether diamine, Texaco Specialty Chemicals) in combination with DGEBA resin produced results which indicated that loss of curing agent was not occuring. This study was undertaken to show the relationships between film (or droplet) size and the amount of curing agent lost (during the processing) for three different aminecured epoxy systems.