晶片表面几何特性对键合的影响

由最小能量原理导出的键合条件出发,利用线性薄板理论,在同一理论模型框架下,通过量度键合过程能否进行的弹性应变能累积率,分析了晶片表面的宏观尺度的弯曲和微观尺度的起伏对晶片键合的影响,并对所得结果进行了详细讨论．     

片式电阻保护浆料的制备

通过与日本样进行对比试验,研究了片式电阻保护浆料的制备工艺及要求。分析了玻璃组成和浆料配方对元件电阻值漂移的影响,并对其保护机理进行了探讨。制备的浆料达到日本样技术指标的要求。利用4号玻璃组分的1MΩ片电阻的阻值漂移率最小为0.9%     

室温晶片键合界面的弹性理论分析

利用接触弹性力学的DMT(Derjaguin,Muller,Toporov)理论,考虑晶片表面起伏的随机性,导出了晶片键合的实际接触面积和有效键合能。并对结果进行了数值分析。讨论了影响室温键合强度大小的各种因素。     

基于Ansoft的电力机器人永磁吸附单元有限元分析

为满足爬壁机器人在狭窄的发电机定子气隙中能可靠地运行,设计了一种基于Halbach阵列的永磁吸附单元。使用Ansoft Maxwell软件建立二维磁场模型,采用有限元分析法对新型吸附单元的磁场进行分析,得到了其磁力线与磁感应强度的分布;通过与传统永磁吸附单元磁场的比较,得出新型吸附单元具有永磁磁能利用率高、单边磁场的特点,验证了新型吸附单元在发电机定子气隙中吸附的可靠性;并分析了结构参数的变化对吸附性能的影响,为吸附单元结构设计提供了参考数据。     

Imide-aryl ether benzoxazole random copolymers

Novel imide-aryl ether benzoxazole copolymers were prepared and their morphology and mechanical properties investigated. A key feature of these copolymers is the incorporation of a benzoxazole moiety by the use of 2,2′-bis[4-(3-aminophenoxy)phenyl]-6,6′-bibenzoxazole or 2,2′-bis[4-(4-aminophenoxy)-phenyl]-6,6′-bibenzoxazole as co-diamines in polyimide syntheses. The preparation of these diamines involved the nucleophilic aromatic substitution of 2,2′-bis(4-fluorophenyl)-6,6′-bibenzoxazole with either 3- or 4-aminophenol in the presence of K₂CO₃. The diamines were co-reacted with various compositions of pyromellitic dianhydride (PMDA) and 4,4′-oxydianiline (ODA) to synthesize the desired poly(amic acids). Films were cast and cured (350°C) to effect the imide formation, affording films with elongations between 40 and 110% and moduli in the 2000–2750 MPa range. The copolymers exhibited good dimensional (T_g in excess of 300°C) and thermal stability. Wide-angle X-ray diffraction measurements on the copolymers showed that the ordered morphology characteristic of PMDA/ODA polyimide was retained. Improvements in the auto-adhesion were observed, particularly in those copolymers which displayed a T_g.     

Fabrication of gold micro-spine structures for improvement of cell/device adhesion

Improvement of the interface contact between biological objects and electronic devices can significantly enhance the quality of electronic signal transfer. The surface of biosensor can be artificially modified in order to strengthen the adhesion of biological cells. We report on results of fabrication of micron and submicron golden spines by means of e-beam lithography and electroplating. The fabrication technique allows easy modification of the size and shape of golden spines by variation of processing parameters. The structures with different spine profiles and spacing have been fabricated for optimization of cell growth conditions. We present the results of growth of rat cortical neurons on the surface of spine modified samples. Well-defined cell guidance was established at the spine arrays. Furthermore, the results of transmission electron microscope and focused ion beam technique confirm the good adhesion between the spines and cell structures.     

温度对玻璃纤维-环氧树脂润湿性的影响

采用Wilhelmy法测定不同温度下CYD128环氧树脂的表面张力和环氧树脂浸润ST,ECT,TM玻璃纤维的动态接触角,计算玻璃纤维的表面自由能及环氧树脂浸润玻璃纤维的热力学黏附功,分析了玻璃纤维-环氧树脂润湿特性。结果表明:室温升至60℃,环氧树脂的黏度及表面张力降低,环氧树脂与玻璃纤维的热力学黏附功升高,玻璃纤维与环氧树脂的润湿性逐步改善;高于60℃后影响较小。     

Adhesion and Mechanical Properties of PNIPAM Microgel Films and Their Potential Use as Switchable Cell Culture Substrates

Thermoresponsive poly(N‐isopropylacrylamide) (PNIPAM) microgel films are shown to allow controlled detachment of adsorbed cells via temperature stimuli. Cell response occurs on the timescale of several minutes, is reversible, and allows for harvesting of cells in a mild fashion. The fact that microgels are attached non‐covalently allows using them on a broad variety of (charged) surfaces and is a major advantage as compared to approaches relying on covalent attachment of active films. In the following, the microgels’ physico‐chemical parameters in the adsorbed state and their changes upon temperature variation are studied in order to gain a deeper understanding of the involved phenomena. By means of atomic force microscopy (AFM), the water content, mechanical properties, and adhesion forces of the microgel films are studied as a function of temperature. The analysis shows that these properties change drastically when crossing the critical temperature of the polymer film, which is the basis of the fast cell response upon temperature changes. Furthermore, nanoscale mechanical analysis shows that the films posses a nanoscopic gradient in mechanical properties.     

无机熔盐镀铝层的制备与性能研究

利用AlCl3-NaCl-KCl三元无机熔盐体系在Q235低碳钢基体上进行了镀铝试验,并就不同电镀工艺对铝镀层表面 形貌、厚度、结构、结合力及耐蚀性能等进行了研究。结果表明,AlCl3-NaCl-KCl无机熔盐体系镀铝层为银白色,并呈现均 匀、细小的针片状生长特征。铝镀层的厚度随电流密度和电镀时间的增加而增大;在低电流密度下,铝镀层主要由(200)面 结构组成;在高电流密度下,铝镀层易形成(111)面的结构。铝镀层与碳钢基体问的结合力随镀层厚度的增加而减少,但均 大于30 N。在3．5％NaCl的水溶液中,铝镀层具有较好的耐蚀性能。铝镀层的最佳工艺为电流密度3．3-4．0 A/dm2,电镀时间 45-90 min。