全文获取类型
收费全文 | 2655篇 |
免费 | 509篇 |
国内免费 | 274篇 |
专业分类
电工技术 | 152篇 |
综合类 | 131篇 |
化学工业 | 780篇 |
金属工艺 | 38篇 |
机械仪表 | 51篇 |
建筑科学 | 43篇 |
矿业工程 | 34篇 |
能源动力 | 33篇 |
轻工业 | 265篇 |
水利工程 | 21篇 |
石油天然气 | 59篇 |
武器工业 | 15篇 |
无线电 | 429篇 |
一般工业技术 | 275篇 |
冶金工业 | 37篇 |
原子能技术 | 3篇 |
自动化技术 | 1072篇 |
出版年
2024年 | 29篇 |
2023年 | 93篇 |
2022年 | 142篇 |
2021年 | 187篇 |
2020年 | 159篇 |
2019年 | 167篇 |
2018年 | 121篇 |
2017年 | 147篇 |
2016年 | 129篇 |
2015年 | 130篇 |
2014年 | 179篇 |
2013年 | 203篇 |
2012年 | 181篇 |
2011年 | 192篇 |
2010年 | 153篇 |
2009年 | 158篇 |
2008年 | 146篇 |
2007年 | 156篇 |
2006年 | 132篇 |
2005年 | 92篇 |
2004年 | 69篇 |
2003年 | 54篇 |
2002年 | 44篇 |
2001年 | 35篇 |
2000年 | 37篇 |
1999年 | 29篇 |
1998年 | 26篇 |
1997年 | 29篇 |
1996年 | 24篇 |
1995年 | 17篇 |
1994年 | 29篇 |
1993年 | 28篇 |
1992年 | 21篇 |
1991年 | 14篇 |
1990年 | 8篇 |
1989年 | 18篇 |
1988年 | 10篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 6篇 |
1984年 | 9篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有3438条查询结果,搜索用时 15 毫秒
41.
研究了meso-四卟啉和meso-四卟啉的离解常数。TBPhP的离解常数为:pKa4=1.13.pKa3=1.88,pKA2=12.21;TTPS的离解常数为:pKa4=4.47,pKa3=6.26。外还发现了两卟啉的酸碱诱导聚合。 相似文献
42.
The aggregation pheromone of the German cockroach,Blattella germanica, consists of attractant and arrestant, which can be detected by olfactometer and choice-chamber assay, respectively. Both were extracted from the frass-contaminated filter paper being used as a shelter. They were separated by solvent partition withn-butanol and water. The arrestant from then-butanol phase was purified by open column chromatography and then successive HPLC isolated two major arrestant components. Spectral evidence from SI-MS, HR-EI-MS, and NMR experiments with pulse techniques provided possible structures as 1-(6-chloro-4,5-epoxy-5-stigmast-3-yl)--d-glucopyranoside and 1-(6-chloro-5-hydroxy-5-stigmast-3-yl)--d-glu-copyranoside, denoted as blattellastanoside-A and blattellastanoside-B, respectively. They represented arrestant activity as median effective doses (ED50) at 0.044 (A) and 3.2 (B) nmol on 1.0 cm2 of Whatman No. 1 filter paper. 相似文献
43.
江云宝 《感光科学与光化学》1996,(3)
在水-二氧六环混合介质中,对二正癸基氨基苯甲腈(DDABN)分子,在水的体积分数超过0.5后,发生簇集并可观察到双重荧光发射且长波长发射带位置与在纯二氧六环中相近。该发射带被证实系分子内扭转电荷转移(TICT)带。吸收光谱表明DDABN簇集体为J-型。 相似文献
44.
We investigated cues that mediate the aggregation behavior of immature pentatomid bugs by using nymphs of six different pentatomid bug species (Nezara viridula, Acrosternum hilare, Chlorochroa ligata, Chlorochroa sayi, Thyanta pallidovirens, and Euschistus conspersus). When first instars of any two species were put together in a Petri dish, they readily formed heterospecific aggregations similar to their natural conspecific aggregations. The chemical profiles of first and second instar nymphs of each species were determined by solvent extraction with pentane, followed by GC-MS analysis. Immature bugs of the different species had some compounds in common, and some that were more species specific. Within a species, there were distinct differences in the profiles of compounds extracted from first and second instars. Bugs did not aggregate around untreated polysulfone beads (1 mm diam) that were glued together in groups approximating bug egg masses, suggesting that tactile cues alone were insufficient to induce aggregation. Furthermore, when tested over a range of doses, groups of polysulfone beads treated with crude whole-body extracts of bugs did not induce or maintain aggregations. However, first instar N. viridula nymphs did respond to beads treated with two of the three major components of bug extracts. 4-Oxo-(E)-2-decenal induced significant aggregations at two doses, whereas tridecane, the major component in extracts from all six species, did not, and (E)-2-decenal was repellent. The repellence of (E)-2-decenal may explain why we and previous researchers were unable to induce aggregations of first instar N. viridula using whole-body extracts. 相似文献
45.
Large aggregation interval asymptotics are used to investigate the relation between Granger causality in disaggregated vector autoregressions (VARs) and associated contemporaneous correlation among innovations of the aggregated system. One of our main contributions is that we outline various conditions under which the informational content of error covariance matrices yields insight into the causal structure of the VAR. Monte Carlo results suggest that our asymptotic findings are applicable even when the aggregation interval is small, as long as the time series are not characterized by high levels of persistence. 相似文献
46.
Katsutoshi Nagaoka Kulathuiyer Seshan Kazuhiro Takanabe Ken-ichi Aika 《Catalysis Letters》2005,99(1-2):97-100
CH4/CO2 reforming over Pt/ZrO2, Pt/CeO2 and Pt/ZrO2 with CeO2 was investigated at 2 MPa. Pt/ZrO2, which shows stable activity under 0.1 MPa, and Pt/CeO2 showed gradual deactivation with time at the high pressure. The deactivation was suppressed drastically on Pt/ZrO2 with CeO2 prepared by different impregnation order (co-impregnation of Pt and CeO2 on ZrO2, and consecutive impregnation of Pt and CeO2 on ZrO2). The amount of coke deposition was found insignificant and similar among all the catalysts (including Pt/ZrO2 and Pt/CeO2). Catalytic activity after the reaction for 24 h was in agreement with Pt particle size after the reaction for same period, indicating that the difference of the catalytic stability is mainly dependent on the extent of Pt aggregation through catalyst preparation, H2 reduction, and the CH4/CO2 reforming. Pt aggregation and the amount of coke deposition were least pronounced on (Pt–Ce)/ZrO2 prepared by impregnation of CeO2 on Pt/ZrO2 and the catalyst showed highest stability. 相似文献
47.
48.
文章介绍了无线传感网络的安全数据融合技术,针对当前数据融合算法安全性不高、开销过大以及融合精度低等问题,提出了基于参考值的可恢复隐私保护数据融合算法。该算法利用公钥同态加密机制为数据提供端到端的机密性和完整性认证。此外,该算法动态地为网络中的每个节点设定下次传输的参考值,并通过传输采样值和参考值之间的差值来减少网络中的数据传输量。仿真结果表明,该算法可以有效地减少数据传输量,提高整个网络的能量和带宽效率。 相似文献
49.
针对电网运行可靠性评估计算量大,但又要求计算时间短的问题,提出了一种基于分布式计算的电网运行可靠性评估算法。该算法采用改进的状态选择和分析方案,解决了计算终端间随机数序列的关联性问题,有效地降低了通信量,提高了计算速度。基于该算法编制的评估软件已通过RTS-24系统和某省级电网的实际运行测试,测试结果表明,该算法不仅能够有效评估电网运行可靠性,而且计算速度随计算终端数增加呈一定倍数提高。 相似文献
50.
(Z)-11-Octadecenyl acetate (Z11–18Ac) and (Z)-11-eicosenyl acetate (Z11–20Ac) were identified as the aggregation pheromones ofDrosophila ananassae, andZ11–20Ac was identified as the aggregation pheromone ofDrosophila bipectinata. Z11–18Ac andZ11–20Ac were not attractive alone; however, in combination with fermenting food odors, the acetates attracted flies of both sexes in a wind-tunnel olfactometer. The pheromones were present in the ejaculatory bulb of sexually mature male flies and transferred to the female during mating. MaleD. bipectinata released little if anyZ11–20Ac to the food; however, recently mated females releasedZ11–20Ac to the surrounding surfaces in just a few hours after mating.D. ananassae males, on the other hand, appeared to release moreZ11–18Ac andZ11–20Ac to the surroundings than mated females. AlthoughD. bipectinata males had noZ11–18Ac, flies were as attracted toZ11–18Ac as to an equal quantity ofZ11–20Ac.D. ananassae were attracted toZ11–18Ac but not toZ11–16Ac orZ11–20Ac. However,Z11–20Ac in combination withZ11–18Ac was significantly more attractive thanZ11–18Ac alone. 相似文献