工业纯铝在模拟海水中的电化学腐蚀行为

为研究铝在海水中的腐蚀过程,采用电化学阻抗谱、浸泡试验、扫描电子显微镜研究工业纯铝在模拟海水中的腐蚀行为.结果表明:铝在模拟海水中发生点蚀的区域为富含Fe的晶间化合物处,点蚀半径随时间的增加而扩大.铝在模拟海水中的溶解曲线分为4个区间:活性溶解区、过渡区、过钝化区、钝化区.铝在模拟海水中,极化电位为过钝化区时,转移电阻R t随着电位的升高而变小,铝发生严重的点蚀;而极化电位为钝化区时,铝的转移电阻R t随着电位的升高基本不变,铝的溶解行为受到抑制.工业纯铝在模拟海水中发生点蚀的电位区间是-0.45～-0.65 V,钝化电位区间为-0.75～-0.85 V.     

Evolution of insoluble eutectic Si particles in anodic oxidation films during adipic-sulfuric acid anodizing processes of ZL114A aluminum alloys

The effects of insoluble eutectic Si particles on the growth of anodic oxide films on ZL114A aluminum alloy substrates were in-vestigated by optical microscopy (OM) and scanning electron microscopy (SE...     

Interfacial Microstructure and Mechanical Properties of Al/Mg Butt Joints Made by MIG Welding Process with Zn-Cd Alloy as Interlayer

Butt joints between Mg alloy AZ31 B and pure Al 1 060 sheets were produced via metal inert gas welding process with Zn-Cd alloy foil. Crack-free Al/Mg butt joints between AZ31 B Mg alloy and pure Al 1060 sheets were obtained. Intermetallic compound layer 1 and layer 2 had formed in fusion zone/Mg alloy and the average thickness of the layer 1 was about 50 μm. The intermetallic compound layer 1 consisted of Al12Mg17 and Mg2Si phases while layer 2 consisted of Al12Mg17, Mg2Si and Mg Zn2 phases. The crack started from the IMC layer at the bottom of the joint and propagated along the brittle IMC layer, then expanded into weld metal during the SEM in situ tensile test. The highest tensile strength of the dissimilar metal butt joints could reach 46.8 MPa and the effect ofinterfacial IMC layer on mechanical property of the joint was discussed in detail in the present study.     

超细Al（OH）3的粒度控制研究

采用铝酸钠种子分解法制备超细Al（OH）3.用X射线衍射仪（XRD）表征了样品的晶相组成,用扫描电子显微镜（SEM）观察了样品的形貌,用激光粒度分析仪测定样品的粒度分布.研究了NaOH浓度、NaOH/Al（OH）3摩尔比,分解温度,分解时间、晶种率和搅拌速率等因素对Al（OH）3的粒度的影响.结果表明：NaOH浓度越高,分解温度越低,NaOH/Al（OH）3摩尔比越小,得到的Al（OH）3颗粒的粒度越小.试验条件为：NaOH浓度180 g/L,NaOH/Al（OH）3摩尔比1.15,分解温度40℃,分解时间26 h,晶种率8％,搅拌速率200 rpm时,氢氧化铝颗粒的平均粒度为2.89 μm.     

高温预析出对Al-Zn-Mg-Cu铝合金显微组织、强度和应力腐蚀抗力的影响

通过改变固溶条件 ,对Al Zn Mg Cu高强铝合金采用先高温后低温的两步固溶处理 (高温预析出 )来改善晶内和晶界的析出状态 ,研究了高温预析出对Al Zn Mg Cu铝合金的金相组织、强度和应力腐蚀性能的影响。结果表明 ,4 6 5℃高温预析出在保持较高强度和塑性的同时 ,可以改善合金的抗应力腐蚀性能     

液态铝合金表面张力快速检测新方法与装置

表面张力是液态合金的重要物性参数之一,铝合金表面张力与其变质处理效果及充型能力等质量参数密切相关,研究铸造铝合金表面张力快速检测方法及装置,对于开发铝合金熔炼质量炉前实时评价系统具有非常重要的实际意义.介绍了一种液态铝合金表面张力快速测试的新方法和新装置,新方法以固定时间内吹入被测液体的气泡个数以及气泡在生长过程中内部压差变化为信息参数,通过回归公式求解表面张力.基于该方法研制的表面张力新型测试装置由单片机测控单元、探头及其锁紧和升降机构、供气单元等部分构成.采用新装置可在5 s内测得铝合金表面张力,且具有较高的测试精度.     

Influence of Reinforcement Content and Matrix Composition on the Oxidation Resistance of Aluminum-Matrix Composites (A3xx.x/SiCp)

A study was made on the influence of the SiCp proportion and the matrix concentration of four composites (A360/SiC/10p, A360/SiC/20p, A380/SiC/10p, A380/SiC/20p) on their oxidation behavior. Gravimetric tests were used in a kinetics study of the corrosion process at different temperatures (350, 400, 450, and 500°C). The influence of corrosion on mechanical properties was evaluated by hardness measurements. The nature of corrosion products and the influence of the microstructure on the morphology and growth of the oxidation layer were analyzed by SEM and low-angle XRD. The extent of the damage due to oxidation for Al/SiCp composites increases with the SiCp concentration due to the increase of nucleation sites. One of these nucleation sites is in the interface region between the matrix and the particles. Oxidation was influenced more by the percentage of alloy elements in the matrix than by the proportion of SiCp reinforcement. The presence of Cu and Ni in the matrix favors the oxidation process through the formation of different intermetallic compounds.     

Corrosion resistance of austenitic stainless steel separator for molten carbonate fuel cell

STS310S and SC-STS310S (simultaneously co-deposited chromium and aluminum onto 310S austenitic stainless steel substrate by pack-cementation process) were used as separator materials on the cathode side of a molten carbonate fuel cell. With the STS310S, corrosion proceeded via three steps; a formation step of unstable corrosion product, a protection step against corrosion until breakaway, and an advance step of corrosion after breakaway. The final corrosion product was LiFeO₂ and the loss of mass was 6.5 mg/cm² after a corrosion test of 480 hr at 650°C. The SC-STS310S showed more effective corrosion resistance, however, than did common STS310S. There was especially no corrosion loss on the SC-STS310S after the 480 hr corrosion test. It is anticipated that it will be very useful as an alternative separator on the cathode side off the MCFC in the future.