MICROWAVE PERMEABILITY SPECTRA OF SPUTTERED Fe-Co-B SOFT MAGNETIC THIN FILMS

Permeability characteristics of sputtered soft magnetic Fe40Co40B20 thin films are investigated in the range of O. 5 to 5 GHz by a shortened microstrip transmission line perturbation method. Excellent microwave permeability is achieved at 0.4 Pa argon pressure： fr is 3.32 GHz, the real and imaginary part of permeability at 0.5 GHz are 104 and 61, respectively. In addition, the thickness effect on permeability is also studied. The minimum damping can be achieved at the thinnest film. Different sources contributed to in-plane anisotropy are discussed briefly. The deviation between the peak frequency of the imaginary part and the zero-crossing frequency of the real part of permeability is also presented.     

Sensing Magnetic Field and Intermolecular Interactions in Diamagnetic Solution Using Residual Dipolar Couplings of Zephycandidine

An unusual residual dipolar coupling of methylene protons was recorded in NMR spectra because aromatic zephycandidine has preferential orientation at the external magnetic field. The observed splitting contains contribution from the dipole–dipole D-coupling and the anisotropic component of J-coupling. Absolute values of the anisotropy of magnetic susceptibility |Δχ_ax| are larger for protic solvents because of the hydrogen-bonding compared to aprotic solvents for which polar and dispersion forces are more important. The energy barrier for the reorientation due to hydrogen-bonding is 1.22 kJ/mol in methanol-d_4, 0.85 kJ/mol in ethanol-d₆ and 0.87 kJ/mol in acetic acid-d₆. In dimethyl sulfoxide-d₆, 1.08 kJ/mol corresponds to the interaction of solvent lone pair electrons with π-electrons of zephycandidine. This energy barrier decreases for acetone-d₆ which has smaller electric dipole moment. In acetonitrile-d₃, there is no energy barrier which suggests solvent ordering around the solute due to the solvent-solvent interactions. The largest absolute values of the magnetic anisotropy are observed for aromatic benezene-d₆ and tolune-d₈ which have their own preferential orientation and enhance the order in the solution. The magnetic anisotropy of “isolated” zephycandidine, not hindered by intermolecular interaction could be estimated from the correlation between Δχ_ax and cohesion energy density.     

The Impact of the Azo-Chromophore Sort on the Features of the Supramolecular Azopolyimide Films Desired to Be Used as Substrates for Flexible Electronics

High-performance supramolecular polyimide systems were synthesized via a simple and innovative approach using two types of azo-chromophores, leading to concomitant special properties: high thermostability, the ability to be processed in the form of films with high flexibility, adequate morphological features, and good structuring capacity via phase mask ultraviolet (UV) laser irradiation, induced by the presence of the azo groups (–N=N–). The dimension and the anisotropy degree of the micro/nano patterns obtained on the surface of the flexible films (determined by atomic force microscopy) depend on the azo-dye type used in the supramolecular azopolyimide synthesis, which were higher when the azo-chromophore containing a –cyano group (–C≡N) was used. The molecular dynamics method, an excellent tool for an in-depth examination of the intermolecular interactions, was used to explain the morphological aspects. Energetic, dynamic and structural parameters were calculated for the two systems containing azo-chromophores, as well as for the pristine polymer system. It was highlighted that the van der Waals forces make a major contribution to the intermolecular interactions. The results from the combination of the dynamic analysis and the concentration profile explain the better mobility of the polyimide chains with a maximum content of azo groups in the cis configuration compared to the other systems. Taking all these data into account, the surfaces of the films can be tuned as required for the proposed applications, namely as substrates for flexible electronis.     

各向异性柔性粘结NdFeB磁体的研制

通过不同的工艺路线制备了各向异性柔性黏结NdFeB磁体,并且分析了影响各向异性柔性黏结NdFeB磁体的因素。试验结果表明,通过溶解造粒和脉冲磁化以及磁场压延等工艺能够显著提高磁体的磁性能。     

水平井流量分析

本文研究水平井在底水或边水油、气藏中的二维稳定渗流问题，利用势函数的镜像迭加原理，得到了水平井的流量公式，并讨论了油层厚度、渗透率各向异性和供水边缘到水平井的距离对水平井产能的影响。     

脆性各向异性岩石破坏过程数值模拟

在改进刚体弹簧方法的基础上,采用Hoek-Brown准则判断界面破坏,提出各向异性Voronoi网格的生成方法,并引入界面细观参数各向异性的赋值函数,最终建立了脆性各向异性岩石损伤破坏过程的数值模拟方法。利用该方法对文献中的试验结果进行了模拟。计算表明,该方法不仅能成功模拟岩石抗压强度随软弱面倾角变化的“U”形规律,定量上与试验结果吻合良好,而且能同时定量模拟岩石变形特性即弹性模量和泊松比的各向异性特征。     

各向异性软黏土基坑抗隆起稳定极限平衡分析

天然黏土表现出明显的强度各向异性,在软黏土地区中的基坑抗隆起分析时有必要考虑土体各向异性的影响。针对桩墙式支护基坑绕下道支撑的圆弧滑动抗隆起稳定模式,采用基于空心圆柱仪（HCA）杭州原状软黏土试验结果的土体强度各向异性不排水强度公式,根据极限平衡法推导得到坑底抗隆起稳定分析公式。结合算例,讨论了土体强度各向异性、挡墙入土深度、最下道支撑和坑底间的距离等因素对坑底抗隆起稳定的影响,比较了该文方法与传统方法结果的差别,指出不考虑土体强度各向异性的软黏土基坑抗隆起分析和基于传统Casagrande各向异性公式的抗隆起分析都将高估杭州软黏土基坑的抗隆起稳定性。最后采用该方法分析杭州某失稳基坑实例,通过与已有方法结果的对比,验证了该文方法的合理性。     

Investigation of the Fuzzy Complex between RSV Nucleoprotein and Phosphoprotein to Optimize an Inhibition Assay by Fluorescence Polarization

The interaction between Respiratory Syncytial Virus phosphoprotein P and nucleoprotein N is essential for the formation of the holo RSV polymerase that carries out replication. In vitro screening of antivirals targeting the N-P protein interaction requires a molecular interaction model, ideally consisting of a complex between N protein and a short peptide corresponding to the C-terminal tail of the P protein. However, the flexibility of C-terminal P peptides as well as their phosphorylation status play a role in binding and may bias the outcome of an inhibition assay. We therefore investigated binding affinities and dynamics of this interaction by testing two N protein constructs and P peptides of different lengths and composition, using nuclear magnetic resonance and fluorescence polarization (FP). We show that, although the last C-terminal Phe₂₄₁ residue is the main determinant for anchoring P to N, only longer peptides afford sub-micromolar affinity, despite increasing mobility towards the N-terminus. We investigated competitive binding by peptides and small compounds, including molecules used as fluorescent labels in FP. Based on these results, we draw optimized parameters for a robust RSV N-P inhibition assay and validated this assay with the M76 molecule, which displays antiviral properties, for further screening of chemical libraries.     

Co基赫斯勒合金研究进展

Co基赫斯勒合金是一类具有高度有序晶体结构的金属间化合物,其化学组成常用Co2XY表示,其中X为过渡金属元素,Y为主族元素。相比于其他材料,它具有更高的自旋极化率、更高的居里温度以及更低的阻尼因子。基于这些优良特性使得Co基赫斯勒合金在自旋阀、隧道结及半导体自旋场效应管等自旋电子学器件中具有巨大的应用前景。本文回顾了近年来国际上关于的Co基赫斯勒合金在垂直磁各向异性和自旋轨道转矩上的研究,从合金成分、微观结构、磁性层的厚度、缓冲层的材料、氧化物层的材料、元素扩散等方面总结了垂直磁各向异性和自旋轨道转矩的影响因素。对垂直磁各向异性和自旋轨道转矩的影响因素的总结有助于我们更好地理解其深层物理机制以及在未来研究中的挑战与前景。     

原位观察MnS对非调质钢拉伸性能各向异性的影响

利用激光共聚焦扫描显微镜原位观察S质量分数为0.065%的非调质钢纵向与横向拉伸过程中MnS的行为,研究MnS形貌与分布对非调质钢各向异性的影响.原位观察表明锻后钢中存在大量长条形MnS,横向与纵向拉伸过程中MnS长度方向与拉力方向取向不同.横向拉伸过程中MnS更易与基体分离产生裂纹,裂纹随MnS长度方向扩展长大,最终导致基体的断裂.MnS在纵向拉伸时不易与基体分离,因此对纵向拉伸性能影响较小.钢中群聚分布的MnS有利于裂纹的聚合长大,会促进基体的断裂.