中国体型模特玩偶娃娃衣袖原型研究

基于模特体型玩偶在市场上对青少年的影响,对市场上常见的模特体型的玩偶娃娃进行了相关尺寸的测量与统计,按照统计结果进行体型分类,在体型分类下制定了中国体型模特玩偶的原型设定数值并根据此数值利用立裁的方式进行反复修改设计出了中国体型模特玩偶的衣袖原型纸样．验证结果表明,在静态与基本动态状态下,其具有合理性及应用性．     

两种适合零膨胀微晶玻璃晶化热处理工艺制定的实验方法研究

通过晶核形成速度和晶体生长速度曲线可以确定零膨胀微晶玻璃晶化热处理工艺的主要参数,但受到各种因素的影响,往往不能及时、准确地得到这两条曲线。研究表明可以通过晶化热处理过程中一些反映内部结构变化的性质和现象,来制定和优化晶化热处理工艺。本文通过对晶化热处理过程折射率ND和发热量的变化进行记录和分析,制定和优化了晶化热处理工艺的方法。     

Synthesis of Cu nano-particle in toluene used for conductive ink with a binder of polyurethane

Copper nanoparticles with a size of about 150 nm were prepared in toluene using oleic acid as protecting agent. The nanoparticles were used to prepare conductive Cu ink with a polyurethane binder. Oleic acid was used to prevent the nanoparticles from oxidization and agglomeration. The prepared Cu nanoparticles were characterized by X-ray diffraction （XRD） and transmission electron microscopy （TEM）. The resistivity of the copper film on glass substrate that was prepared using Cu nanoparticle ink reached about 1.5× 10-4 2. cm-1 after it was annealed to 120 ~C. Both the nanoparticle ink and the films were characterized by XRD, fourier transform infrared （FT-IR）, and the thermogravimetry-differential scanning calorimetry instrument （TG- DSC）.     

人因工效学在生产工位作业中的分析及应用

利用Jack软件建立所需要的人体模型,并在此基础上运用OWAS和RULP分析工具进行仿真,对生产线中的手工作业进行工效学分析。通过仿真分析来研究员工在生产线的工序操作中的人因缺陷,结合人因学改善原则设计出相应的改进方案,改善员工的操作作业。结果显示改善方案明显减轻了操作者的劳动损伤,降低其疲劳度。     

玻璃钢横流冷却塔变频调速的运行节能

本文根据经统计分析得到的哈尔滨地区地面逐时气象资料，对微机控制变频调速玻璃钢横流冷却塔的风机能耗进行了动态计算，运用经济分析理论中的动态评价方法，同不调速玻璃钢横流冷却塔的风机能耗进行了定量分析对比，结果表明，尽管变频调速冷却塔初投资高，但其节能效益相当可观，应引起工程界的重视。     

高导热系数聚丙烯复合材料的制备及研究

将氧化镁、氧化铝和石墨分别与聚丙烯熔融共混制备导热复合材料,考察了填料种类、基体黏度和增容改性对复合材料导热系数(λ)的影响。结果表明:增加填料含量能逐渐提高λ,且填料的λ直接决定了复合材料的λ;基体黏度越高,复合材料导热性能提高越显著;对氧化镁和氧化铝进行表面改性同时加入增容剂,可以明显减少填料的团聚,形成更多的有效网链,能有效提高复合材料的导热性能。探究了将氧化镁和氧化铝分别与石墨复配来制备高λ的复合材料,发现少量石墨与无机填料复配可以大幅提高复合材料的λ,当聚丙烯/增容剂/氧化镁/石墨质量比为30/10/50/10时,λ达到1.267 W/(m K),比不添加石墨时提高了50%;而对于氧化铝和石墨的复配体系,λ为0.622 W/(m K),相比于未添加石墨时增加了60%。     

Structural symmetry breaking of silicon‐containing poly(amide‐imide) oligomers and its relation to electrical conductivity and Raman‐active vibrations

Optically active poly(amide‐imide) oligomers were synthesized by direct polycondensation between an aromatic diamine and a dicarboxylic acid both containing a diphenylsilylene unit. The reaction was carried out using triphenyl phosphite/pyridine in the presence of CaCl₂ and N‐methyl‐2‐pyrrolidone as solvent. Oligomers were obtained in good yields and showed high solubility in common aprotic polar solvents. The precursors, monomers and poly(amide‐imide) oligomers were characterized using elemental analysis and Fourier transform infrared and NMR (¹H, ¹³C, ²⁹Si) spectroscopy. Additionally, the main vibrations of the functional groups (C?O, C?C or N? H) in the oligomers with respect to temperature were characterized using Raman spectroscopy. The glass transition temperature was determined by studying the Raman spectra and corroborated using differential scanning calorimetry. The thermal stability was studied using thermogravimetric analysis. The molecular mass of the compounds was obtained from matrix‐assisted laser desorption ionization time‐of‐flight mass spectrometry and their optical properties were analyzed using UV‐visible diode array spectrophotometry. The electronic properties of the oligomers as well as the delocalization of charge carriers within their structures were analyzed using conductance‐voltage curves, which showed that these materials are excellent candidates for integrated optoelectronic applications. Copyright © 2011 Society of Chemical Industry     

HGB/TPU复合泡沫材料的制备及泡孔结构研究

采用空心玻璃微珠（HGB）填充热塑性聚氨酯（TPU）,制备了HGB/TPU复合泡沫材料。研究了硅烷偶联剂KH550对HGB的表面处理,并借助SEM探讨了不同发泡方式、发泡剂含量、HGB含量对复合泡沫材料微观形态结构的影响。结果表明：经KH550处理的HGB与TPU基体界面结合良好;通过注塑发泡得到的泡沫材料发泡效果较好;当发泡剂含量为1%、HGB含量为2%时复合泡沫材料的泡孔分布均匀,尺寸较为均一。     

导电高分子材料的研究进展

与传统的导电材料相比较,导电高分子材料具有许多独特的性能,例如密度小、易加工、耐腐蚀、结构易变、半导体、可大面积成膜以及电导率可在大范围内调节等特点,显示出了其广阔的应用前景。着重综述了导电高分子材料的分类,并分别介绍了复合型和结构型两种导电高分子材料的制备以及导电机理,列举出了导电高分子材料在隐身技术、显示材料、电池、导体、药物释放、传感器方面的应用,并对导电高分子材料未来的发展前景做了展望。     

Acetone—Formaldehyde—Phenol based IPNs for Glass Fibre Reinforced Composite Applications

Abstract

Three component IPNs Glass fibre reinforced composites (GRC) have been prepared from acetone-formaldehyde-phenol (AF-P) resin, Diglycedyl ether of bisphenol-A (DGEBA) (a commercial epoxy resin) and methyl methacrylate (MMA) (a vinyl monomer). The curing catalyst hexamethylene tetramine (HMTA) for AF-P, radical initiators 2,2′-azobisisobutyronitrile (AIBN) for MMA and curing catalyst 4,4′-diamino diphenyl methane (DDM) for epoxy resin were employed. All the IPN GRCs were characterized in terms of their resistance to chemical reagents, thermal behaviour (DSC, TGA) and mechanical properties.