Analysis and characterization of orientation structure of pre-oxidized PAN fibers in high magnetic fields

PAN fibers pre-oxidized at 240 ℃, 260 ℃, 280 ℃, 300 ℃ were treated in 8 T, 12 T, 16 T high magnetic fields, respectively. The experimental result implied that there were two kinds of magnetic units cyan and carbon-nitrogen heterocycle in pre-oxidized PAN fibers, and the movement of magnetic units resulted in changes of orientation structure of pre-oxidized PAN fibers in high magnetic fields. Overall orientation increased with increase of magnetic field intensity and extension of processing time, whereas change of crystalline orientation depended on magnetic field intensity and content of carbon-nitrogen heterocycle due to the competition of two magnetic units. Furthermore, magnetic fields induced the conversion from amorphous region to crystal region and improved crystalline properties of pre-oxidized PAN fibers.     

国际化视野下城市公共艺术案例研究

公共艺术是一个城市的名片,代表城市的形象,放大了城市的功能价值,因此,城市公共艺术建设越来越被关注和重视.国际上,人们对公共艺术功能的解读逐渐清晰,不再将其简单看作城市装饰品,而是更高地定位在创造和提升城市美学品质,注重物质文化消费,平衡生态环境,促进自然社会可持续发展等方面.通过对相关城市公共艺术案例的解读分析,试图揭示公共艺术的价值取向,营造理想的公共艺术文化生态.     

知识管理能力、创业导向与中小企业绩效的关系研究

首先通过知网搜索相关文献,讨论知识管理能力、创业导向与企业绩效的基本内涵;其次挖掘三者之间可能的潜在关系,提出了创业导向、知识管理能力与企业绩效之间关系的基本假设、理论雏形以及相关变量测度问题,在此基础上,收集皖江城市带中小企业相关数据进行实证分析。实证结果表明:创业导向、知识管理能力对企业绩效起着正向作用;创业导向对知识管理能力起着正向作用;知识管理能力在创业导向对企业绩效中起着部分中介作用。最后,提出结论、相关建议以及未来展望。     

高校始业教育中团体辅导模式探索

高校始业教育中团体辅导模式对大学生具有的激励和引导作用。应以促进人际关系发展、培养集体归属感、拓展个体视野、提升个体价值等为前提,通过班级辅导、职业规划、自我探索、时间管理等辅导模式,探索团体辅导模式在高校始业教育活动中的积极作用。     

论自备电厂的价税导向政策

自备电厂在能源供给中占有特殊的地位,其存在和壮大既有我国宏观市场经济发展的背景,也有微观企业逐利行为的影响。文章着重从充分发挥价格财税杠杆作用,及时传导电价信号的角度出发,梳理目前自备电厂在节能减排、环保电价、税费政策执行等方面存在的问题,剖析成因,提出以价值导向为核心的解决思路,以期为促进自备电厂的健康发展提出有益的意见和建议。     

论地方本科院校培养目标的定位:技术应用型人才

文章对应用型人才的内涵、界定及分类培养等进行了剖析,基于对"培养高等技术应用型人才"的理解和把握,阐述了地方本科院校培养目标的定位问题。     

Phase evolution and <110>-orientation mechanism in RTGG-processed BaTiO3 ceramics with electrical properties

The <110>-oriented BaTiO₃ ceramics were fabricated using BaCO₃ matrix and H_1.08Ti_1.73O₄.nH₂O (HTO) template particles, and the mechanism of BaTiO₃ phase formation was investigated. The dielectric, ferroelectric, and piezoelectric properties were also investigated. The transformation of the HTO phase into the TiO₂ bronze or TiO₂ (B) phase was observed at 600°C, where the BaTiO₃ nucleation was accompanied by the formation of a Ba₂TiO₄ phase. The TiO₂ phase reacted with the Ba₂TiO₄ phase at 800°C to give a BaTiO₃ phase, whereas its reaction with the BaTiO₃ resulted in the formation of BaTi₂O₅ phase that got decomposed into BaTiO₃ and Ba₆Ti₁₇O₄₀ phase at sintering temperature ≥1300°C. Sintering with samples’ embedding in BaTiO₃ powders prevented the formation of the Ba₆Ti₁₇O₄₀ secondary phase. The crystallographic orientation along the <110> direction (F₁₁₀) was developed by the epitaxial grain growth mechanism. In addition to the contribution of the grain-size increment for enhancing the F₁₁₀, the preservation of the platelike structure was also found to have a significant impact. The ceramics prepared by the embedded sintering (grain size ≈12.4 µm and F₁₁₀ = 83%) exhibited the room-temperature dielectric constant of 1708 and piezoelectric strain constant of 445 pm/V, which are higher than those of the BaTiO₃ ceramics with randomly oriented grains.     

碳纳米纤维增强聚甲醛复合材料制备及性能

通过纳米碳纤维(CNFs)在聚甲醛(POM)基体中的均匀分散以及取向,制备了具有优异力学性能和热性能的POM/CNFs复合材料。利用扫描电子显微镜、透射电子显微镜、拉伸性能测试、热重分析、动态热机械分析测试表征了POM/CNFs复合材料的结构和力学、热学性能。结果表明,CNFs与POM分子链形成氢键相互作用,促进了CNFs在POM基体内分散,同时使POM/CNFs复合材料的结晶度显著提高。随着CNFs含量增加,POM/CNFs复合材料的拉伸强度、储能模量和损耗模量均得到提高。当添加0.5%的CNFs时,拉伸强度、储能模量及损耗模量分别提高了20.5%,127%和58%。进一步研究了高温拉伸对POM/CNFs复合材料性能的影响。结果表明,CNFs沿拉伸方向定向排列,同时复合材料拉伸后结晶度提高,拉伸强度显著增加。     

Study of δ-hydrides in Ti-2Al-2.5Zr and Ti-4Al-2V alloys

The α alloy Ti-2Al-2.5Zr and near α alloy Ti-4Al-2V were hydrogenated to various levels. The morphology,orientation relation (OR), and habit plane of the hydrides were studied by means of transmission electron microscopy (TEM). It was found that in the two alloys most of the precipitates are δ-hydrides which have fcc structure with the lattice parameter a = 0.44 nm. Two basic orientation relationships and habit planes of the precipitates are determined. Twin structure was observed in both alloys.     

一种新型五自由度混联机床的运动及仿真分析

提出用两个二自由度并联机构相串联而成的混联机构作为主进给机构,外加一维运动的工作平台使之能实现五坐标数控加工的一种新型混联机床.其具有结构简单、易于控制的特点.对其机构进行了描述,应用螺旋理论分析了球形五杆机构的运动螺旋及其反螺旋,在此基础上求得其自由度;分析了该混联机床封闭的运动学正反解,用数值方法对其正确性进行了验证;并在此基础上以Visual C 为平台,利用OpenGL对其运动进行了仿真,对设计思想及设计细节进行了验证,为样机制造提供了可靠保证.