一种低压燃料电池用逆变器的设计

研制了一种适用于低电压大电流输入的具有高频链燃料电池逆变器,详细介绍了这种逆变器的电路拓扑结构、控制策略和实现方法。该逆变器由前级Boost型推挽变换器和后级DC/AC逆变桥构成,为有效地提高逆变器的效率,在实际中采取了多种措施。研制了一台12V/50Hz/1kW的样机,通过工业现场中实际运行,表明该逆变器电气性能优良,为该逆变器在低压大电流工况下的应用提供了一种理想解决方案。     

Phase change memory alloys: GST cell array characterization using picosecond ultrasonics

Phase change random access memory alloys (PRAM or PCM) are a class of non-volatile memory that is thought as viable alternatives to flash memory technology or to supplement other memory technologies depending on the end applications and its key performance requirements. Ge₂Sb₂Te₅ alloy (GST) is the most widely used chalcogenide material for PCM application, and has many unique properties, including strong temperature-dependent film properties, low thermal conductivity, and high electrical resistivity. Picosecond ultrasonics was used to make non-contact, non-destructive measurements of GST films on blanket wafers and directly on product wafers. On-product wafer measurements were made on various via array (0.5 μm and 1 μm between cell edges with CD size from 250 to 800 nm). Measurements have shown excellent correlation to cross-section SEM and were consistent with CMP polish times for both blanket and pattern wafer measurement. Excellent repeatability based on extensive measurements demonstrates the capability and reliability of picosecond ultrasonic technology. Picosecond ultrasonic measurements also provide rapid characterization across the whole wafer at production-worthy throughputs.     

Infrared emission properties and energy transfer in ZnO-SiO2:Yb composites

Intense near-infrared emission at 1 μm has been obtained in ZnO-SiO₂:Yb³⁺ composites via a facile sol-gel method upon broadband ultraviolet light excitation. Systematic optical measurements including static and time-resolved photoluminescence have been performed to elucidate the energy transfer from ZnO quantum dots to Yb³⁺ ions. The dependence of energy transfer efficiency on Yb³⁺ concentration has been investigated in detail. Codoping with Li⁺ ions leads to about twice enhancement of the near-infrared luminescence intensity around 1 μm at room temperature. The enhancement in the luminescence intensity could be mostly attributed to the modification of the local symmetry around Yb³⁺ ions by codoping with Li⁺ ions.     

华蟾素注射液对人肝癌HepG-2细胞增殖及周期的影响

Objective: The aim of our study was to investigate the effect of Cinobufacini injection on the proliferation and cell cycle of human hepatoma HepG-2 cells. Methods: Cell proliferation was assessed by MTT assay, cell cycle distributionwas detected by the flow cytometry (FCM). The expression of Cyclin A, CDK2 mRNA levels were examined by RT-PCR.Quantitative colorimetric assay was used to analyze Cyclin NCDK2 activity in HepG-2 cells. Results: Cinobufacini injection significantly inhibited HepG-2 cells proliferation in dose- and time-dependent ways; FCM analysis showed Cinobufacini injection induced cell cycle arrest at S phase; RT-PCR assay showed Cinobufacini injection down-regulated Cyclin A, CDK2expression at mRNA levels; Quantitative colorimetric assay showed Cinobufacini injection deceased Cyclin A/CDK2 activity in HepG-2 cells. Conclusion: Cinobufacini injection can inhibit human hepatoma HepG-2 cells growth, induce cell apoptosis and induce cell cycle arrest at S phase, the mechanism of which might be partly related to the down-regulation of Cyclin A,CDK2 mRNA expression and inhibition of Cyclin A/CDK2 activity.     

Lectin Conjugated Gold Nanoparticle-based Colorimetric Assay for Studying the Interactions of Antibiotic with Living Cell

The interactions of antibiotic with living cells were studied by lectin conjugated gold nanoparticles(GNPs)based colorimetric assay. Because of the high affinity of lectin for saccharides, the lectin conjugated GNPs are able to employ as indicators for monitoring the antibiotic induced changes of glycosyl complexes. The interactions of a well known antibiotiC., tunicamycin, with two different cell lines, HeLa and SHG-44, were selected to establish this assay.In the presence of tunicamycin, the dose-and time-dependence on the decreasing of binding affinity of lectin conjugated GNPs with living cells were demonstrated by conventional microscopic and UV-Vis spectroscopic studies. The experimental result demonstrates that our approach can be used to identify antibiotic induced expression difference of glycosyl complexes on different cellular surfaces and determine drug activity quantitatively. For further confirming the capability of the GNP-based assay, the system was also studied by confocal laser scanning microscopy(CLSM)and classic flow cytometry(FCM) assay, and satisfactory results were obtained.     

Electrochemical analysis of dye adsorption on aligned carbon nanofiber arrays coated with TiO2 nanoneedles for dye-sensitized solar cell

An electrochemical method has been developed to analyze dye absorption on the aligned carbon nanofiber arrays coated with TiO2 nanoneedles for dyesensitized solar cell. The unique nanostructure with the roughness factor of 90.6 provides a large effective surface area for dye adsorption. The experimental results showed that the dye molecules cover 39.7% of the TiO2 surface area which influences the performance of dye-sensitized solar cell. The electrochemical method provides the information of the coverage of dye molecules which is a key issue to optimize solar cell performance.     

A 3D multilevel model of damage and strength of wood: Analysis of microstructural effects

A 3D hierarchical computational model of damage and strength of wood is developed. The model takes into account the four scale microstructures of wood, including the microfibril reinforced structure at nanoscale, multilayered cell walls at microscale, hexagon-shape-tube cellular structure at mesoscale and annual rings at the macroscale. With the use of the developed hierarchical model, the influence of the microstructure, including microfibril angle (MFA), the cell shape and the wood density (annual ring structure), differences between earlywood and latewood as well as microstructural arrangements and cellulose strength distributions on the tensile strength of wood is studied numerically. Good agreement of the theoretical results with experimental data has been obtained.     

The Role of Lattice Matching Techniques in the Characterization of Polymorphic Forms

An inspection of the recent literature reveals that polymorphism is a frequently encountered phenomenon. The recognition of polymorphic forms plays a vital role in the materials sciences because such structures are characterized by different crystal packing and accordingly have different physical properties. In the pharmaceutical industry, recognition of polymorphic forms can be critical for, in certain cases, a polymorphic form of a drug may be an ineffective therapeutic agent due to its unfavorable physical properties. A check of the recent literature has revealed that in some cases new polymorphic forms are not recognized. In other instances, a supposedly new polymeric form is actually the result of an incorrect structure determination. Fortunately, lattice-matching techniques, which have proved invaluable in the identification and characterization of crystal structures, represent a powerful tool for analyzing polymorphic forms. These lattice-matching methods are based on either of two strategies: (a) the reduced cell strategy–the matching of reduced cells of the respective lattices or (b) the matrix strategy–the determination of a matrix or matrices relating the two lattices coupled with an analysis of the matrix elements. Herein, these techniques are applied to three typical cases–(a) the identification of a new polymorphic form, (b) the demonstration that a substance may not be a new polymorphic form due to missed symmetry, and (c) the evaluation of pseudo polymorphism because of a missed lattice. To identify new polymorphic forms and to prevent errors, it is recommended that these lattice matching techniques become an integral part of the editorial review process of crystallography journals.