特高压1000kV并联电抗器首端引线两种出线方式的分析与研究

本文中作者介绍了1 000kV并联电抗器首端两种引线出线方式的结构,利用Elec Net软件对两者进行了仿真分析,并进行了经济性对比。     

Alchemical Design of Pharmacological Chaperones with Higher Affinity for Phenylalanine Hydroxylase

Phenylketonuria (PKU) is a rare metabolic disease caused by variations in a human gene, PAH, encoding phenylalanine hydroxylase (PAH), and the enzyme converting the essential amino acid phenylalanine into tyrosine. Many PKU-causing variations compromise the conformational stability of the encoded enzyme, decreasing or abolishing its catalytic activity, and leading to an elevated concentration of phenylalanine in the blood, which is neurotoxic. Several therapeutic approaches have been developed to treat the more severe manifestations of the disorder, but they are either not entirely effective or difficult to adhere to throughout life. In a search for novel pharmacological chaperones to treat PKU, a lead compound was discovered (compound IV) that exhibited promising in vitro and in vivo chaperoning activity on PAH. The structure of the PAH-IV complex has been reported. Here, using alchemical free energy calculations (AFEC) on the structure of the PAH-IV complex, we design a new generation of compound IV-analogues with a higher affinity for the enzyme. Seventeen novel analogues were synthesized, and thermal shift and isothermal titration calorimetry (ITC) assays were performed to experimentally evaluate their stabilizing effect and their affinity for the enzyme. Most of the new derivatives bind to PAH tighter than lead compound IV and induce a greater thermostabilization of the enzyme upon binding. Importantly, the correspondence between the calculated alchemical binding free energies and the experimentally determined ΔΔG_b values is excellent, which supports the use of AFEC to design pharmacological chaperones to treat PKU using the X-ray structure of their complexes with the target PAH enzyme.     

不拆高压引线测量耦合电容器介质损耗和电容量

针对耦合电容器拆高压引线传统预防性试验的不足,根据不拆高压引线测量耦合电容器介质损耗和电容量值的试验方法,通过对南雁变南仙4367线等4条线路实测,与传统试验数据进行了对比分析,证明该方法可行有效。     

InGaAlP LED发光特性分析

InGaAlP LED发光效率高，性能稳定，应用相当广泛。在InGaAlP LED的应用中，发光特性是相当重要的参数，而发光强度和半强度角是LED发光特性的两个主要参数。介绍了不同的InGaAlP LED芯片结构．分析了其发光特点及封装后的发光特性，讨论了不同的反射式支架结构对其发光特性产生的不同影响。     

(Na_(1/2)Bi_(1/2))TiO_3-SrTiO_3无铅压电陶瓷的介电、压电性能

研究了 (Na1 / 2 Bi1 / 2 ) Ti O3- Sr Ti O3二元系无铅压电陶瓷的介电、压电性性。Sr2 的引入对 NBT材料的常温介电系数、铁电相与反铁电相转变温度 TF A(180°C)以及居里温度 TC(30 0°C)的影响都不大 ,但却较大幅度地降低了 NBT材料的高矫顽场 ,从而使极化相对容易。(Na1 / 2 Bi1 / 2 ) Ti O3- Sr Ti O3二元系的压电性能参数 d33和 kt分别达到 10 0 p C/N和 0 .45     

等离子蚀刻挠性PI基材制作悬空引线及其参数优化

悬空引线的制作是挠性印制线路板制作的难点之一,需要在基材的某些区域蚀刻掉PI（聚酰亚胺）基材来满足设计的要求。目前采用的在基材上开窗口的方法有机械冲切、数控铣、化学试剂蚀刻法和等离子蚀刻法等。其中,等离子蚀刻法加工精度高、操作简便、清洁环保,但由于运行成本相对较高使其生产应用受到了限制。本文通过正交设计试验优化等离子蚀刻PI的参数,以达到充分利用气体、缩短等离子蚀刻时间的目的,从而大大降低等离子蚀刻过程的成本。并最终完成悬空引线的制作。     

A Systematic Approach to Achieving High Performance Hybrid Lighting Phosphors with Excellent Thermal‐ and Photostability

The authors have designed and synthesized a family of high‐performance inorganic–organic hybrid phosphor materials composed of extended and robust networks of one, two, and three dimensions. Following a bottom‐up solution‐based synthetic approach, these structures are constructed by connecting highly emissive Cu₄I₄ cubic clusters via carefully selected ligands that form strong Cu? N bonds. They emit intensive yellow‐orange light with high luminescence quantum efficiency, coupled with large Stokes shift, which greatly reduces self‐absorption. They also demonstrate exceptionally high framework‐ and photostability, comparable to those of commercial phosphors. The high stabilities are the result of significantly enhanced Cu? N bonds, as confirmed by the density functional theory (DFT) binding energy and electron density calculations. Possible emission mechanisms are analyzed based on the results of theoretical calculations and optical experiments. Two‐component white phosphors obtained by blending blue and yellow emitters reach an internal quantum yield as high as 82% and correlated color temperature as low as 2534 K. The performance level of this subfamily exceeds all other types of Cu–I based hybrid systems. The combined advantages make them excellent candidates as alternative rare‐earth element‐free phosphors for possible use in energy‐efficient lighting devices.     

Investigation of LSPR Coupling Effects toward the Rational Design of CsxWO3–δ Based Solar NIR Filtering Coatings

The optical range of localized surface plasmon resonance (LSPR) is extended into the infrared region, thanks to the development of highly doped semiconductor nanocrystals. Particularly, the near-infrared (NIR) range holds a significant interest in managing solar radiation. However, practical applications necessitate the arrangement of particles, which is known to possibly impact their optical properties through LSPR coupling effects. How such coupling modifies the LSPR response in semiconductor hosts remains largely unexplored. In this study, a protocol for producing composite coatings composed of cesium-doped tungsten bronze nanocrystals embedded in a silica matrix is presented. Achieving individual dispersion of nanocrystals is made possible through careful selection of a surface polyglycerol ligand exchange. This allows to tune the interparticle distance by adjusting the nanocrystal volume fraction in the composite. The findings demonstrate that LSPR coupling effects significantly influence the LSPR intensity of nanocrystals in the composite when the nanocrystal-to-nanocrystal distance matches their size. Beyond elucidating the LSPR coupling effect, this study provides insights into the potential use of Cs-HTB nanocrystals for solar control applications. Through the optimization of morphology and film structure, remarkable selectivity is obtained in terms of maintaining good transparency in the visible range while achieving high absorption in the NIR.     

热分解法制备钛酸铅镧薄膜及其电性能研究

本文研究了用金属有机物热发解法制备ＰＬＴ８薄膜的工艺过程和基片对薄膜结构的影响，并且给出了铁电性能的测量结果。