The effect of aluminium coating on elemental standards in X-ray microanalysis

The standardisation of frozen hydrated bulk biological specimens using gelatin standards is described. The relationship between corrected elemental X-ray counts and ionic concentration was found to be linear, and minimum detectable limits for each element are stated. Variations in uncorrected standard curves were found to be due to changes in aluminium coating thickness. There was an inverse relationship between coating thickness and elemental X-ray counts. The factors causing this are discussed. To avoid errors arising from inconsistent aluminium thickness, experimental material should only be compared with standards of similar aluminium net counts. This can be achieved most easily by mounting and analysing specimen and standard together.     

搅拌工艺对半固态Y112铝合金组织及性能的影响

采用自行研制的机械搅拌装置,研究了不同工艺参数对半固态Y112铝合金组织及性能的影响.研究表明,搅拌温度越高,搅拌速度越大,固相颗粒越细小、均匀和圆整,其抗拉强度与伸长率越高;但温度太高,固相颗粒会熔化,抗拉强度及伸长率也降低;随搅拌时间的延长,固相颗粒先变得细小、均匀和圆整,然后长大,抗拉强度、伸长率先升高后降低.     

Numerical study on PEMFC’s geometrical parameters under different humidifying conditions

Steady-state and three-dimensional simulations were carried out to study the influences of geometrical parameters on the performance of PEMFC under different hydrating conditions. Flow fields, species transport, transport of water in polymer membrane and movement of liquid water in cathode and anode porous layers were determined, in order to accomplish a complete estimation of ohmic and concentration losses of PEMFC power. The geometrical parameters were thickness of the polymer membrane, cathode catalyst layer as well as gas channel to rib width ratio. Every simulation was made under different relative humidities of inlet flows (50 and 100%) for every change of characteristic length. Results show that the influence of the geometrical parameters on ohmic and concentration losses is of considerable importance. The performance of PEMFC is seriously affected under dehydrating conditions. However, such performance may be considerably improved by using suitable geometrical parameters. Cathode and anode liquid saturation may not only affect the transport of species, but also the polymer electrolyte water content. These results show the importance of simultaneously calculating both the water absorption and desorption through the polymer electrolyte and the liquid saturation in the cathode and anode porous mediums to obtain an actual view of ohmic and concentration losses of the PEMFC performance.     

高坝洲电站碾压混凝土纵向围堰拆除爆破设计与实践

介绍了高坝洲电站碾压混凝土下游纵向围堰现场爆破试验成果,在分析爆破试验效果的基础上进行碾压混凝土围堰拆除爆破设计,详细分析了拆除爆破实施效果及主要影响因素.     

基于人文关怀的信号配时方法研究

在传统的信号配时中，都是以减少车辆的总延误为目标，这样并不能很好地体现出整个社会中人的时间价值。现以减少所有通过交叉口的出行者的总延误为目标，在传统的信号配时方案的基础上，提出了一套新的配时方案，同时以减少全部出行者的总延误时间为目标给出了相应的延误评价公式，最后以杭州市文一路-古翠路口的实测交通数据进行分析，论证了本配时方案的有效性。     

Non-steady-state model for kinetics of free radical polymerization, 4. Direct thermal initiation

This paper deals with the non-steady-state kinetics of direct thermal initiated polymerization. The initiation is assumed to be a bimolecular reaction of the monomer. The relationship between the radical concentration and the monomer conversion is rigorously derived. In further treatment a few very close approximations are introduced based on the fact that the number of monomer molecules reacting in the initiation step is much less than that consumed in the propagation step for a process producing high polymer, and the value of the rate constant for propagation or chain transfer is much lower than that for chain termination. Expressions for various molecular parameters, such as molecular weight distribution, number-average and weight-average degrees of polymerization, and dispersity, are given. Several numerical examples are provided.     

旋波媒质基本参数的一种测试方法

本文提出了直接利用旋波材料板的Ｓ参数获得其基本参数的方法。通过自由空间测量旋波材料板的反射场和透射场，可以反演得到媒质的复介电常数、复磁导率、旋波量以及透射场的轴比和旋转角，测试程序简单，结果精度高。     

节理岩体的代表单元集合体模型及弹性参数预测

本文明确提出了节理岩体“代表单元集合体”的概念和模型，通过对节理岩体的“代表单元集合体”进行数值模拟，研究了节理岩体的“代表单元集合体”的变形特性，建立了节理岩体的弹性模型，提出了预测节理岩体宏观等效弹性参数的计算机模拟方法，并将其应用于岩体工程稳定性分析中。     

Hydrolytic stability and protective properties of polyurethane oligomers based on polyester/ether/polyols

The present study deals with effect of the type and chemical character of incorporated polyester/polyether blocks on the hydrolytic stability of crosslinked polyurethane oligomers. Diffusion parameters of the investigated polyurethane oligomers, giving information concerning chemical changes taking place in neutral, basic and acidic aqueous environments, have also been determined.